Coordination compounds of monoborane-Lewis base adducts: Syntheses and structures of [M(CO)5(η1-BH3·L)] (M = Cr, Mo, W; L = NMe3, PMe3, PPh3)

Journal of the American Chemical Society

Volumn 121, Issue 50, 1999, Pages 11704-11712

  Shimoi, Mamoru ^a   Nagai, Shin Ichiro ^a   Ichikawa, Madoka ^a   Kawano, Yasuro ^a   Katoh, Kinji ^b   Uruichi, Mikio ^b   Ogino, Hiroshi ^b  

^a UNIVERSITY OF TOKYO   (Japan)

^b TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BORANE DERIVATIVE; BORON; HYDROGEN; MOLYBDENUM COMPLEX;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CONTROLLED STUDY; CRYSTAL STRUCTURE; PHOTOLYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; TEMPERATURE DEPENDENCE; THERMOSTABILITY; X RAY ANALYSIS;

EID: 0033596338     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja990828p     Document Type: Article

References (91)

1. (a) Vogler, A. In Concepts of Inorganic Photochemistry; Adamson, A. W., Freischauer, P. W., Eds.; John Wiley and Sons: New York, 1975; pp 274-276.
2. (b) Alway, D. G.; Barnett, K. W. Photochemical Process in Cyclopentadienylmetal Carbonyl Complexes. In Inorganic and Organometallic Photochemistry; Wrighton, M. S., Ed.; Advances in Chemistry Series 168; American Chemical Society: Washington, DC, 1978.
3. (a) Kelly, J. M.; Hermann, H.; Koerner von Gustorf, E. J. J. Chem. Soc., Chem. Commun. 1973, 105.
4. (b) Simon, J. D.; Xie, X. J. Phys. Chem. 1986, 90, 6751.
5. Joly, A. G.; Nelson, K. A. J. Phys. Chem. 1989, 93, 2876.
6. (a) Hermann, H.; Grevels, F.-W.; Henne, A.; Schaffner, K. J. Phys. Chem. 1982, 86, 5151.
7. (b) Hodges, P. M.; Jackson, S. A.; Jacke, J.; Poliakoff, M.; Turner, J. J.; Grevels, F.-W. J. Am. Chem. Soc. 1990, 112, 1234.
8. Zarić, S.; Hall, M. B. J. Phys. Chem. A 1997, 101, 4646.
9. Marks, T. J.; Kolb, J. R. Chem. Rev. 1977, 77, 263 and references cited therein.
10. (a) Kirtley, S. W.; Andrews, M. A.; Bau, R.: Grynkewich, G. W.; Marks, T. J.; Tipton, D. L.; Whittlesey, B. R. J. Am. Chem. Soc. 1977, 99, 7154.
11. (b) Darensbourg, M. Y.; Bau, R.; Marks, M. W.; Burch, R. R., Jr.; Deaton, J. C.; Slater, S. J. Am. Chem. Soc. 1982, 104, 6961.
12. (c) Wei, C.-Y.; Marks, M. W.; Bau, R.; Kirtley, S. W.; Bisson, D. E.; Henderson, M. E.; Koetzle, T. F. Inorg. Chem. 1982, 21, 2556.
13. (a) Bommer, J. C.; Morse, K. W. J. Chem. Soc., Chem. Commun. 1977, 137.
14. (b) Bommer, J. C.; Morse, K. W. Inorg. Chem. 1979, 18, 531.
15. Bommer, J. C.; Morse, K. W. Inorg. Chem. 1980, 19, 587.
16. (a) Atwood, J. L.; Rogers, R. D.; Kutal, C.; Grutsch, P. A. J. Chem. Soc., Chem. Commun. 1977, 593.
17. 9
18. Takusagawa, F.; Fumagalli, A.; Koetzle, T. F.; Shore, S. G.; Scmitkons, T.; Fratini, A.; Morse, K. W.; Wei, C. W.; Bau, R. J. Am. Chem. Soc. 1981, 103, 5165.
19. (b) Liu, F.-C.; Liu, J.; Meyers, E. A.; Shore, S. G. Inorg. Chem. 1999, 38, 2169.
20. Parry, R. W. Phosphorus, Sulfur Silicon Relat. Elem. 1994, 87, 177.
21. Snow, S. A.; Shimoi, M.; Ostler, C. D.; Thompson, B. K.; Kodama, G.; Parry, R. W. Inorg. Chem. 1984, 23, 511.
