Supported bimetallic cluster catalysts

Industrial and Engineering Chemistry Research

Volumn 42, Issue 8, 2003, Pages 1571-1587

  Alexeev, O S ^a   Gates, B C ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; BIMETALS; CHEMICAL BONDS; REDUCTION; ZEOLITES;

CLUSTER CATALYSTS;

CATALYST ACTIVITY;

CARBON MONOXIDE; HYDROGEN; IRIDIUM; METAL; PLATINUM; RHENIUM; TIN; ZEOLITE;

CATALYST;

ADSORPTION; CATALYST; CHEMICAL BOND; HYDROGENATION; REVIEW; SYNTHESIS; X RAY DIFFRACTION;

EID: 0037448970     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020351h     Document Type: Review

References (98)

1. Sinfelt, J. H. Bimetallic Catalysts: Discoveries, Concepts, and Applications; Wiley: New York, 1983.
2. Sinfelt, J. H. From the 1950s to the 1990s-My Years as a Scientist in an Industrial Laboratory. Catal. Today 1999, 53, 305.
3. Sinfelt, J. H. Catalytic Hydrogenolysis on Metals. Catal. Lett. 1991, 9, 159.
4. Ponec, V.; Bond, G. C. Catalysis by Metals and Alloys; Elsevier: Amsterdam, The Netherlands, 1995.
5. Antos, G. J., Aitani, A. M., Parera, J. M., Eds. Catalytic Naphtha Reforming: Science and Technology; Dekker: New York, 1995.
6. 12]: Characterization by Extended X-ray Absorption Fine Structure Spectroscopy and Catalysis of Methylcyclohexane Dehydrogenation. J. Am. Chem. Soc. 1997, 119, 5877.
7. Schüth, F.; Unger, K. In Preparation of Solid Catalysts; Ertl, G., Knözinger, H., Weitkamp, J., Eds.; Wiley-VCH: Weinheim, Germany, 1999; p 60.
8. Yermakov, Y. I.; Kuznetsov, B. N.; Zakharov, V. A. Catalysis by Supported Complexes; Elsevier: Amsterdam, The Netherlands, 1981.
9. Lefebvre, F.; Candy, J. P.; Basset, J.-M. In Metal Clusters in Chemistry; Braunstein, P., Oro, L. A., Raithby, P. R., Eds.; Wiley-VCH: Weinheim, Germany, 1999; p 782.
10. Margitfalvi, J. L.; Borbáth, I.; Hegedüs, M.; Göbölös, S.; Lónyi, F. New Approaches to Prepare Supported Sn-Pt Bimetallic Catalysts. React. Kinet. Catal. Lett. 1999, 68, 133.
11. Gates, B. C. Supported Metal Cluster Catalysts. J. Mol. Catal. A: Chem. 2000, 163, 55.
12. Ichikawa, M. In Metal Clusters in Chemistry; Braunstein, P., Oro, L. A., Raithby, P. R., Eds.; Wiley-VCH: Weinheim, Germany, 1999; p 1273.
13. Ichikawa, M.; Rao, L.; Ito, T.; Fukuoka, A. Ensemble and Ligand Effects in Selective Alkane Hydrogenolysis Catalysed on Well Characterized RhIr and RhFe Bimetallic Clusters inside NaY Zeolite. Faraday Discuss. Chem. Soc. 1989, 87, 321.
14. Ichikawa, M.; Rao, L.-F.; Kimura, T.; Fukuoka, A. Heterogenized Bimetallic Clusters: Their Structures and Bifunctional Catalysis. J. Mol. Catal. 1990, 62, 15.
15. 2-grafted and Zeolite-entrapped Ru, Co and RuCo Bimetallic Clusters: Their EXAFS and FTIR Characterization and Catalytic Performances. Top. Catal. 1995, 2, 141.
16. 129Xe NMR and EXAFS. J. Catal. 1992, 133, 191.
17. 10 on NaY and NaHY Zeolites - Effect of Prereduced Pt Clusters in the Supercages. J. Mol. Catal. 1989, 52, 193.
18. Braunstein, P.; Rosé, J. In Metal Clusters in Chemistry; Braunstein, P., Oro, L. A., Raithby, P. R., Eds.; Wiley-VCH: Weinheim, Germany, 1999; p 616.
19. Huber, C.; Moller, K.; Bein, T. Encapsulation of Tetracarbonyl(trimethylstannyl)cobalt in NaY Zeolite: Reactivity and Alloy Cluster Formation. J. Phys. Chem. 1994, 98, 12067.
20. Guczi, L.; Beck, A. Elementary Steps in the Formation of Bimetallic Catalysts Derived from Carbonyl Clusters. Polyhedron 1988, 7, 2387.
