Assemblage and alignment of the spins of the organic trinitroxide radical with a quartet ground state by means of complexation with magnetic metal ions. A molecule-based magnet with three-dimensional structure and high TC of 46 K

Journal of the American Chemical Society

Volumn 118, Issue 7, 1996, Pages 1803-1804

  Inoue, Katsuya ^a,d   Hayamizu, Takashi ^b,e   Iwamura, Hiizu ^b,e   Hashizume, Daisuke ^c   Ohashi, Yuji ^c  

^a KITASATO UNIVERSITY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

^c TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^d INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^e KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX; RADICAL;

ARTICLE; COMPLEX FORMATION; MAGNETISM; SPIN LABELING; STEREOCHEMISTRY;

EID: 0029927731     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja952301s     Document Type: Article

References (20)

1. Borden, W. T. Diradicals: Wiley New York, 1982. Iwamura, H. Adv. Phys. Org. Chem. 1990, 26, 179. Weltner, W., Jr. Magneric Atoms and Molecules: Scientific and Academic Editions: New York, 1983. Dougherty, D. Acc. Chem. Res. 1991, 24, 88. Iwamura, H ; Koga, N. Acc. Chem. Res. 1993, 26, 346. Kurreck, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1409. Rajca, A. Chem. Rev. 1994, 94, 871. Miller, J. S., Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
2. Borden, W. T. Diradicals: Wiley New York, 1982. Iwamura, H. Adv. Phys. Org. Chem. 1990, 26, 179. Weltner, W., Jr. Magneric Atoms and Molecules: Scientific and Academic Editions: New York, 1983. Dougherty, D. Acc. Chem. Res. 1991, 24, 88. Iwamura, H ; Koga, N. Acc. Chem. Res. 1993, 26, 346. Kurreck, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1409. Rajca, A. Chem. Rev. 1994, 94, 871. Miller, J. S., Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
3. Borden, W. T. Diradicals: Wiley New York, 1982. Iwamura, H. Adv. Phys. Org. Chem. 1990, 26, 179. Weltner, W., Jr. Magneric Atoms and Molecules: Scientific and Academic Editions: New York, 1983. Dougherty, D. Acc. Chem. Res. 1991, 24, 88. Iwamura, H ; Koga, N. Acc. Chem. Res. 1993, 26, 346. Kurreck, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1409. Rajca, A. Chem. Rev. 1994, 94, 871. Miller, J. S., Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
4. Borden, W. T. Diradicals: Wiley New York, 1982. Iwamura, H. Adv. Phys. Org. Chem. 1990, 26, 179. Weltner, W., Jr. Magneric Atoms and Molecules: Scientific and Academic Editions: New York, 1983. Dougherty, D. Acc. Chem. Res. 1991, 24, 88. Iwamura, H ; Koga, N. Acc. Chem. Res. 1993, 26, 346. Kurreck, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1409. Rajca, A. Chem. Rev. 1994, 94, 871. Miller, J. S., Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
5. Borden, W. T. Diradicals: Wiley New York, 1982. Iwamura, H. Adv. Phys. Org. Chem. 1990, 26, 179. Weltner, W., Jr. Magneric Atoms and Molecules: Scientific and Academic Editions: New York, 1983. Dougherty, D. Acc. Chem. Res. 1991, 24, 88. Iwamura, H ; Koga, N. Acc. Chem. Res. 1993, 26, 346. Kurreck, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1409. Rajca, A. Chem. Rev. 1994, 94, 871. Miller, J. S., Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
