Component stress-strain behavior and small-angle neutron scattering investigation of stereoblock elastomeric polypropylene

Macromolecules

Volumn 36, Issue 4, 2003, Pages 1178-1187

  Wiyatno, Willy ^a   Fuller, Gerald G ^a   Pople, John A ^b   Gast, Alice P ^c   Chen, Zhong Ren ^d   Waymouth, Robert M ^d   Myers, Charles L ^e  

^a Stanford University   (United States)

^b SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^c Massachusetts Institute of Technology Cambridge   (United States)

^d STANFORD UNIVERSITY   (United States)

^e NONE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BLENDING; CATALYSTS; COOLING; CRYSTALLIZATION; ELASTICITY; ELASTOMERS; HEPTANE; NEUTRON SCATTERING; REACTION KINETICS; SOLVENTS; STRAIN; STRESS ANALYSIS; THERMAL EFFECTS;

SMALL-ANGLE NEUTRON SCATTERING (SANS);

POLYPROPYLENES;

EID: 0037465571     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma020477q     Document Type: Article

References (80)

1. Jebens, A. Polypropylene Resins; SRI International: Menlo Park, CA, 1997.
2. Natta, G.; Mazzanti, G.; Crespi, G.; Moraglio, G. Chim. Ind. 1957, 39, 275-283.
3. Natta, G. J. Polym. Sci. 1959, 34, 531-549.
4. Collette, J. W.; Ovenall, D. W.; Buck, W. H.; Ferguson, R. C. Macromolecules 1989, 22, 3858-3866.
5. Collette, J. W.; Tullock, C. W. US Patent 4,335,225, 1982.
6. Collette, J. W.; Tullock, C. W.; MacDonald, R. N.; Buck, W. H.; Su, A. C. L.; Harrel, J. R.; Mulhaupt, R.; Anderson, B. C. Macromolecules 1989, 22, 3851-3858.
7. Tullock, C. W.; Tebbe, F. N.; Mulhaupt, R.; Ovenall, D. W.; Setterquist, R. A.; Ittel, S. D. J. Polym. Sci, Part A: Polym. Chem. 1989, 27, 3063-3081.
8. Ittel, S. D. J. Macromol. Sci. Chem. 1990, A27, 9-11.
9. Tullock, C. W.; Mulhaupt, R.; Ittel, S. D. Makromol. Chem., Rapid Commun. 1989, 10, 19-23.
10. Job, R. C.; Haas, D. F. US Patent 5,118,768, 1992.
11. Job, R. C. US Patent 5,089,573, 1992.
12. Chen, R.; Xie, M. R.; Wu, Q.; Lin, S. G. J. Polym. Sci., Part A: Polym. Chem. 2000, 38, 411-415.
13. Kuhl, O.; Koch, T.; Somoza, F. B.; Junk, P. C.; Hey-Hawkins, E.; Plat, D.; Eisen, M. S. J. Organomet. Chem. 2000, 604, 116-125.
14. Longo, P.; Amendola, A. G.; Fortunato, E.; Boccia, A. C.; Zambelli, A, Macromol. Rapid Commun. 2001, 22, 339-344.
15. Mansel, S.; Perez, E.; Benavente, R.; Perena, J. M.; Bello, A.; Roll, W.; Kirsten, R.; Beck, S.; Brintzinger, H. H. Macromol. Chem. Phys. 1999, 200, 1292-1297.
16. Nedorezova, P. M.; Tsvetkova, V. I.; Bravaya, N. M.; Savinov, D. V.; Optov, V. A. Polym. Sci. Ser. A 2000, 42, 573-579.
17. Schmidt, R.; Alt, H. G. J. Organomet. Chem. 2001, 621,304-309.
18. Yoon, J. S.; Lee, Y. S.; Park, E. S.; Lee, I. M.; Park, D. K.; Jung, S. O. Eur. Polym. J. 2000, 36, 1271-1275.
19. Resconi, L.; Piemontesi, F.; Lin-Chen, Y. US Patent 5,747,621, 1998.
20. Sassmannshausen, J.; Bochmann, M.; Rosch, J.; Lilge, D. J. Organomet. Chem. 1997, 548, 23-28.
21. Chien, J. C. W.; Llinas, G. H.; Rausch, M. D.; Lin, Y. G.; Winter, H. H.; Atwood, J. L.; Bott, S. G. J. Polym. Sci., Part A: Polym. Chem. 1992, 30, 2601-2617.
22. Mallin, D. T.; Rausch, M. D.; Lin, Y. G.; Dong, S.; Chien, J. C. W. J. Am. Chem. Soc. 1990, 112, 2030-2031.
