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85080606846
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2-=meso-tetrakis(3,4,5-trimethoxyphenyl)porphyrinato.
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38
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51149211064
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Mo complexes: B. S. McGilligan, T. C. Wright, G. Wilkinson, M. Motevalli, M. B. Hursthouse, J. Chem. Soc. Dalton Trans. 1988, 1737.
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85080494257
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W complexes: a See refs. [1b] and [16b]
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W complexes: a) See refs. [1b] and [16b];
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85080608407
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see ref. [19a]
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85080482157
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note
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2-=meso-tetrakis(2,4,6-trimethylphenyl)porphyrinato.
-
-
-
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96
-
-
85080484598
-
-
note
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14 (977.29, a product recrystallized from dichloromethane/n-hexane): calcd: C 72.51, H 6.91, N 8.59; found: C 72.32, H 6.78, N 8.30.
-
-
-
-
97
-
-
33846815530
-
-
a) Both cytochrome P-450 and synthetic metalloporphyrins are known to catalyze N-dealkylation of tertiary amines. Metal-oxo species are proposed as the key intermediates in these processes. However, to our knowledge, there are no reports on the N-dealkylation by isolated oxo metalloporphyrins, see: J. R. Lindsay Smith, D. N. Mortimer, J. Chem. Soc. Perkin Trans II 1986,1743;
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Lindsay Smith, J.R.1
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0026202483
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b) M. M. T. Khan, D. Chatterjee, S. Kumar, R. R. Merchant, K. N. Bhatt, J. Mol. Catalysis 1991, 67, 317.
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0013060692
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a) N. Farrell, D. H. Dolphin, B. R. James, J. Chem. Soc. 1978, 100, 324;
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101
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0016859166
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Synthesized by the standard method for the preparation of bis(pyridine)ruthenium(II) porphyrins, see: a) F. R. Hopf, T. P. O'Brien, W. R. Scheidt, D. G. Whitten, J. Am. Chem. Soc. 1975, 97, 277;
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103
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0000730148
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Formation of 5a shifted such resonances upfield by 6.18 ppm, a value very similar to the upfield shift of 6.14 ppm observed for the ortho proton resonances of pyridine after formation of 9 (see Table 1)
-
The free N(Et)=CHMe ligand exhibits the ethylidene CH proton resonances at δ=7.63 (C. Stevens, N. D. Kimpe, J. Org. Chem. 1993, 58, 132). Formation of 5a shifted such resonances upfield by 6.18 ppm, a value very similar to the upfield shift of 6.14 ppm observed for the ortho proton resonances of pyridine after formation of 9 (see Table 1).
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β protons for diamagnetic metalloporphyrins usually increase with the oxidation state of the metal ions: a See ref. [13f];
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β protons for diamagnetic metalloporphyrins usually increase with the oxidation state of the metal ions: a) See ref. [13f];
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β chemical shifts (δ=8.6-8.9).
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108
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85080531077
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1H NMR measurements.
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115
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85080530149
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tpy=2,2′:6,2″-terpyridine.
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116
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2 6.70 (t, 4H), 6.55 (t, 8H), 3.81 (d, 8H).
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