6. Borden, W. T. Diradicals: Wiley New York, 1982. Iwamura, H. Adv. Phys. Org. Chem. 1990, 26, 179. Weltner, W., Jr. Magneric Atoms and Molecules: Scientific and Academic Editions: New York, 1983. Dougherty, D. Acc. Chem. Res. 1991, 24, 88. Iwamura, H ; Koga, N. Acc. Chem. Res. 1993, 26, 346. Kurreck, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1409. Rajca, A. Chem. Rev. 1994, 94, 871. Miller, J. S., Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
7. Borden, W. T. Diradicals: Wiley New York, 1982. Iwamura, H. Adv. Phys. Org. Chem. 1990, 26, 179. Weltner, W., Jr. Magneric Atoms and Molecules: Scientific and Academic Editions: New York, 1983. Dougherty, D. Acc. Chem. Res. 1991, 24, 88. Iwamura, H ; Koga, N. Acc. Chem. Res. 1993, 26, 346. Kurreck, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1409. Rajca, A. Chem. Rev. 1994, 94, 871. Miller, J. S., Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
8. Borden, W. T. Diradicals: Wiley New York, 1982. Iwamura, H. Adv. Phys. Org. Chem. 1990, 26, 179. Weltner, W., Jr. Magneric Atoms and Molecules: Scientific and Academic Editions: New York, 1983. Dougherty, D. Acc. Chem. Res. 1991, 24, 88. Iwamura, H ; Koga, N. Acc. Chem. Res. 1993, 26, 346. Kurreck, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 1409. Rajca, A. Chem. Rev. 1994, 94, 871. Miller, J. S., Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
9. Nakamura, N.; Inoue, K.; Iwamura, H ; Fujioka, T.; Sawaki, Y. J. Am Chem. Soc 1992, 114, 1484. Nakamura, N., Inoue, K., Iwamura, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 872. See also: Matsuda, K.; Nakamura, N.; Takahashi, K , Inoue, K.; Koga, N., Iwamura, H J. Am. Chem. Soc. 1994, 117, 5550
10. Nakamura, N.; Inoue, K.; Iwamura, H ; Fujioka, T.; Sawaki, Y. J. Am Chem. Soc 1992, 114, 1484. Nakamura, N., Inoue, K., Iwamura, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 872. See also: Matsuda, K.; Nakamura, N.; Takahashi, K , Inoue, K.; Koga, N., Iwamura, H J. Am. Chem. Soc. 1994, 117, 5550
11. Nakamura, N.; Inoue, K.; Iwamura, H ; Fujioka, T.; Sawaki, Y. J. Am Chem. Soc 1992, 114, 1484. Nakamura, N., Inoue, K., Iwamura, H. Angew. Chem., Int. Ed. Engl. 1993, 32, 872. See also: Matsuda, K.; Nakamura, N.; Takahashi, K , Inoue, K.; Koga, N., Iwamura, H J. Am. Chem. Soc. 1994, 117, 5550
12. Ishida, T.; Iwamura, H. J. Am. Chem Soc 1991, 113, 4238.
13. Matsuda, K.; Inoue, K.; Koga, N.; Nakamura, N., Iwamura, H Mol. Crust Liq Cryst. 1994, 253, 33. Matsuda, K.; Nakamura, N.; Inoue, K.; Koga, N , Iwamura, H. Chem. Eur. J , in press.
14. Matsuda, K.; Inoue, K.; Koga, N.; Nakamura, N., Iwamura, H Mol. Crust Liq Cryst. 1994, 253, 33. Matsuda, K.; Nakamura, N.; Inoue, K.; Koga, N , Iwamura, H. Chem. Eur. J , in press.
15. C above 300 K with unknown crystal structure, may also belong to this family of complexes (Manriquez, J M.; Yee, G. T ; McLean, R S., Epstein, A J.; Miller, J. S. Science 1991, 252, 1415)
16. C above 300 K with unknown crystal structure, may also belong to this family of complexes (Manriquez, J M.; Yee, G. T ; McLean, R S., Epstein, A J.; Miller, J. S. Science 1991, 252, 1415)
17. C above 300 K with unknown crystal structure, may also belong to this family of complexes (Manriquez, J M.; Yee, G. T ; McLean, R S., Epstein, A J.; Miller, J. S. Science 1991, 252, 1415)
18. C above 300 K with unknown crystal structure, may also belong to this family of complexes (Manriquez, J M.; Yee, G. T ; McLean, R S., Epstein, A J.; Miller, J. S. Science 1991, 252, 1415)
19. Inoue, K., Iwamura, H. J Am. Chem. Soc. 1994, 116, 3173
20. 3 and tert-butyl groups. Refinement is still in progress.