22. Snow, S. A.; Kodama, G. Inorg. Chem. 1985, 24, 795.
23. Shimoi, M.; Katoh, K.; Tobita, H.; Ogino, H. Inorg. Chem. 1990, 29, 814.
24. (a) Katoh, K.; Shimoi, M.; Ogino, H. Inorg. Chem. 1992, 31, 670.
25. (b) Shimoi, M.; Katoh, K.; Ogino, H. J. Chem. Soc., Chem. Commun. 1990, 811.
26. Shimoi, M.; Katoh, K.; Uruichi, M.; Nagai, S.; Ogino. H. In Current Topics in the Chemistry of Boron; Kabalka, G. W., Ed.; The Royal Society of Chemistry: London, 1994; pp 293-296.
27. 3·L". equation presented
28. 17b have been reported. (a) Khasnis, D. V.; Toupet, L.; Dixneuf, P. H. J. Chem. Soc., Chem. Commun. 1987, 230.
29. (b) McNamara, W. F.; Duesler, E. N.; Paine, R. T.; Ortiz, J. V.; Kolle, P.; Nöth, H. Organometallics 1986, 5, 380.
30. 3·inner base adduct to Rh in a bidentate fashion was reported: Macìas, R.; Rath, N. P.; Barton, L. Angew. Chem., Int. Ed. Engl. 1999, 38, 162.
31. Elschenbroich, Ch.; Salzer, A. Organometallics; A Consice Introduction, 2nd ed.; VCH: Weinheim, 1992; p 232.
32. Jensen, J. A.; Girolami, G. S. J. Am. Chem. Soc. 1988, 110, 4450.
33. (a) Baker, M. V.; Field, L. D. J. Chem. Soc., Chem. Commun. 1984, 996.
34. (b) Bau, R.; Yuan, H. S.; Baker, M. V.; Field, L. D. Inorg. Chim. Acta 1986, 114, L27.
35. (a) Schubert, U. Adv. Orgunomet. Chem. 1990, 30, 151.
36. (b) Schubert, U.; Ackermann, K.; Wörle, B. J. Am. Chem. Soc. 1982, 104, 7378.
37. (c) Schubert, U.; Bahr, K.; Müller, J. J. Organomet. Chem. 1987, 327, 357.
38. (d) Schubert, U.; Müller, J.; Alt, H. G. Organnmetallics 1987, 6, 469.
39. (e) Colomer, K.; Corriu, R. J. P.; Manzin, C.; Viox, A. Inorg. Chem. 1982, 21, 368.
40. (f) Schubert, U.; Scholz, G.; Müller, J.; Ackermann, K.; Wörle, B.; Stansfield, R. F. D. J. Organomet. Chem. 1986, 306, 303.
41. (a) Kubas, G. J. Acc. Chem. Res. 1988, 21, 120.
42. (b) Crabtree, R. H. Acc. Chem. Res. 1990, 23, 95.
43. (c) Morris, R. H.; Jessop, P. G. Coord. Chem. Rev. 1992, 92, 155.
44. (d) Heinkey, D. M.; Oldham, W. J., Jr. Chem. Rev. 1993, 93, 913.
45. (a) Green, M. L. H. J. Organomet. Chem. 1983, 205, 395.
46. (b) Schulz, A. J. Science 1983, 220, 197.
47. (c) Brookhart, M.; Green, M. L. H.; Wang, L. L. Prog. Inorg. Chem. 1988, 36, 1.
48. Crabtree, R. H. Angew. Chem., Int. Ed. Engt. 1993, 32, 789.
49. 26c), (a) Brammer, L.; Howard, J. A. K.; Johnson, O.; Kuetzle, T. F.; Spencer, J. L.; Stringer, A. M. J. Chem. Soc., Chem. Commun. 1991, 241.
50. (b) Schubert, U.; Schwarz, M.; Müller, F. Organometallics 1994, 13, 1554.
51. (c) Aitken, C. T.; Harrod, J. F.; Samuel, E. J. Am. Chem. Soc. 1986, 108, 4059.
52. (a) Crabtree, R. H.; Lavin, M. Inorg. Chem. 1986, 25, 805.
53. (b) Simpson, C. Q., Il; Hall, M. B. J. Am. Chem. Soc. 1992, 114, 1641.
54. (c) Fischer, R. A.; Miehr, A.; Priermeier, T. Chem. Ber. 1995, 128, 831.
55. (d) Weiss, J.; Stetzkamp, D.; Nuber, B.; Fischer, R. A.; Boehme, C.; Frenking, G. Angew. Chem., Im. Ed. Engl. 1997, 36, 70.
56. (a) Lindner, H. H.; Onak, T. J. Am. Chem. Soc. 1966, 88, 1890.
57. (b) Bushweiler, C. H.; Beall, H.; Grace, M.; Dewkett, W. J.; Bilofsky, H. S. J. Am. Chem. Soc. 1971, 93, 2145.
