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Volumn 125, Issue 14, 2003, Pages 4038-4039

A general methodology for the synthesis of transition metal pnictide nanoparticles from pnictate precursors and its application to iron-phosphorus phases

Author keywords

[No Author keywords available]

Indexed keywords

FERRIC PHOSPHATE; IRON; METAL; PHOSPHORUS; PNICTIDE; UNCLASSIFIED DRUG;

EID: 0037427236     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028180v     Document Type: Article
Times cited : (70)

References (27)
  • 9
    • 0242528123 scopus 로고    scopus 로고
    • note
    • 6c,d
  • 14
    • 0242444597 scopus 로고    scopus 로고
    • note
    • 5
  • 15
    • 0242528122 scopus 로고    scopus 로고
    • note
    • 3 was treated with crystalline H3PO4 and tri-n-octylamine in tris-2-ethylhexylphosphonate (TEHP) at 160 °C overnight, followed by precipitation with methanol. The resultant nanoparticles have an Fe:P ratio of 0.92 ± 5% (ICP-MS) and are soluble in pyridine, toluene, or hexane.
  • 17
    • 0242444598 scopus 로고    scopus 로고
    • note
    • 10d
  • 21
    • 0242696981 scopus 로고    scopus 로고
    • note
    • Lateral AFM sizes are a convolution of tip geometry. Without aggressive deconvolution, it is more reliable to use measurements of nanoparticle heights. Over 150 cursor profiles were analyzed for average particle size determinations.
  • 22
    • 0242696980 scopus 로고    scopus 로고
    • note
    • 3). all reduction reactions were either conducted in, or vented to. a fume hood.
  • 23
    • 0242528120 scopus 로고    scopus 로고
    • note
    • Powder diffraction file (PDF) data were obtained from the ICDD-PDF database, release 2000.
  • 25
    • 0242612853 scopus 로고    scopus 로고
    • note
    • AFM imaging of plain mica substrates indicates that the surface remains atomically flat under the annealing conditions employed here.
  • 26
    • 0242696977 scopus 로고    scopus 로고
    • note
    • 8 will probe whether the reduction temperature dependence of the phase transformation is identical to that observed in the bulk, or if there are differences due to size effects, and this will be presented in a full paper.
  • 27
    • 0242444596 scopus 로고    scopus 로고
    • Binding energy data are available online at http://srdata.nist.gov/xps/.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.