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Volumn 125, Issue 6, 2003, Pages 1607-1617

Trends in metal-biradical exchange interaction for first-row MII(nitronyl nitroxide-semiquinone) complexes

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; ION EXCHANGE; MAGNETIC SUSCEPTIBILITY; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; ORGANOMETALLICS;

EID: 0037433229     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja020715x     Document Type: Article
Times cited : (81)

References (82)
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  • 23
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    • Public EPR Software Tools, National Institute of Environmental Health Sciences, National Institutes of Health: Triangle Park, NC
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    • Duling, D.1
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    • note
    • Cum,Me (see text), where no maximum in ξ vs T is observed. Thus, the curvature of the ξT vs T plots are greater and provide for better analysis of the data.
  • 45
    • 0035557578 scopus 로고    scopus 로고
    • Solid state chemistry of inorganic materials III
    • Geselbracht, M. J., Greedan, J. E., Johnson, D. C., Subramanian, M. A., Eds.; Materials Research Society: Warrendale, PA
    • Dai, D.; Koo, H.-J.; Whangbo, M.-H. Solid State Chemistry of Inorganic Materials III. In MRS Symposium Proceedings; Geselbracht, M. J., Greedan, J. E., Johnson, D. C., Subramanian, M. A., Eds.; Materials Research Society: Warrendale, PA, 2001; Vol. 658, GG5.3.1-5.3.11.
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  • 49
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    • note
    • i| = 0.164 Å, but this may reflect the lower quality of structural data.
  • 50
    • 0001640061 scopus 로고    scopus 로고
    • Conformational exchange modulation in Trimethylenemethane (TMM)-Type biradicals
    • Lahti, P., Ed.; Marcel Dekker: New York
    • Shultz, D. A. Conformational Exchange Modulation in Trimethylenemethane (TMM)-Type Biradicals. In Magnetic Properties of Organic Materials; Lahti, P., Ed.; Marcel Dekker: New York, 1999.
    • (1999) Magnetic Properties of Organic Materials
    • Shultz, D.A.1
  • 67
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    • High-Spin polyradicals
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    • Rajca, A. High-Spin Polyradicals. In Magnetic Properties of Organic Materials; Lahti, P., Ed.; Marcel Dekker: New York, 1999; p 345.
    • (1999) Magnetic Properties of Organic Materials , pp. 345
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  • 70
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    • For the hyperfine coupling constant of SQ, we used the value for H4 reported in our previous work (3,33 G), and assumed negligible difference between the spin densities of C4 and C5: Shultz, D. A.; Boal, A. K.; Campbell, N. P. Inorg. Chem. 1998, 37, 1540-3: see also: Wheeler, D. E.; Rodriquez, J. H.; McCusker, J. K. J. Phys. Chem. A 1999, 103, 4101. For the H4′ hyperfine coupling constant for 3-tert-butyl-5-phenylsemiquione (0.6 G), we prepared the radical anion and simulated its fluid solution EPR spectrum, see Supporting Information.
    • (1998) Inorg. Chem. , vol.37 , pp. 1540-1543
    • Shultz, D.A.1    Boal, A.K.2    Campbell, N.P.3
  • 71
    • 0001373891 scopus 로고    scopus 로고
    • For the hyperfine coupling constant of SQ, we used the value for H4 reported in our previous work (3,33 G), and assumed negligible difference between the spin densities of C4 and C5: Shultz, D. A.; Boal, A. K.; Campbell, N. P. Inorg. Chem. 1998, 37, 1540-3: see also: Wheeler, D. E.; Rodriquez, J. H.; McCusker, J. K. J. Phys. Chem. A 1999, 103, 4101. For the H4′ hyperfine coupling constant for 3-tert-butyl-5-phenylsemiquione (0.6 G), we prepared the radical anion and simulated its fluid solution EPR spectrum, see Supporting Information.
    • (1999) J. Phys. Chem. A , vol.103 , pp. 4101
    • Wheeler, D.E.1    Rodriquez, J.H.2    McCusker, J.K.3
  • 78
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    • These pathways are described by the Goodenough Kanamori rules, see the following. Ginsberg, A. P. Inorg. Chim. Acta Rev. 1971, 5, 45. Hatfield, W. E. In Theory and Applications of Molecular Paramagnetism; Boudreaux, E. A., Mulay, L. N., Eds.; Chapter 7, Properties of Condensed Compounds (Compounds with Spin Exchange); Wiley-Interscience: New York, 1976; pp 381-385.
    • (1971) Inorg. Chim. Acta Rev. , vol.5 , pp. 45
    • Ginsberg, A.P.1
  • 79
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    • Boudreaux, E. A., Mulay, L. N., Eds.; Chapter 7, Properties of Condensed Compounds (Compounds with Spin Exchange); Wiley-Interscience: New York
    • These pathways are described by the Goodenough Kanamori rules, see the following. Ginsberg, A. P. Inorg. Chim. Acta Rev. 1971, 5, 45. Hatfield, W. E. In Theory and Applications of Molecular Paramagnetism; Boudreaux, E. A., Mulay, L. N., Eds.; Chapter 7, Properties of Condensed Compounds (Compounds with Spin Exchange); Wiley-Interscience: New York, 1976; pp 381-385.
    • (1976) Theory and Applications of Molecular Paramagnetism , pp. 381-385
    • Hatfield, W.E.1
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    • note
    • -1. Analogous methods were used for the nickel complexes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.