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Comparisons between chemiresistor vapor sensors coated with monolayerprotected nanoparticles and surface acoustic wave vapor sensors coated with polymers have been presented by Snow and co-workers at the April 2001 ACS Meeting (Defense Applications of Nanomaterials) in San Diego and at the AVS Topical Conference on Understanding and Operating in Threat Environments, Monterey, CA, April 30-May 2, 2002.
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Arthur Snow has measured the densities for alkanethiol-protected gold nanoparticle materials and finds that they vary systematically with core size and alkanethiol length. Values from 2.7 to 3.7 g/mL were determined with a value of 3 g/mL for dodecanethiol-protected gold nanoparticles. Personal communication.
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44
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Zellers has reported estimated effective densities of 1.2 g/mL for as-deposited films of his monolayer-protected gold nanoparticle materials. This value was estimated from the thicknesses and masses of spray-coated films on glass cover slips as determined by profilometry and microbalance measurements, respectively.
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2. This material has a metal mass fraction of 0.72 and a metal volume fraction of only 0.10.
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