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Bravakis, A. M.; Baily, L. E.; Pigeon, M.; Collins, S. Macromolecules 1998, 31, 1000-1009. Gauthier, W. J.; Corrigan, J. F.; Taylor, N. J.; Collins, S. Macromolecules 1995, 28, 3771-3778.
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Studies of Waymouth et al. on the unbridged bis(2-phenylindenyl)-zirconocene dichloride showed the possibility of producing thermoplastic polypropene elastomers. For references, see, e.g.: (a) Coates, G. W.; Waymouth, R. M. Science 1995, 267, 217-219. (b) Bruce, M. D.; Coates, G. W.; Hauptmann, E.; Waymouth, R. M.; Ziller, J. W. J. Am. Chem. Soc. 1997, 119, 11174-11182. (c) Tsvetkova, V. I.; Nedorezova, P. M.; Bravaya, N. M.; Savinov, D. V. Dubnikova, I. L.; Optov, V. A. Polym. Sci., Ser. A 1997, 39 (3), 235-240 and literature cited there.
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Waymouth, R.M.2
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1842299890
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Studies of Waymouth et al. on the unbridged bis(2-phenylindenyl)- zirconocene dichloride showed the possibility of producing thermoplastic polypropene elastomers. For references, see, e.g.: (a) Coates, G. W.; Waymouth, R. M. Science 1995, 267, 217-219. (b) Bruce, M. D.; Coates, G. W.; Hauptmann, E.; Waymouth, R. M.; Ziller, J. W. J. Am. Chem. Soc. 1997, 119, 11174-11182. (c) Tsvetkova, V. I.; Nedorezova, P. M.; Bravaya, N. M.; Savinov, D. V. Dubnikova, I. L.; Optov, V. A. Polym. Sci., Ser. A 1997, 39 (3), 235-240 and literature cited there.
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Bruce, M.D.1
Coates, G.W.2
Hauptmann, E.3
Waymouth, R.M.4
Ziller, J.W.5
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13
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0031287411
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and literature cited there
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Studies of Waymouth et al. on the unbridged bis(2-phenylindenyl)- zirconocene dichloride showed the possibility of producing thermoplastic polypropene elastomers. For references, see, e.g.: (a) Coates, G. W.; Waymouth, R. M. Science 1995, 267, 217-219. (b) Bruce, M. D.; Coates, G. W.; Hauptmann, E.; Waymouth, R. M.; Ziller, J. W. J. Am. Chem. Soc. 1997, 119, 11174-11182. (c) Tsvetkova, V. I.; Nedorezova, P. M.; Bravaya, N. M.; Savinov, D. V. Dubnikova, I. L.; Optov, V. A. Polym. Sci., Ser. A 1997, 39 (3), 235-240 and literature cited there.
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Nedorezova, P.M.2
Bravaya, N.M.3
Savinov, D.V.4
Dubnikova, I.L.5
Optov, V.A.6
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14
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33947463460
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The terms "δ-forward" and "λ-backward" refer to the conformation of twisted metallacycles; for definitions and closer discussion, cf.: (a) Corey, E. J.; Bailar, J. C., Jr. J. Am. Chem. Soc. 1959, 81, 2620. (b) Rieger, B.; Jany, G.; Fawzi, R.; Steimann, M. Organometallics 1994, 13, 647-653.
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Corey, E.J.1
Bailar J.C., Jr.2
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0009812621
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The terms "δ-forward" and "λ-backward" refer to the conformation of twisted metallacycles; for definitions and closer discussion, cf.: (a) Corey, E. J.; Bailar, J. C., Jr. J. Am. Chem. Soc. 1959, 81, 2620. (b) Rieger, B.; Jany, G.; Fawzi, R.; Steimann, M. Organometallics 1994, 13, 647-653.
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Jany, G.2
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0344118390
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EP 0519237, priority 18.06.1991
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(a) Roll, W.; Karl, E.; Brintzinger, H. H.; Stehling, U.; Rieger, B. EP 0519237, priority 18.06.1991.