21. Bergmeister, J. J.; Hanson, B. E. Adsorption of Ruthenium-Cobalt Bimetallic Clusters on Hydroxylated Alumina. Organometallics 1989, 8, 283.
22. 4 upon Impregnation onto Inorganic Supports. J. Chem. Soc., Chem. Commun. 1983, 334.
23. Ugo, R.; Dossi, C.; Psaro, R. Molecular Metal Carbonyl Clusters and Volatile Organometallic Compounds for Tailored Mono and Bimetallic Heterogeneous Catalysts. J. Mol. Catal. A: Chem. 1996, 107, 13.
24. Chandler, B. D.; Schnabel, A. B.; Pignolet, L. H. Preparation and Characterization of Supported Bimetallic Pt-Au Particle Catalysts from Molecular Cluster and Chloride Salt Precursors. J. Catal. 2000, 187, 367.
25. Chandler, B. D.; Schnabel, A. B.; Pignolet, L. H. Preparation and Characterization of Supported Bimetallic Pt-Au and Pt-Cu Catalysts from Bimetallic Molecular Precursors. J. Catal. 2000, 193, 186.
26. Chandler, B. D.; Schnabel, A. B.; Pignolet, L. H. Ensemble Size Effects on Toluene Hydrogenation and Hydrogen Chemisorption by Supported Bimetallic Particle Catalysts. J. Phys. Chem. B 2001, 105, 149.
27. Raja, R.; Sankar, G.; Hermans, S.; Shephard, D. S.; Bromley, S.; Thomas, J. M.; Johnson, B. F. G. Preparation and Characterisation of a Highly Active Bimetallic (Pd-Ru) Nanoparticle Heterogeneous Catalyst. Chem. Commun. 1999, 1571.
28. Hills, C. W.; Nasher, M. S.; Frenkel, A. I.; Shapley, J. R.; Nuzzo, R. G. Carbon Support Effects on Bimetallic Pt-Ru Nanoparticles Formed from Molecular Precursors. Langmuir 1999, 15, 690.
29. 18]: Characterization by Infrared and Extended X-ray Absorption Fine Structure Spectroscopies. J. Phys. Chem. B 2002, 106, 4697.
30. x, Catalysis: Dissociative or Associative Nitric Oxide Adsorption, and its Assisted Decomposition in the Presence of a Reductant. Part I. Nitric Oxide Decomposition Assisted by CO Over Reduced or Oxidized Rhodium Species Supported on Ceria. J. Mol. Catal. A: Chem. 2000, 161, 179.
31. Long, J. W.; Stroud, R. M.; Swider-Lyons, K. E.; Rolison, D. R. How to Make Electrocatalysts More Active for Direct Methanol Oxidation - Avoid PtRu Bimetallic Alloys. J. Phys. Chem. B 2000, 104, 9772.
32. 3-Supported Pt Catalysts with Extremely high Dispersions Resulting from Pt-W Interactions. J. Catal. 2000, 190, 157.
33. 3-supported Pt-W Catalysts Prepared from Molecular Organometallic Precursors: Characterization by IR Spectroscopy. Phys. Chem. Chem. Phys. 1999, 1, 5725.
34. Alexeev, O.; Shelef, M.; Gates, B. C. MgO-supported Platinum- Tungsten Catalysts Prepared from Organometallic Precursors: Platinum Clusters Isolated on Dispersed Tungsten. J. Catal. 1996, 164, 1.
35. Hoost, T. E.; Graham, G. W.; Shelef, M.; Alexeev, O.; Gates, B. C. Highly Dispersed MgO-supported Model Pd-Mo Catalysts Prepared from Bimetallic Clusters: Chemisorption and Selective Catalytic Reduction of NO. Catal. Lett. 1996, 38, 57.
36. Alexeev, O.; Kawi, S.; Shelef, M.; Gates, B. C. Synthesis and Characterization of Model MgO-Supported Catalysts with Pt-Mo Interactions. J. Phys. Chem. 1996, 100, 253.
37. Kawi, S.; Alexeev, O.; Shelef, M.; Gates, B. C. Highly Dispersed MgO-Supported Model Pd-Mo Catalysts Prepared from Bimetallic Clusters. J. Phys. Chem. 1995, 99, 6926.
38. Bromley, S. T.; Sankar, G.; Catlow, C. R. A.; Maschmeyer, T.; Johnson, B. F. G.; Thomas, J. M. New Insights into the Structure of Supported Bimetallic Nanocluster Catalysts Prepared from Carbonylated Precursors: a Combined Density Functional Theory and EXAFS Study. Chem. Phys. Lett. 2001, 340, 524.
