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Volumn 110, Issue 3-6, 2003, Pages 1039-1054

Application of Statistical Physics to Understand Static and Dynamic Anomalies in Liquid Water

Author keywords

High density liquid; Homogeneous nucleation; Instantaneous normal mode; Low density liquid; Mode coupling theory; Structural heterogeneities

Indexed keywords


EID: 0037274128     PISSN: 00224715     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1022188608924     Document Type: Conference Paper
Times cited : (25)

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    • C. A. Angell, (private communication) has pointed out that the fact that the low density liquid phase of phosphorus that participates in a liquid-liquid equilibrium contains tetrahedral molecules, is not of as much significance as originally hoped, There are no third neighbor correlations in P4 phosphorus, which is more like carbon tetrachloride than water in its behavior. The liquid-liquid phase transition line in the phase diagram runs vertical to the P axis, instead of nearly horizontal as in the case of water, and the liquid-liquid equilibrium is due to electron redistribution (i.e., chemical bonding changes) rather than molecular packing changes as in the case of water. Such equilibria will likely be found in the future in many cases of molecular liquids subjected to high pressure (simply because polymerized forms occupy less volume) - and molecular shapes in the low pressure phase will be found to be a minor factor. We thank C. A. Angell for sharing his observations with us.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.