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3 is carried out at 200 °C for 17 h with a difunctional base, but no further product characterization was reported in this particular case
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Recently, this catalytic dehydrocoupling method was extended to amine-borane adducts to form cyclic products: Jaska, C. A.; Temple, K.; Lough, A. J.; Manners, I. Chem. Commun. 2001, 962.
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For a brief discussion of the influence of P-H bond polarity on dehydrocoupling see: Dorn, H.; Veizovic, E.; Lough, A.J.; Manners, I. Inorg. Chem. 2001, 40, 4327.
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0013061831
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Polyphosphinoboranes 2 and 4 are gums and are therefore also essentially amorphous.
-
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58
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0013067597
-
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note
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No thermal transitions were detected for polymer 1 in the range of 25-150 °C.
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59
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0013067598
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note
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2O) loss. Drying these materials is challenging compared to 1 as they are gums.
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62
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0013067599
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note; unpublished results
-
2 gave boron phosphide (BP) as a major crystalline component of the ceramic material by powder X-ray diffraction. Full details of our studies in this area will be reported elsewhere: Dorn, H.; Ginzburg, M.; Manners, I., unpublished results.
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Dorn, H.1
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0013108828
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n directly from secondary phosphine-borane adducts have so far been unsuccessful and only cyclic or short chain species results. See refs 20 and 22.
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