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Volumn 125, Issue 4, 2003, Pages 860-861

Competition between C-C and C-H insertion in prototype transition metal-hydrocarbon reactions

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CYCLOPROPANE; HYDROCARBON; HYDROGEN; METAL COMPLEX; MOLYBDENUM; NIOBIUM; YTTRIUM; ZIRCONIUM;

EID: 0037471663     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0278842     Document Type: Article
Times cited : (56)

References (20)
  • 8
    • 0003676669 scopus 로고
    • van Leeuwen P. W. N. M., Morokuma K., van Lenthe, J. H., Eds.; Kluwer Academic Publishers: Dordrecht
    • Siegbahn, P. E. M.; Blomberg, M. R. A. In Theoretical Aspects of Homogeneous Catalysis; van Leeuwen, P. W. N. M., Morokuma, K., van Lenthe, J. H., Eds.; Kluwer Academic Publishers: Dordrecht, 1995.
    • (1995) Theoretical Aspects of Homogeneous Catalysis
    • Siegbahn, P.E.M.1    Blomberg, M.R.A.2
  • 11
  • 15
    • 0013008256 scopus 로고    scopus 로고
    • note
    • For cation reactions, at least two stable species are formed prior to the rate-limiting step; thus, product branching ratios are complex functions of several potential energy barrier heights along each reaction coordinate.
  • 16
    • 0012967768 scopus 로고    scopus 로고
    • note
    • 4 was different for reactions of a given metal with cyclopropane and propene, and because C-C and C-H insertion barriers are larger than subsequent barriers, interconversion between C-C and C-H insertion complexes is insignificant.
  • 19
    • 0012967769 scopus 로고    scopus 로고
    • note
    • For Mo*, the potential energy barrier heights were both decreased by the electronic excitation energy, 30.8 kcal/mol.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.