Singularity-free interpretation of the thermodynamics of supercooled water

Physical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics

Volumn 53, Issue 6 SUPPL. B, 1996, Pages 6144-6154

  Sastry, Srikanth ^a,b   Debenedetti, Pablo G ^b   Sciortino, Francesco ^c   Stanley, H E ^d  

^a NATIONAL INSTITUTES OF HEALTH   (United States)

^b Princeton University   (United States)

^c SAPIENZA UNIVERSITY OF ROME   (Italy)

^d Boston University ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001101089     PISSN: 1063651X     EISSN: None     Source Type: Journal    
DOI: 10.1103/physreve.53.6144     Document Type: Article

References (37)

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22. The model does not prove that there are no low temperature singularities in water; only experiments can do that. Because such experiments must probe the behavior of a highly supercooled liquid, they are especially difficult. Given this situation, theoretical calculations are useful in two ways. First, they provide thermodynamically consistent scenarios with stringent constraints on the allowed behavior of observable quantities (e.g., a negatively-sloped TMD implies that the compressibility must increase upon cooling). Second, they suggest what must be measured in order to test the theoretical predictions. For example, volumetric and calorimetric measurements of glassy water at different pressures will yield information on the continuity of states between supercooled and glassy water, and hence on the presence, or absence, of the proposed spinodal, critical point, etc.
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