Methyltrioxorhenium catalyzed domino epoxidation-nucleophilic ring opening of glycals

Tetrahedron Letters

Volumn 44, Issue 30, 2003, Pages 5589-5592

  Soldaini, Gianluca ^a   Cardona, Francesca ^a   Goti, Andrea ^a  

^a UNIVERSITY OF FLORENCE   (Italy)

Author keywords

Catalysis; Glycosyl donors; Glycosyl phosphates; Ionic liquids; Methyltrioxorhenium; Oxidation

Indexed keywords

HYDROGEN PEROXIDE; METHYLTRIOXORHENIUM; PHOSPHORIC ACID DERIVATIVE; RHENIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; DIASTEREOISOMER; EPOXIDATION; GLYCOSYLATION; HYDROLYSIS; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; RING OPENING; ROOM TEMPERATURE; SYNTHESIS;

EID: 0037492320     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(03)01386-8     Document Type: Article

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35. 4. The solvent was removed under vacuum. The crude oil was dissolved in pyridine (1 mL) and acetic anhydride (0.5 mL) was added dropwise. After stirring at rt for 15 h the mixture was concentrated and the dibutyl glycosyl phosphates were collected by chromatography on silica gel.