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Roll, W.1
Karl, E.2
Brintzinger, H.H.3
Stehling, U.4
Rieger, B.5
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18
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33748245136
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(b) Spaleck, W.; Antberg, A.; Rohrmann, J.; Winter, A.; Bachmann B.; Kiprof, P., Behm, J.; Herrmann, W. A. Angew. Chem., Int. Ed. Engl. 1992, 31, 1347.
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Spaleck, W.1
Antberg, A.2
Rohrmann, J.3
Winter, A.4
Bachmann, B.5
Kiprof, P.6
Behm, J.7
Herrmann, W.A.8
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19
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33751157397
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The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
-
(1994)
Organometallics
, vol.13
, pp. 954-963
-
-
Spaleck, W.1
Küber, F.2
Winter, A.3
Rohrmann, J.4
Bachmann, B.5
Antberg, M.6
Dolle, V.7
Paulus, E.F.8
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20
-
-
0001354354
-
-
DE 41 04 931, priority 18.02.1991
-
The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
-
-
-
Erker, G.1
Nolte, R.2
Aulbach, M.3
Weiss, A.4
Reuschling, D.5
Rohrmann, J.6
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21
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-
0001354354
-
-
EP 0 537 686, priority 15.10.1991
-
The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
-
-
-
Winter, A.1
Antberg, M.2
Dolle, V.3
Rohrmann, J.4
Spaleck, W.5
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22
-
-
0011622541
-
-
The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
-
(1994)
Organometallics
, vol.13
, pp. 964-970
-
-
Stehling, U.1
Diebold, J.2
Kirsten, R.3
Röll, W.4
Brintzinger, H.H.5
Jüngling, S.6
Mühlhaupt, R.7
Langhauser, F.8
-
23
-
-
0001354354
-
-
EP 0 545 304, priority 30.11.1991
-
The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
-
-
-
Rohrmann, J.1
Küber, F.2
-
24
-
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0001354354
-
-
The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
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Kaminksky, W.1
Rabe, O.2
Schauwienold, A.-M.3
Schupfner, G.U.4
Hanss, J.5
Kopf, J.6
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25
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0343865902
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For the use of methacrylic acid bromide and cycloalkenes in similar reactions, cf.: Hacini, S.; Pardo, R.; Santelli, M. Tetrahedron Lett. 1979, 47, 4553-4556.
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25544443002
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DE 19624828, priority 09.07.1996
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Süling, C.; Gregorius, H.; Dobler, W.; Hingmann, R.; Rieger, B.; Dietrich, U.; Wagner, J. M.; Müller, H. J. DE 19624828, priority 09.07.1996.
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Süling, C.1
Gregorius, H.2
Dobler, W.3
Hingmann, R.4
Rieger, B.5
Dietrich, U.6
Wagner, J.M.7
Müller, H.J.8
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27
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25544463698
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DE 19634684, priority 12.09.1996
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Müller, H. J.; Trübenbach, P.; Rieger, B.; Wagner, J. M.; Dietrich, U. DE 19634684, priority 12.09.1996.
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Müller, H.J.1
Trübenbach, P.2
Rieger, B.3
Wagner, J.M.4
Dietrich, U.5
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28
-
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0031186811
-
-
Tetrahydrobenz[e]indene was already published before by Brintzinger's group. However, their route using α-bromoisobutyric acid bromide led to a mixture of angular and linear products with 55 and 30% yields, respectively; cf.: Schneider, N.; Huttenloch, M. E.; Stehling, U.; Kirsten, R.; Schaper, F.; Brintzinger, H. H. Organometallics 1997, 16, 3413-3420.
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Schneider, N.1
Huttenloch, M.E.2
Stehling, U.3
Kirsten, R.4
Schaper, F.5
Brintzinger, H.H.6
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29
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0344118384
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The "angular" 4,5-substituted isomer is only formed in traces
-
The "angular" 4,5-substituted isomer is only formed in traces.
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0000221146
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Rieger, B.; Fawzi, R.; Steimann, M. Chem. Ber. 1992, 125, 2373-2377.
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