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Volumn 120, Issue 23, 1998, Pages 5704-5712

Reactions of ground-state Ti+ and V+ with propane: Factors that govern C-H and C-C bond cleavage product branching ratios

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; DEUTERIUM; ETHYLENE; METHANE; PROPANE; TITANIUM;

EID: 0032540652     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja974372s     Document Type: Article
Times cited : (61)

References (64)
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    • note
    • +, in its reaction with propane, especially when competing with the tight transition state needed for product formation.
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    • Analysis of these thresholds is performed as detailed in many previous papers. See for example: Tjelta, B. L.; Armentrout, P. B. J. Am. Chem. Soc. 1996, 118, 9652. Haynes, C. L.; Fisher, E. R.; Armentrout, P. B. J. Phys. Chem. 1996, 100, 18300.
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    • Tjelta, B.L.1    Armentrout, P.B.2
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    • 0000942525 scopus 로고    scopus 로고
    • Analysis of these thresholds is performed as detailed in many previous papers. See for example: Tjelta, B. L.; Armentrout, P. B. J. Am. Chem. Soc. 1996, 118, 9652. Haynes, C. L.; Fisher, E. R.; Armentrout, P. B. J. Phys. Chem. 1996, 100, 18300.
    • (1996) J. Phys. Chem. , vol.100 , pp. 18300
    • Haynes, C.L.1    Fisher, E.R.2    Armentrout, P.B.3
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    • note
    • 2), one mass unit lower. Data acquired for this latter system were taken at somewhat lower mass resolution than those for the other systems.
  • 45
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    • Freiser, B. S., Ed.; Kluwer Academic Publishers: The Netherlands
    • Armentrout, P. B.; Kickel, B. L. In Organometallic Ion Chemistry; Freiser, B. S., Ed.; Kluwer Academic Publishers: The Netherlands, 1996; p 1.
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    • Freiser, B. S., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands
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    • Literature thermochemistry for stable hydrocarbons is taken from the following: (a) Pedley, J. B.; Naylor, R. D.; Kirby, S. P. Thermochemical Data of Organic Compounds, 2nd ed.; Chapman and Hall: New York, 1986. Correction to 0 K values is achieved using information in the following: Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. J. Phys. Chem. Ref. Data 1985, 14 (No. 1). (b) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
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    • Literature thermochemistry for stable hydrocarbons is taken from the following: (a) Pedley, J. B.; Naylor, R. D.; Kirby, S. P. Thermochemical Data of Organic Compounds, 2nd ed.; Chapman and Hall: New York, 1986. Correction to 0 K values is achieved using information in the following: Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. J. Phys. Chem. Ref. Data 1985, 14 (No. 1). (b) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
    • (1985) J. Phys. Chem. Ref. Data , vol.14 , Issue.1
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  • 51
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    • Literature thermochemistry for stable hydrocarbons is taken from the following: (a) Pedley, J. B.; Naylor, R. D.; Kirby, S. P. Thermochemical Data of Organic Compounds, 2nd ed.; Chapman and Hall: New York, 1986. Correction to 0 K values is achieved using information in the following: Chase, M. W., Jr.; Davies, C. A.; Downey, J. R., Jr.; Frurip, D. J.; McDonald, R. A.; Syverud, A. N. J. Phys. Chem. Ref. Data 1985, 14 (No. 1). (b) Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. L.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
    • (1988) J. Phys. Chem. Ref. Data , vol.17 , Issue.SUPPL. 1
    • Lias, S.G.1    Bartmess, J.E.2    Liebman, J.F.3    Holmes, J.L.4    Levin, R.D.5    Mallard, W.G.6
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    • note
    • 3 points to initial primary C-H insertion as the dominant process for methane loss (Table 2), as previously discussed in the text. No isotope effect is expected from initial primary insertion if a MCTS is involved.
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    • Kluwer Academic Publishers: Dordrecht, The Netherlands; Metal-Ligand Bond Dissociation Energies table
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    • Freiser, B.S.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.