Synthesis and Structure of Novel MnIII and MnV Complexes: Development of a New, Mild Method for Forming Mn≡N Bonds

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 15, 1997, Pages 1645-1647

  Du Bois, J ^a   Tomooka, Craig S ^a   Hong, Jason ^a   Carreira, Erick M ^a   Day, Michael W ^b  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

Aminations; Manganese; N ligands; Nitrides; Schiff bases

Indexed keywords

EID: 0030772607     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199716451     Document Type: Article

References (46)

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37. 2 from low-valent metal azides to generate nitrido metal species have been documented, see: a) T. Jüstel, T. Weyhermüller, K. Wieghardt, E. Bill, M. Lengen, A. X. Trautwein, P. Hildebrandt, Angew. Chem. 1995, 107, 744; Angew. Chem. Int. Ed. Engl. 1995, 34, 669; b) J. W. Buchler, C. Dreher, Z. Naturforsch. B 1984, 39, 222; c) S. I. Arshankow, A. L. Poznjak, Z. Anorg. Allg. Chem. 1981, 481, 201.
38. 2 from low-valent metal azides to generate nitrido metal species have been documented, see: a) T. Jüstel, T. Weyhermüller, K. Wieghardt, E. Bill, M. Lengen, A. X. Trautwein, P. Hildebrandt, Angew. Chem. 1995, 107, 744; Angew. Chem. Int. Ed. Engl. 1995, 34, 669; b) J. W. Buchler, C. Dreher, Z. Naturforsch. B 1984, 39, 222; c) S. I. Arshankow, A. L. Poznjak, Z. Anorg. Allg. Chem. 1981, 481, 201.
39. 2 from low-valent metal azides to generate nitrido metal species have been documented, see: a) T. Jüstel, T. Weyhermüller, K. Wieghardt, E. Bill, M. Lengen, A. X. Trautwein, P. Hildebrandt, Angew. Chem. 1995, 107, 744; Angew. Chem. Int. Ed. Engl. 1995, 34, 669; b) J. W. Buchler, C. Dreher, Z. Naturforsch. B 1984, 39, 222; c) S. I. Arshankow, A. L. Poznjak, Z. Anorg. Allg. Chem. 1981, 481, 201.
40. 2 from low-valent metal azides to generate nitrido metal species have been documented, see: a) T. Jüstel, T. Weyhermüller, K. Wieghardt, E. Bill, M. Lengen, A. X. Trautwein, P. Hildebrandt, Angew. Chem. 1995, 107, 744; Angew. Chem. Int. Ed. Engl. 1995, 34, 669; b) J. W. Buchler, C. Dreher, Z. Naturforsch. B 1984, 39, 222; c) S. I. Arshankow, A. L. Poznjak, Z. Anorg. Allg. Chem. 1981, 481, 201.
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43. Other methods for synthesizing Mn≡N bonds with porphyrin and phthalocyanine complexes have been described, see: a) Hill, C. L.; Hollander, F. J. J. Am. Chem. Soc. 1982, 104, 7318; b) H. Grunewald, H. Homborg, Z. Anorg. Allg. Chem. 1992, 608, 81, and references therein.
44. 2(N)], respectively). Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: int. code +(1223) 336-033; e-mail: deposit@chemcrys.cam.ac.uk).
45. J. W. Buchler, C. Dreher, K.-L. Lay, Y. J. A. Lee, W. R. Scheidt, Inorg. Chem. 1983, 12, 888.
46. V porphyrin and salen complexes.