39. Bromley, S. T.; Sankar, G.; Catlow, C. R. A.; Thomas, J. M.; Maschmeyer, T. Bimetallic Clusters Supported on Mesoporous Silica: the Effects of Support Interactions on Cluster Morphology. Microporous Mesoporous Mater. 2001, 44, 395.
40. 3. J. Catal. 1999, 185, 170.
41. Ryndin, Y. A.; Alexeev, O. S.; Paukshtis, E. A.; Zaikovskii, V. I.; Kalinkin, A. V. Influence of Zr Ions on the Properties of Pd Supported on Graphite and Diamond. J. Mol. Catal. 1991, 68, 355.
42. 2. Appl. Catal. 1990, 63, 37.
43. Alexeev, O. S.; Ryndin, Y. A. The Mechanism of the Interaction between Group VIII Metals and the Oxides of the Transition Elements. Usp. Khim. (Russ. Chem. Rev.) 1992, 61, 765.
44. Ryndin, Y. A.; Nogin, Y. N.; Zverev, Y. B.; Chernyaev, N. P.; Abdikova, F. G.; Ermakov, Y. I. Influence of Rare Earth Ions on the Properties of Palladium/Silica in Carbon Monoxide Hydrogenation. React. Kinet. Catal. Lett. 1986, 31, 151.
45. Chandler, B. D.; Pignolet, L. H. DRIFTS Studies of Carbon Monoxide Coverage on Highly Dispersed Bimetallic Pt-Cu and Pt-Au Catalysts. Catal. Today 2001, 65, 39.
46. 3-supported Platinum Catalysts With and Without Tungsten. Phys. Chem. Chem. Phys. 2000, 2, 1997.
47. Kip, B. J.; Duivenvoorden, F. B. M.; Koningsberger, D. C.; Prins, R. Determination of Metal Particle Size of Highly Dispersed Rhodium, Iridium, and Platinum Catalysts by Hydrogen Chemisorption and EXAFS. J. Catal. 1987, 105, 26.
48. Alexeev, O. S.; Kim, D.-W.; Gates, B. C. Partially Decarbonylated Tetrairidium Clusters on MgO: Structural Characterization and Catalysis of Toluene Hydrogenation. J. Mol. Catal. A: Chem. 2000, 162, 67.
49. 3: Structural Characterization and Catalysis of Toluene Hydrogenation. J. Catal. 1998, 176, 310.
50. 3: Structural Characterization and Catalysis of Toluene Hydrogenation. J. Catal. 1998, 173, 196.
51. Xu, Z.; Xiao, F.-S.; Purnell, S. K.; Alexeev, O.; Kawi, S.; Deutsch, S. E.; Gates, B. C. Size-dependent Catalytic Activity of Supported Metal Clusters. Nature (London) 1994, 372, 346.
52. Goellner, J. F.; Gates, B. C. Synthesis and Characterization of Site-Isolated Hexarhodium Clusters on Titania Powder. J. Phys. Chem. B 2001, 105, 3269.
53. Burch, R.; Flambard, A. R. Strong Metal-support Interactions in Nickel/Titania Catalysts: the Importance of Interfacial Phenomena. J. Catal. 1982, 78, 389.
54. Rieck, J. S.; Bell, A. T. Studies of the Interactions of Hydrogen and Carbon Monoxide with Silica- and Lanthana-supported Palladium. J. Catal. 1985, 96, 88.
55. Bredikhin, M. N.; Lokhov, Y. A.; Kuznetsov, V. L. Role of Support in Adsorption and Catalysis on Supported Metals. I. IR Study of Carbon Monoxide and Hydrogen Adsorption on Rhodium/silica, Rhodium/alumina, and Rhodium/lanthanum oxide. Kinet. Katal. 1987, 28, 671.
56. Bredikhin, M. N.; Lokhov, Y. A. Role of Support in Adsorption and Catalysis on Supported Metals. II. IR Study of Carbon Monoxide and Carbon Dioxide Adsorption on Rhodium/zirconia. Kinet. Katal. 1987, 28, 678.
57. Bredikhin, M. N.; Lokhov, Y. A.; Zamaraev, K. I. Characteristics of Catalysts of the Group VIII Metal/transition Metal Oxide Type in Relation to Adsorption of Carbon Monoxide According to the IR Spectroscopic Data. Dokl. Akad. Nauk SSSR 1988, 301, 1124.
