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Volumn , Issue 3, 2000, Pages 225-226

Probing the catalytic oxidation of alcohols via an anionic dimolybdate centre using multistage mass spectrometry

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; ANION; MOLYBDIC ACID; OXYGEN 18; QUATERNARY AMMONIUM DERIVATIVE;

EID: 0034615096     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a909353b     Document Type: Article
Times cited : (18)

References (20)
  • 3
    • 0001113587 scopus 로고    scopus 로고
    • (b) vol. 2 Ion Trap Instrumentation. The operation of the modified instrument has been described previously: G. E. Reid, R. J. Simpson and R. A. J. O'Hair, Int. J. Mass Spectrom., 1999, 190/191, 209.
    • Ion Trap Instrumentation , vol.2
  • 4
    • 0001113587 scopus 로고    scopus 로고
    • (b) vol. 2 Ion Trap Instrumentation. The operation of the modified instrument has been described previously: G. E. Reid, R. J. Simpson and R. A. J. O'Hair, Int. J. Mass Spectrom., 1999, 190/191, 209.
    • (1999) Int. J. Mass Spectrom. , vol.190-191 , pp. 209
    • Reid, G.E.1    Simpson, R.J.2    O'Hair, R.A.J.3
  • 11
    • 0342963791 scopus 로고    scopus 로고
    • note
    • -1 in MeCN. Typical ESI conditions: Sheath gas flow rate 50 (arbitrary units), auxilliary gas flow rate 0 (arbitrary units), spray voltage 3 kV, capillary temp. 100 °C, capillary voltage -5 V, tube lens offset -5 V.
  • 13
    • 0342529597 scopus 로고    scopus 로고
    • note
    • 3SiCl.
  • 16
    • 0342529595 scopus 로고    scopus 로고
    • note
    • tOH.
  • 17
    • 19944381083 scopus 로고    scopus 로고
    • note
    • -.
  • 18
    • 0001101786 scopus 로고
    • For a review on related oxygen atom transfer reactions, see: R. H. Holm and J. P. Donahue, Polyhedron, 1993, 12, 571.
    • (1993) Polyhedron , vol.12 , pp. 571
    • Holm, R.H.1    Donahue, J.P.2
  • 19
    • 0343834848 scopus 로고    scopus 로고
    • note
    • n experiments were carried out using a Q value of 0.25. Ion-molecule reactions times were typically: reaction (ii) = 5 s; reaction (iv) = 20 ms; reaction (v) = 200 ms. Typical CID reactions were carried out for 30 ms using the following activation amplitudes: reaction (i) = 0.75 V; reaction (iii) = 0.65 V.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.