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85034560823
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note
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Ferrocenecarboxylic acid was synthesized from lithioferrocene and dry ice.
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85034559242
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The preliminary X-ray structure of M4 indicates that it also crystallizes in the rac conformation with both enantiomers in the unit cell. Unfortunately, disorder in the crystal structure prevents a more detailed comparison of the structures.
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31
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85034542007
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note
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The presence of some of the free ligand in the sample of metallocene M3 may have resulted in an underestimation of the productivity of this catalyst.
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32
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85034559851
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note
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The broad molecular weight distributions appear to be a general trend for unbridged 2-arylindene catalysts that yield polymers of intermediate isotacticity. For the polymers reported here, the GPC traces are monomodal for all catalysts except M2, which shows a shoulder on the high-molecular-weight end of the distribution. The origin of these broad molecular weight distributions is not clear but is the subject of ongoing investigations,
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33
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85034540800
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note
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For random (atactic) polypropylene, [mmmm] = 6%; for pure isotactic polypropylene, [mmmm] = 100%.
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For highly isotactic polypropylene the IR index approaches unity.
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85034533703
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note
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Because the remaining solvent in the isolated solid could not be removed in vacuo, elemental analyses were off in carbon about 3%.
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