58. Mehandru, S. P.; Anderson, A. B.; Ross, P. N. Carbon Monoxide Adsorption on (111) and (100) Surfaces of the Platinumtitanium (Pt3Ti) Alloy: Evidence for Parallel Binding and Strong Activation of Carbon Monoxide. J. Catal. 1986, 100, 210.
59. Rice, R. W.; Haller, G. L. Internal Reflection Spectroscopy of Adsorbed Molecules on Metal Films. Carbon Monoxide on Palladium. J. Catal. 1975, 40, 249.
60. Sachtler, W. M. H.; Shriver, D. F.; Hollenberg, W. B.; Lang, A. F. Promoter Action in Fischer-Tropsch Catalysis. J. Catal. 1985, 92, 429.
61. - with Cations on Magnesia, Alumina, and Potassium-Modified Alumina. J. Am. Chem. Soc. 1994, 116, 1372.
62. 2 Catalysts Promoted by Niobium Oxide. J. Mol. Catal. 1994, 92, 217.
63. Vannice, M. A. The Use of Metal-support Interactions to Selectively Activate Carbonyl Bonds. J. Mol. Catal. 1990, 59, 165.
64. 2. J. Catal. 1997, 166, 25.
65. Delbecq, F.; Sautet, P. Competitive C:C and C:O Adsorption of α,β Unsaturated Aldehydes on Pt and Pd Surfaces in Relation with the Selectivity of Hydrogenation Reactions: a Theoretical Approach. J. Catal. 1995, 152, 217.
66. Vannice, M. A.; Sen, B. Metal-support Effects on the Intramolecular Selectivity of Crotonaldehyde Hydrogenation over Platinum. J. Catal. 1989, 115, 65.
67. Coloma, F.; Sepúlveda-Escribano, A.; Fierro, J. L. G.; Rodriguez-Reinoso, F. Crotonaldehyde Hydrogenation over Bimetallic Pt-Sn Catalysts Supported on Pregraphitized Carbon Black. Effect of the Preparation Method. Appl. Catal. A 1996, 148, 63.
68. Coloma, F.; Sepúlveda-Escribano, A.; Fierro, J. L. G.; Rodriguez-Reinoso, F. Crotonaldehyde Hydrogenation over Bimetallic Pt-Sn Catalysts Supported on Pregraphitized Carbon Black. Effect of the Sn/Pt Atomic Ratio. Appl. Catal. A 1996, 136, 231.
69. Richard, D.; Ockelford, J.; Giroir-Fendler, A.; Gallezot, P. Composition and Catalytic Properties in Cinnamaldehyde Hydrogenation of Charcoal-supported Platinum Catalysts Modified by iron(II) chloride. Catal. Lett. 1989, 3, 53.
70. 2 Catalysts for Hydrogenation of Crotonaldehyde. J. Mol. Catal. 1992, 75, 71.
71. Raab, C. G.; Lercher, J. A. Activity and Selectivity of Platinum- nickel/titania Catalysts for Hydrogenation of Crotonal-dehyde. Catal. Lett. 1993, 18, 99.
72. Waghray, A.; Wang, J.; Oukaci, R.; Blackmond, D. G. Influence of Alkali Promoters in the Selective Hydrogenation of 3-methyl-2-butenal over Ruthenium/silica Catalysts. J. Phys. Chem. 1992, 96, 5954.
73. Giroir-Fendler, A.; Richard, D.; Gallezot, P. Chemoselectivity in the Catalytic Hydrogenation of Cinnamaldehyde. Effect of Metal Particle Morphology. Catal. Lett. 1990, 5, 175.
74. Galvagno, S.; Capannelli, G.; Neri, G.; Donato, A.; Pietropaolo, R. Hydrogenation of Cinnamaldehyde over Ruthenium/carbon Catalysts: Effect of Ruthenium Particle Size. J. Mol. Catal. 1991, 64, 237.
75. Chandler, B. D.; Rubinstein, L. I.; Pignolet, L. H. Alkane Dehydrogenation with Silica Supported Platinum and Platinum-gold Catalysts Derived from Phosphine Ligated Precursors. J. Mol. Catal. A: Chem. 1998, 133, 267.
76. Lin, S. D.; Vannice, M. A. Hydrogenation of Aromatic Hydrocarbons over Supported Platinum Catalysts. I. Benzene Hydrogenation. J. Catal. 1993, 143, 539.
77. Lin, S. D.; Vannice, M. A. Hydrogenation of Aromatic Hydrocarbons over Supported Platinum Catalysts. III. Reaction Models for Metal Surfaces and Acidic Sites on Oxide Supports. J. Catal. 1993, 143, 563.
