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Volumn 36, Issue 2, 2003, Pages 291-297

Synthesis, characterization, and properties of the polyphosphinoboranes [RPH-BH2]n (R = Ph, iBu, p-nBuC6H4, p-dodecylC6H4): Inorganic Polymers with a phosphorus-boron backbone

Author keywords

[No Author keywords available]

Indexed keywords

DEHYDROCOUPLING; POLYPHOSPHINOBORANES; WIDE ANGLE X RAY SCATTERING;

EID: 0037469282     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma021447q     Document Type: Article
Times cited : (104)

References (68)
  • 26
    • 0035941073 scopus 로고    scopus 로고
    • (c) Manners, I. Science 2001, 294, 1664.
    • (2001) Science , vol.294 , pp. 1664
    • Manners, I.1
  • 39
    • 0001630856 scopus 로고
    • note
    • n with molecular weights of 1800-6000 (where determined): (a) Burg, A. B.; Wagner, R. I. J. Am. Chem. Soc. 1953, 75, 3872.
    • (1953) J. Am. Chem. Soc. , vol.75 , pp. 3872
    • Burg, A.B.1    Wagner, R.I.2
  • 41
    • 0001035628 scopus 로고
    • 3 is carried out at 200 °C for 17 h with a difunctional base, but no further product characterization was reported in this particular case
    • (1959) J. Inorg. Nucl. Chem. , vol.11 , pp. 258
    • Burg, A.B.1
  • 42
    • 0013112831 scopus 로고
    • U.S. Patent 3,071,553
    • Burg, A. B.; Wagner, R. I. U.S. Patent 3,071,553, 1963.
    • (1963)
    • Burg, A.B.1    Wagner, R.I.2
  • 43
    • 0001637403 scopus 로고
    • note
    • (d) For a more recent review on phosphinoborane chemistry see, Paine, R. T.; Nöth, H. Chem. Rev. 1995, 95, 343.
    • (1995) Chem. Rev. , vol.95 , pp. 343
    • Paine, R.T.1    Nöth, H.2
  • 47
  • 57
    • 0013061831 scopus 로고    scopus 로고
    • note
    • Polyphosphinoboranes 2 and 4 are gums and are therefore also essentially amorphous.
  • 58
    • 0013067597 scopus 로고    scopus 로고
    • note
    • No thermal transitions were detected for polymer 1 in the range of 25-150 °C.
  • 61
    • 0013067598 scopus 로고    scopus 로고
    • note
    • 2O) loss. Drying these materials is challenging compared to 1 as they are gums.
  • 62
    • 0013067599 scopus 로고    scopus 로고
    • note; unpublished results
    • 2 gave boron phosphide (BP) as a major crystalline component of the ceramic material by powder X-ray diffraction. Full details of our studies in this area will be reported elsewhere: Dorn, H.; Ginzburg, M.; Manners, I., unpublished results.
    • Dorn, H.1    Ginzburg, M.2    Manners, I.3
  • 66
    • 0013108828 scopus 로고    scopus 로고
    • note
    • n directly from secondary phosphine-borane adducts have so far been unsuccessful and only cyclic or short chain species results. See refs 20 and 22.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.