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Volumn 4, Issue 7, 1998, Pages 1214-1224

Preparation, characterisation and performance of encapsulated copper-ruthenium bimetallic catalysts derived from molecular cluster carbonyl precursors

Author keywords

Bimetallic nanoparticles; Clusters; Copper; Heterogeneous catalysis; Hydrogenations; Ruthenium

Indexed keywords


EID: 0031851103     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3765(19980710)4:7<1214::AID-CHEM1214>3.0.CO;2-E     Document Type: Article
Times cited : (158)

References (53)
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    • M. A. Beswick, Ph.D Thesis, University of Cambridge, 1992, and references therein; M. A. Beswick, J. Lewis, P. R. Raithby, M. C. Ramirez de Arellano, Angew. Chem. 1997, 109, 303; Angew. Chem. Int. Ed. Engl. 1997, 36, 291.
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    • Solvent extraction of this material with dichloromethane showed the bimetallic clusters can be quantitatively desorbed and remain chemically unchanged
    • Solvent extraction of this material with dichloromethane showed the bimetallic clusters can be quantitatively desorbed and remain chemically unchanged.
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    • The overall TOP of this reaction was unexpectedly low; this may be a result of deactivation by long-lived intermediates blocking reactive sites on the bimetallic particles. We are currently attempting to determine the cause of this loss of activity
    • The overall TOP of this reaction was unexpectedly low; this may be a result of deactivation by long-lived intermediates blocking reactive sites on the bimetallic particles. We are currently attempting to determine the cause of this loss of activity.
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    • Pergamon, Oxford
    • The degree of substitution of a given olefin is known to be geometrically inversely proportional to the rate at which it may be hydrogenated on a metal surface; see Comprehensive Organic Synthesis, Vol X, Pergamon, Oxford, 1988.
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    • The precise theoretical treatment of this approach for these systems will be published elsewhere, but is already available in its general form from the XFIT documentation, Australian Synchrotron Research Program, c/- ANSTO, Private Mail Bag 1, Menai, NSW, 2234 (Australia)
    • The precise theoretical treatment of this approach for these systems will be published elsewhere, but is already available in its general form from the XFIT documentation, Australian Synchrotron Research Program, c/- ANSTO, Private Mail Bag 1, Menai, NSW, 2234 (Australia).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.