78. 3-supported Iridium Clusters and Particles for Toluene Hydrogenation. Stud. Surf. Sci. Catal. 1996, 101, 1135.
79. Heiz, U.; Schneider, W.-D. Physical Chemistry of Supported Clusters. Met. Clusters Surf. 2000, 237.
80. Heiz, U.; Sanchez, A.; Abbet, S.; Schneider, W.-D. The Reactivity of Gold and Platinum Metals in their Cluster Phase. Eur. Phys. J. D 1999, 9, 35.
81. 2 Catalyst Prepared under Various Temperatures. Surf. Interface Anal. 2001, 31, 73.
82. Valden, M.; Lai, X.; Goodman, D. W. Onset of Catalytic Activity of Gold clusters on Titania with the Appearance of Nonmetallic Properties. Science 1998, 281, 1647.
83. Argo, A. M.; Odzak, J. F.; Lai, F. S.; Gates, B. C. Observation of Ligand Effects During Alkene Hydrogenation Catalysed by Supported Metal Clusters. Nature (London) 2002, 415, 623.
84. Via, G. H.; Drake, K. F.; Meitzner, G.; Lytle, F. W.; Sinfelt, J. H. Analysis of EXAFS Data on Bimetallic Clusters. Catal. Lett. 1990, 5, 25.
85. Borvornwattananont, A.; Bein, T. Reactivity of (Trimethyl stannyl)pentacarbonylmanganese in Zeolite Cavities. J. Phys. Chem. 1992, 96, 9447.
86. Shen, J. G. C.; Ichikawa, M. Intrazeolite Anchoring of Co, Ru, and [Ru-Co] Carbonyl Clusters: Synthesis, Characterization, and Their Catalysis for CO Hydrogenation. J. Phys. Chem. B 1998, 102, 5602.
87. 18 and Products Obtained from Its Reactions with 1,2-Bis(diphenylphosphino)ethane. J. Cluster Sci. 1993, 4, 119.
88. Nashner, M. S.; Frenkel, A. I.; Somerville, D.; Hills, C. W.; Shapley, J. R.; Nuzzo, R. G. Core Shell Inversion during Nucleation and Growth of Bimetallic Pt/Ru Nanoparticles. J. Am. Chem. Soc. 1998, 120, 8093.
89. 16. J. Am. Chem. Soc. 1997, 119, 7760.
90. Deutsch, S. E.; Chang, J. R.; Gates, B. C. Osmium Subcarbonyls on γ-alumina: Characterization of the Metal-support Bonding by Infrared, Nuclear Magnetic Resonance, and X-ray Absorption Spectroscopies. Langmuir 1993, 9, 1284.
91. Hu, A.; Neyman, K. M.; Staufer, M.; Belling, T.; Gates, B. C.; Rösch, N. A Surface Site as Polydentate Ligand of a Metal Complex: Density Functional Studies of Rhenium Subcarbonyls Supported on Magnesium Oxide. J. Am. Chem. Soc. 1999, 121, 4522.
92. 4 Clusters. A Density Functional Model Study of Metal-zeolite Interactions. J. Phys. Chem. B 1999, 103, 5311.
93. n (n = 1-5) Clusters on Nonbridging Oxygen Defects. J. Phys. Chem. B 1999, 103, 1712.
94. Goellner, J. F.; Neyman, K. M.; Mayer, M.; Nöertemann, F.; Gates, B. C.; Rösch, N. Ligand-free Osmium Clusters Supported on MgO. A Density Functional Study. Langmuir 2000, 16, 2736.
95. Alexeev, O.; Gates, B. C. EXAFS Characterization of Supported Metal-complex and Metal-cluster Catalysts Made from Organometallic Precursors. Top. Catal. 2000, 10, 273.
96. 6]/MgO Catalyst: the Catalytic Activity for NO-CO Reactions and Structural Analysis by EXAFS. Bull. Chem. Soc. Jpn. 1997, 70, 1607.
97. Shephard, D. S.; Maschmeyer, T.; Sankar, G.; Thomas, J. M.; Ozkaya, D.; Johnson, B. F. G.; Raja, R.; Oldroyd, R. D.; Bell, R. G. Preparation, Characterization and Performance of Encapsulated Copper-ruthenium Bimetallic Catalysts Derived from Molecular Cluster Carbonyl Precursors. Chem. Eur. J. 1998, 4, 1214.
98. Nashner, M. S.; Somerville, D. M.; Lane, P. D.; Adler, D. L.; Shapley, J. R.; Nuzzo, R. G. Bimetallic Catalyst Particle Nanostructure. Evolution from Molecular Cluster Precursors. J. Am. Chem. Soc. 1996, 118, 12964.