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24
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85034143937
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note
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General procedure: 1.0 equiv of glycal, 1.5 equiv of 0.08 M dimethyldioxirane, 1.10 equiv of dialkyl phosphate, 1.5 equiv of pivaloyl chloride and 3.0 equiv of DMAP. All steps were carried out in dichloromethane unless noted otherwise.
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25
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For a review see: Danishefsky, S. J.; Bilodeau, M. T. Angew. Chem., Int. Ed. Engl. 1996, 35, 1380.
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