23. Llinas, G. H.; Dong, S. H.; Mallin, D. T.; Rausch, M. D.; Lin, Y. G.; Winter, H. H.; Chien, J. C. W. Macromolecules 1992, 25, 1242-1253.
24. Chien, J. C. W.; Llinas, G. H.; Rausch, M. D.; Lin, G. Y.; Winter, H. H.; Atwood, J. L.; Bott, S. G. J. Am. Chem. Soc. 1991, 113, 8569-8570.
25. Cheng, H. N.; Babu, G. N.; Newmark, R. A.; Chien, J. C. W. Macromolecules 1992, 25, 6980-6987.
26. Gauthier, W. J.; Corrigan, J. F.; Taylor, N. J.; Collins, S. Macromolecules 1995, 28, 3771-3778.
27. Gauthier, W. J.; Collins, S. Macromolecules 1995, 28, 3779-3786.
28. Bravakis, A. M.; Bailey, L. E.; Pigeon, M.; Collins, S. Macromolecules 1998, 31, 1000-1009.
29. Dietrich, U.; Hackmann, M.; Rieger, B.; Klinga, M.; Leskelae, M. J. Am. Chem. Soc. 1999, 121, 4348-4355.
30. Kukral, J.; Lehmus, P.; Feifel, T.; Troll, C.; Rieger, B. Organometallics 2000, 19, 3767-3775.
31. Dreier, T.; Erker, G.; Froehlich, R.; Wibbeling, B. Organometallics 2000, 19, 4095-4103.
32. Coates, G. W.; Waymouth, R. M. Science 1995, 267, 217-219.
33. Hauptman, E.; Waymouth, R. M.; Ziller, J. W. J. Am. Chem. Soc. 1995, 117, 11586-11587.
34. Bruce, M. D.; Coates, G. W.; Hauptman, E.; Waymouth, R. M.; Ziller, J. W. J. Am. Chem. Soc. 1997, 119, 11174-11182.
35. Kravchenko, R.; Masood, A.; Waymouth, R. M. Organometallics 1997, 16, 3635-3639.
36. Petoff, J. L. M.; Bruce, M. D.; Waymouth, R. M.; Masood, A.; Lal, T. K.; Quan, R. W.; Behrend, S. J. Organometallics 1997, 16, 5909-5916.
37. Bruce, M. D.; Waymouth, R. M. Macromolecules 1998, 31, 2707-2715.
38. Carlson, E. D.; Krejchi, M. T.; Shah, C. D.; Terakawa, T.; Waymouth, R. M.; Fuller, G. G. Macromolecules 1998, 31, 5343-5351.
39. Hu, Y. R.; Krejchi, M. T.; Shah, C. D.; Myers, C. L.; Waymouth, R. M. Macromolecules 1998, 31, 6908-6916.
40. Kravchenko, R.; Masood, A.; Waymouth, R. M.; Myers, C. L. J. Am. Chem. Soc. 1998, 120, 2039-2046.
41. Kravchenko, R.; Waymouth, R. M. Macromolecules 1998, 31, 1-6.
42. Lin, S.; Hauptman, E.; Lal, T. K.; Waymouth, R. M.; Quan, R. W.; Ernst, A. B. J. Mol. Catal. A: Chem. 1998, 136, 23-33.
43. Petoff, J. L. M.; Agoston, T.; Lal, T. K.; Waymouth, R. M. J. Am. Chem. Soc. 1998, 120, 11316-11322.
44. Waymouth, R. M.; Kravchenko, R.; Bendig, L. L.; Moore, E. J.; Myers, C. L.; Quan, R. W.; Ernst, A. B. US Patent 6,160,064, 2000.
45. Witte, P.; Lal, T. K.; Waymouth, R. M. Organometallics 1999, 18, 4147-4155.
46. Carlson, E. D.; Fuller, G. G.; Waymouth, R. M. Macromolecules 1999, 32, 8100-8106.
47. Carlson, E. D.; Fuller, G. G.; Waymouth, R. M. Macromelecules 1999, 32, 8094-8099.
48. Hu, Y. R.; Carlson, E. D.; Fuller, G. G.; Waymouth, R. M. Macromolecules 1999, 32, 3334-3340.
49. Lin, S.; Waymouth, R. M. Macromolecules 1999, 32, 8283-8290.
50. Petoff, J. L. M.; Myers, C. L.; Waymouth, R. M. Macromolecules 1999, 32, 7984-7989.
51. Tagge, C. D.; Kravchenko, R. L.; Lal, T. K.; Waymouth, R. M. Organometallics 1999, 18, 380-388.
52. Boue, F. Adv. Polym. Sci. 1987, 82, 47-101.
53. Lohse, D. J. Rubber Chem. Technol. 1994, 67, 367-383.
54. Zirkel, A.; Urban, V.; Richter, D.; Fetters, L. J.; Huang, J. S.; Kampmann, R.; Hadjichristidis, N. Macromolecules 1992, 25, 6148-6155.
