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Volumn 121, Issue 18, 1999, Pages 4348-4355

Control of stereoerror formation with high-activity 'dual-side' zirconocene catalysts: A novel strategy to design the properties of thermoplastic elastic polypropenes

Author keywords

[No Author keywords available]

Indexed keywords

POLYMER; POLYPROPYLENE; UNCLASSIFIED DRUG; ZIRCONIUM DERIVATIVE; ZIRCONOCENE;

EID: 0033549090     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9833220     Document Type: Article
Times cited : (175)

References (50)
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    • and literature cited there
    • Studies of Waymouth et al. on the unbridged bis(2-phenylindenyl)- zirconocene dichloride showed the possibility of producing thermoplastic polypropene elastomers. For references, see, e.g.: (a) Coates, G. W.; Waymouth, R. M. Science 1995, 267, 217-219. (b) Bruce, M. D.; Coates, G. W.; Hauptmann, E.; Waymouth, R. M.; Ziller, J. W. J. Am. Chem. Soc. 1997, 119, 11174-11182. (c) Tsvetkova, V. I.; Nedorezova, P. M.; Bravaya, N. M.; Savinov, D. V. Dubnikova, I. L.; Optov, V. A. Polym. Sci., Ser. A 1997, 39 (3), 235-240 and literature cited there.
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    • Tsvetkova, V.I.1    Nedorezova, P.M.2    Bravaya, N.M.3    Savinov, D.V.4    Dubnikova, I.L.5    Optov, V.A.6
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    • 33751157397 scopus 로고
    • The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
    • (1994) Organometallics , vol.13 , pp. 954-963
    • Spaleck, W.1    Küber, F.2    Winter, A.3    Rohrmann, J.4    Bachmann, B.5    Antberg, M.6    Dolle, V.7    Paulus, E.F.8
  • 20
    • 0001354354 scopus 로고    scopus 로고
    • DE 41 04 931, priority 18.02.1991
    • The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
    • Erker, G.1    Nolte, R.2    Aulbach, M.3    Weiss, A.4    Reuschling, D.5    Rohrmann, J.6
  • 21
    • 0001354354 scopus 로고    scopus 로고
    • EP 0 537 686, priority 15.10.1991
    • The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
    • Winter, A.1    Antberg, M.2    Dolle, V.3    Rohrmann, J.4    Spaleck, W.5
  • 22
    • 0011622541 scopus 로고
    • The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
    • (1994) Organometallics , vol.13 , pp. 964-970
    • Stehling, U.1    Diebold, J.2    Kirsten, R.3    Röll, W.4    Brintzinger, H.H.5    Jüngling, S.6    Mühlhaupt, R.7    Langhauser, F.8
  • 23
    • 0001354354 scopus 로고    scopus 로고
    • EP 0 545 304, priority 30.11.1991
    • The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
    • Rohrmann, J.1    Küber, F.2
  • 24
    • 0001354354 scopus 로고    scopus 로고
    • The synthesis of indene leading structures (2,4-substituted indenes) in clean reactions and high yields is still a challenge. For other approaches, see the following. 4-Phenyl-2-methylindene: (a) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954-963. Reaction of γ-diketo derivatives with cyclopentadiene(s): (b) Erker, G.; Nolte, R.; Aulbach, M.; Weiss, A.; Reuschling, D.; Rohrmann, J. DE 41 04 931, priority 18.02.1991. (c) Winter, A.; Antberg, M.; Dolle, V.; Rohrmann, J.; Spaleck, W. EP 0 537 686, priority 15.10.1991. Acylation and cyclization of benzene derivatives with α-bromo isobutyric acid bromide: (d) Stehling, U.; Diebold, J.; Kirsten, R.; Röll, W.; Brintzinger, H. H.; Jüngling, S.; Mühlhaupt, R.; Langhauser, F. Organometallics 1994, 13, 964-970. (e) Rohrmann, J.; Küber, F. EP 0 545 304, priority 30.11.1991. Cyclization of benzene derivatives and methacrylic acid with polyphosphoric acid: (f) Kaminksky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181-193.
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    • The "angular" 4,5-substituted isomer is only formed in traces.
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