[8,8-η2-{η2-(BH3)Ph2PCH2PPh2}-nido-8,7-RhSB9H10]: A rhodathiaborane with a novel bidentate chelating ligand

Angewandte Chemie - International Edition

Volumn 38, Issue 1-2, 1999, Pages 162-164

  Macías, Ramón ^a   Rath, Nigam P ^a   Barton, Lawrence ^a  

^a UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

Boron; Clusters; P ligands; Rhodium

Indexed keywords

BORANE DERIVATIVE; CHELATING AGENT; LIGAND; PHOSPHINE DERIVATIVE; PROPANE; RHODIUM DERIVATIVE;

ARTICLE; CHELATION; CHEMICAL BOND; CHEMICAL REACTION; CRYSTAL STRUCTURE; LIGAND BINDING; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOCHEMISTRY;

EID: 0037755054     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990115)38:1/2<162::AID-ANIE162>3.0.CO;2-U     Document Type: Article

References (15)

1. R. N. Grimes in Metal Interactions with Boron Clusters (Ed.: R. N. Grimes), Plenum Press, New York, 1982, chap. 7. pp. 269-319.
2. F. Takusagawa, A. Fumigalli, T. F. Koetzle, S. G. Shore, T. Schmitkons, A. V. Fratini, K. W. Morse, C.-Y. Wei, R. Bau. J. Am. Chem. Soc. 1981, 103, 5165-5171.
3. M. Y. Darensbourg, R. Bau, M. W. Mark, R. R. Burch, Jr., J. C. Deaton, S. Slater. J. Am. Chem. Soc. 1982, 104, 6961-6969.
4. S. A. Snow, M. Shimoi, C. D. Ostler, B. K. Thompson, G. Kodama, R. W. Parry, Inorg. Chem. 1984, 23, 511-512.
5. S. A. Snow, G. Kodama, Inorg. Chem. 1985, 24, 795-796.
6. K. Katoh, M. Shimoi, H. Ogino, Inorg. Chem. 1992, 31, 670-675.
7. M. Shimoi, K. Katoh, M. Uruichi, S. Nagai, H. Ogino in Current Topics in the Chemistry of Boron, Vol. 143 (Ed.: G. W. Kabalka). Royal Society of Chemistry, Cambridge, 1994, pp. 293-296.
8. G. Ferguson, M. C. Jennings, A. L. Lough, S. Coughlan, T. R. Spalding, J. D. Kennedy, X. L. R. Fontaine, B. Štíbr. J. Chem. Soc. Chem. Commun. 1990, 891-894.
9. P. McQuade, R. L. Thomas, H. Fang, N. P. Rath, L. Barton, Abstr. Pap. 6th Boron-USA Workshop (Athens, GA, USA) 1998.
10. G. M. Rosair, A. J. Welch, A. S. Weller, Acta Crystallogr. Sect. C 1996, 52, 3020-3024.
11. L. Barton, J. Bould, H. Fang, K. Hupp, N. P. Rath, C. Gloeckner. J. Am. Chem. Soc. 1997, 119, 631-632.
12. D. J. Elliot, C. J. Levy, R. J. Puddephatt, D. G. Holah, A. N. Hughes, V. R. Magnuson, I. M. Moser, Inorg. Chem. 1990, 29, 5014-5015.
13. Cambridge Structural Database. QUEST-3D query, with the Rh-B distance in the fragment Rh-B-H constrained to be between 1.8 and 2.5 Å.
14. 3, 25 C): δ = 15.2.
15. K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1-66.