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note
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The collinear ("focusing") DS and TS paths, that arise from linear three-atom arrangements, generally contribute a large amplitude to the overall EXAFS function for close-packed structures. For example, in the fee crystal structure, collinear DS paths result from (1) forward scattering by an atom in the first-shell, and (2) backscattering by an atom in the fourth shell (M-M(1)-M(4)-M). Since this path is time-reversed, there are two times more degenerate scattering paths (i.e., 24) than the number of atoms in the 4th shell of the fee structure. The collinear TS paths are similar to the DS paths except that the photoelectron scatters from atoms in the first-shell twice (M-M(1)-M(4)-M(1)-M). This path is not time reversed, resulting in only 12 degenerate paths, i.e., the same as the number of atoms in the fourth shell.
-
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-
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67
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1842310880
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note
-
Some of the triangle paths may also contribute significantly to the MS amplitude because of their large degeneracy in the fee structure. These paths arise from noncollinear scattering from two neighbors. For example two significant triangle paths include scattering between the 1st and 3rd shells, and between two first shells (M-M(3)-M(1)-M and M-M(1)-M(1)-M).
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