55. (a) Wiyatno, W.; Pople, J. A.; Gast, A. P.; Waymouth, R. M.; Fuller, G. G. Macromolecules 2002 35, 8488-8497.
56. (b) Wiyatno, W.; Pople, J. A.; Gast, A. P.; Waymouth, R. M.; Fuller, G. G. Macromolecules 2002 35, 8498-8508.
57. Wiyatno, W.; Chen, Z.-R.; Liu, Y.; Waymouth, R. M.; Krukonis, V.; Brennan, K. submitted to Macromolecules 2002.
58. Wunderlich, B. Macromolecular Physics; Academic Press: New York, 1976. Vol. 2: Crystal Nucleation, Growth, Annealing.
59. Daoud, M.; Cotton, J. P.; Farnoux, B.; Jannink, G.; Sarma, G.; Benoit, H.; Duplessix, R.; Picot, C.; Gennes, P. G. D. Macromolecules 1975, 8, 804-818.
60. Maconnachie, A.; Richards, R. W. Polymer 1978, 19, 739-762.
61. Hayashi, H.; Flow, P. J.; Wignall, G. D. Macromolecules 1983, 16, 1328-1335.
62. De Gennes, P. G. Scaling Concepts in Polymer Physics; Cornell University Press: Ithaca, NY, 1979.
63. Glatter, O.; Kratky, O.; Editors. Small-Angle X-ray Scattering; Academic Press: New York, 1982.
64. Debye, P. J. Phys. Colloid Chem. 1947, 51, 18-32.
65. Wignall, G. D. Encycl. Polym. Sci. Eng. 1987, 10, 112-184.
66. Alamo, R. G.; Londono, J. D.; Mandelkern, L.; Stehling, F. C.; Wignall, G. D. Macromolecules 1994, 27, 411-417.
67. Bassett, D. C.; Editor. Developments in Crystalline Polymers- 2; Kluwer Academic Publishers, Dordrecht, The Netherlands, 1988.
68. Pople, J. A.; Mitchell, G. R. Liq. Cryst. 1997, 23, 467-473.
69. Lacey, D.; Beattie, H. N.; Mitchell, G. R.; Pople, J. A. J. Mater. Chem. 1998, 8, 53-60.
70. Pople, J. A.; Mitchell, G. R.; Chai, C. K. Polymer 1996, 37, 4187-4191.
71. Myers, C. A.; Allen, C.; Ernst, A.; Naim, H. Society of Plastics Engineers (SPE) Conference Proceedings; Society of Plastics Engineers (SPE) New York, 1999; Vol. 55, Session M10.
72. The tensile properties were also tested on compression-molded samples retained for i year at room temperature. The tensile properties of the 1-year-old samples were very similar to those tested 1 day after compression molding.
73. Schonherr, H.; Wiyatno, W.; Pople, J. A.; Frank, C. W.; Fuller, G. G.; Gast, A. P.; Waymouth, R. M. Macromolecules 2002, 35.
74. Alamo, R. G.; Graessley, W. W.; Krishnamoorti, R.; Lohse, D. J.; Londono, J. D.; Mandelkern, L.; Stehling, F. C.; Wignall, G. D. Macromolecules 1997, 30, 561-566.
75. Debye, P.; Anderson, H. R., Jr.; Brumberger, H. J. Appl. Phys. 1957, 28, 679-683.
76. Debye, P.; Bueche, A. M. J. Appl. Phys. 1949, 20, 518-525.
77. Wignall, G. D.; Alamo, R. G.; Londono, J. D.; Mandelkern, L.; Kim, M. H.; Lin, J. S.; Brown, G. M. Macromolecules 2000, 33, 551-561.
78. Wignall, G. D.; Londono, J. D.; Lin, J. S.; Alamo, R. G.; Galante, M. J.; Mandelkern, L. Macromolecules 1995, 28, 3156-3167.
79. Seki, M.; Nakano, H.; Yamauchi, S.; Suzuki, J.; Matsushita, Y. Macromolecules 1999, 32, 3227-3234.
80. The order parameters of dES-ePP cannot be directly compared to those of dHI-ePP because the d-ES fraction, unlike its d-HS and d-HI counterparts, is not homogeneously distributed within ePP-10 in its semicrystalline form at 25°C. Nevertheless, there is some constraint that prevents the d-ES fraction from relaxing when held at strain, and therefore, some cooperative behavior between the d-ES fraction and its host matrix.