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For related work on elastomeric polypropylene see: (a) Collette, J. W.; Tullock, C. W.; MacDonald, R. N.; Buck, W. H.; Su, A. C. L.; Harrel, J. R.; Mulhaupt, R.; Anderson, B. C. Macromolecules 1989, 22, 3851-3858. (b) Mallin, D. T.; Rausch, M. D.; Lin, Y. G.; Dong, S.; Chien, J. C. W. J. Am. Chem. Soc. 1990, 112, 2030-2031. (c) Gauthier, W. J.; Corrigan, J. F.; Taylor, N. J.; Collins, S. Macromolecules 1995, 28, 3771-3778.
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For related work on elastomeric polypropylene see: (a) Collette, J. W.; Tullock, C. W.; MacDonald, R. N.; Buck, W. H.; Su, A. C. L.; Harrel, J. R.; Mulhaupt, R.; Anderson, B. C. Macromolecules 1989, 22, 3851-3858. (b) Mallin, D. T.; Rausch, M. D.; Lin, Y. G.; Dong, S.; Chien, J. C. W. J. Am. Chem. Soc. 1990, 112, 2030-2031. (c) Gauthier, W. J.; Corrigan, J. F.; Taylor, N. J.; Collins, S. Macromolecules 1995, 28, 3771-3778.
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Chien, J.C.W.5
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For related work on elastomeric polypropylene see: (a) Collette, J. W.; Tullock, C. W.; MacDonald, R. N.; Buck, W. H.; Su, A. C. L.; Harrel, J. R.; Mulhaupt, R.; Anderson, B. C. Macromolecules 1989, 22, 3851-3858. (b) Mallin, D. T.; Rausch, M. D.; Lin, Y. G.; Dong, S.; Chien, J. C. W. J. Am. Chem. Soc. 1990, 112, 2030-2031. (c) Gauthier, W. J.; Corrigan, J. F.; Taylor, N. J.; Collins, S. Macromolecules 1995, 28, 3771-3778.
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w with a much broader PDI in order to encompass both the isotactic and atactic only distributions. See: Coleman, B. D.; Fox, T. G. J. Am. Chem. Soc., 1963, 85, 1241-1244.
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1842271790
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note
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A higher average active site concentration for hafnium might result from a slower rate of inactivation of hafnium catalysts sites over the course of the polymerization reaction.
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25
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1842310297
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note
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At 75 psig, 20°C, the productivity of 1 is 1480 kg of PP/mol of Zr. This corresponds to 9.78 insertions/s.
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SHELXTL
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SHELXTL.
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31
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1842390284
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UCLA Crystallographic Computing Package
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UCLA Crystallographic Computing Package.
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