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Analysis of these thresholds is performed as detailed in many previous papers. See for example: Tjelta, B. L.; Armentrout, P. B. J. Am. Chem. Soc. 1996, 118, 9652. Haynes, C. L.; Fisher, E. R.; Armentrout, P. B. J. Phys. Chem. 1996, 100, 18300.
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0000942525
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Analysis of these thresholds is performed as detailed in many previous papers. See for example: Tjelta, B. L.; Armentrout, P. B. J. Am. Chem. Soc. 1996, 118, 9652. Haynes, C. L.; Fisher, E. R.; Armentrout, P. B. J. Phys. Chem. 1996, 100, 18300.
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17344363186
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note
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2), one mass unit lower. Data acquired for this latter system were taken at somewhat lower mass resolution than those for the other systems.
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Literature thermochemistry for stable hydrocarbons is taken from the following: (a) Pedley, J. B.; Naylor, R. D.; Kirby, S. P. Thermochemical Data of Organic Compounds, 2nd ed.; Chapman and Hall: New York, 1986. Correction to 0 K values is achieved using information in the following: Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. J. Phys. Chem. Ref. Data 1985, 14 (No. 1). (b) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
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17344366551
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Literature thermochemistry for stable hydrocarbons is taken from the following: (a) Pedley, J. B.; Naylor, R. D.; Kirby, S. P. Thermochemical Data of Organic Compounds, 2nd ed.; Chapman and Hall: New York, 1986. Correction to 0 K values is achieved using information in the following: Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. J. Phys. Chem. Ref. Data 1985, 14 (No. 1). (b) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
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17344363820
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17344373530
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3 points to initial primary C-H insertion as the dominant process for methane loss (Table 2), as previously discussed in the text. No isotope effect is expected from initial primary insertion if a MCTS is involved.
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