메뉴 건너뛰기




Volumn 64, Issue 19, 1999, Pages 7243-7245

Inexpensive and environmentally friendly oxidation of hydroxylamines to nitrones with bleach

Author keywords

[No Author keywords available]

Indexed keywords

HYDROXYLAMINE; HYPOCHLORITE SODIUM; NITRO DERIVATIVE; NITRONE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 0033578945     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo990417r     Document Type: Article
Times cited : (75)

References (44)
  • 8
    • 0038106171 scopus 로고    scopus 로고
    • (a) Bloch, R. Chem. Rev. 1998, 98, 1407-1438.
    • (1998) Chem. Rev. , vol.98 , pp. 1407-1438
    • Bloch, R.1
  • 10
    • 0001596517 scopus 로고
    • Pryor, W. A., Ed.; Academic Press: New York
    • (a) Janzen, E. G. In Free Radicals in Biology; Pryor, W. A., Ed.; Academic Press: New York, 1980; Vol. 4, pp 115-154.
    • (1980) Free Radicals in Biology , vol.4 , pp. 115-154
    • Janzen, E.G.1
  • 17
    • 24444449974 scopus 로고
    • Klamann, D.; Hagemann, H., Eds.; Georg Thieme Verlag: Stuttgart
    • (a) Döpp, D.; Döpp, H. In Houben-Weyl - Methoden der organischen Chemie, vol. E14b/Part 2; Klamann, D.; Hagemann, H., Eds.; Georg Thieme Verlag: Stuttgart, 1990.
    • (1990) Houben-Weyl - Methoden der Organischen Chemie , vol.E14B , Issue.2 PART
    • Döpp, D.1    Döpp, H.2
  • 28
    • 0344601558 scopus 로고    scopus 로고
    • note
    • 10 While the titer of bleach remained always in the range 3.5-4% during all the time of this study, we observed a dramatic decrease in the NaClO concentration of the 13% solution. Then, all the reactions with the more concentrated solution have been carried out at the same time with a 10.2% solution, immediately after titration. In our experience, the use of bleach is much more practical, requiring no titration providing that a 1.5-2-fold excess is used. On the other hand, it is advisable to titrate the 13% NaClO solution before its use: we are indebted to one referee for warning us about the rapid decline of its titer.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.