58. (c) Bommer, J. C.; Morse, K. W. Inorg. Chem. 1981, 19, 589.
59. Jiang, Q.; Carroll, P. J.; Berry, D. H. Organometallics 1993, 12, 177.
60. Luo, X.-L.; Kubas, G. J.; Burns, C. J.; Bryan, J. C.; Unkefer, C. J. J. Am. Chem. Soc. 1995, 117, 1159.
61. 4)] is in equilibrium not with the hydrido(silyl) complex but with an isomer generated by the rotation of the silane ligand: Fan, M.-F.; Jia, G.; Lin, Z. J. Am. Chem. Soc. 1996, 118, 9915.
62. Kubas, G. J.; Unkefer, C. J.; Swanson, B. I.; Fukushima, E. J. Am. Chem. Soc. 1986, 108, 7000.
63. Hartwig, J. F.; De Gala, R. J. Am. Chem. Soc. 1994, 116, 3661.
64. 2(cyclopentane), was directly observed by NMR: Geftakis, S.; Ball, G. E. J. Am. Chem. Soc. 1998, 120, 9953.
65. (a) Hall, M. B.; Fenske, R. F. Inorg. Chem. 1972, 11, 768.
66. (b) Bürsten, B. E.; Fenske, R. F. J. Chem. Phys. 1977, 67, 3138.
67. (c) Bürsten, B. E.; Jensen, R. J.; Fenske, R. F. J. Chem. Phys. 1978, 68, 3320.
68. (d) Fenske, R. F. Pure Appl. Chem. 1988, 60, 1153.
69. Zang, S.; Dobson, G. R.; Brown, T. L. J. Am. Chem. Soc. 1991, 113, 6908.
70. Saillard, J.-Y.; Hoffmann, R. J. Am. Chem. Soc. 1984, 106, 2006.
71. Hartwig, J. F.; Muhoro, C. F.; He, X.; Eisenstein, O.; Bosque, R.; Maseras, F. J. Am. Chern. Soc. 1996, 118, 10936.
72. Muhoro, C. F.; Hartwig, J. F. Angew. Chem., Int. Ed. Engl. 1997, 36, 1510.
73. Muhoro, C. N.; He, X.; Hartwig, J. F. J. Am. Chem. Soc. 1999, 121, 5033.
74. Hall, C.; Perutz., R. N. Chem. Rev. 1996, 96, 3125.
75. Sun, X.-Z.; Grills, D. C; Nikiforov, S. M.; Poliakoff, M.; George, M. W. J. Am. Chem. Soc. 1997, 119, 7521.
76. Coordination of heptane to an iron-porphirin in the solid state has been suggested: Evans, D. R.; Drovetskaya, T.; Bau, R.; Reed, C. A.; Boyd, P. D. W. J. Am. Chem. Soc. 1997, 119, 3633.
77. Graham, M. A.; Poliakoff, M.; Turner, J. J. J. Chem. Soc. (A) 1971, 2939.
78. (a) Graham, M. A.; Perutz, R. N.; Poliakoff, M.; Turner, J. J. J. Organomet. Chem. 1972, 34, C34.
79. (b) Poliakoff, M.; Turner, J. J. J. Chem. Soc., Dalton Trans. 1974, 2276.
80. (c) Perutz, R. N.; Turner, J. J. J. Am. Chem. Soc. 1975, 97, 4791.
81. Schubert, U. J. Organomet. Chem. 1983, 205, 395.
82. Butts, M. D.; Bryan, J. C.; Luo, X.-L.; Kubas, G. J. Inong. Chem. 1997, 36, 3341.
83. Periana, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1986, 108, 7332.
84. Bullock, R. M.; Headford, C. E. L.; Kegley, S. E.; Norton, J. R. J. Am. Chem. Soc. 1985, 107, 727.
85. Gould, G. L.; Heinkey, D. M. J. Am. Chem. Soc. 1989, 111, 5502.
86. Gross, C. L.; Girolami, G. S. J. Am. Chem. Soc. 1998, 120, 6605.
87. Dobson, G. R.; Hodges, P. M.; Healy, M. A.; Poliakoff, M.; Turner, J. J.; Firth, S.; Asali, K. J. J. Am. Chem. Soc. 1987, 109, 4218.
88. Hewitt, F.; Holliday, A. K. J. Chem. Soc. 1953, 530.
89. International Tables for X-ray crystallography; Kynoch Press: Birmingham, 1974; vol. IV.
90. Stewart, R. F.; Davidson, R. E.; Simpson, W. T. J. Chem. Phys. 1965, 42, 3175.
91. Sakurai, T.; Kobayashi, M. Rikagaku Kenkyujo Hokoku 1979, 55, 69.