Core-softened potentials and the anomalous properties of water

Journal of Chemical Physics

Volumn 111, Issue 19, 1999, Pages 8980-8986

  Jagla, E A ^a  

^a ABDUS SALAM INTERNATIONAL CENTRE FOR THEORETICAL PHYSICS   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001327328     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.480241     Document Type: Article

References (42)

1. Water, a Comprehensive Treatise, edited by F. Franks (Plenum, New York, 1972).
2. C. A. Angell, in Ref. 1, Vol. 7.
3. O. Mishima and H. E. Stanley, Nature (London) 396, 329 (1998).
4. P. G. Debenedetti, Metastable Liquids (Princeton University Press, Princeton, NJ, 1997).
5. C. A. Angell, Science 267, 1924 (1995).
6. R. J. Speedy, Nature (London) 380, 289 (1996).
7. R. J. Speedy and C. A. Angell, J. Chem. Phys. 65, 851 (1976).
8. O. Mishima, L. D. Calvert, and E. Whalley, Nature (London) 310, 393 (1984); 314, 76 (1995); O. Mishima, K. Takemura, and K. Aoki, Science 254, 406 (1991); O. Mishima, J. Chem. Phys. 100, 5910 (1994).
9. O. Mishima, L. D. Calvert, and E. Whalley, Nature (London) 310, 393 (1984); 314, 76 (1995); O. Mishima, K. Takemura, and K. Aoki, Science 254, 406 (1991); O. Mishima, J. Chem. Phys. 100, 5910 (1994).
10. O. Mishima, L. D. Calvert, and E. Whalley, Nature (London) 310, 393 (1984); 314, 76 (1995); O. Mishima, K. Takemura, and K. Aoki, Science 254, 406 (1991); O. Mishima, J. Chem. Phys. 100, 5910 (1994).
11. O. Mishima, L. D. Calvert, and E. Whalley, Nature (London) 310, 393 (1984); 314, 76 (1995); O. Mishima, K. Takemura, and K. Aoki, Science 254, 406 (1991); O. Mishima, J. Chem. Phys. 100, 5910 (1994).
12. R. S. Smith and B. D. Kay, Nature (London) 398, 788 (1999); R. J. Speedy et al., J. Chem. Phys. 105, 240 (1996).
13. R. S. Smith and B. D. Kay, Nature (London) 398, 788 (1999); R. J. Speedy et al., J. Chem. Phys. 105, 240 (1996).
14. P. H. Poole, F. Sciortino, U. Essmann, and H. E. Stanley, Nature (London) 360, 324 (1992).
15. P. H. Poole et al., Phys. Rev. Lett. 73, 1632 (1994).
16. H. Tanaka, Phys. Rev. Lett. 80, 5750 (1998).
17. S. Sastry, P. Debenedetti, F. Sciortino, and H. E. Stanley, Phys. Rev. E 53, 6144 (1996).
18. H. E. Stanley and J. Texeira, J. Chem. Phys. 73, 3404 (1980).
19. F. Sciortino, P. H. Poole, U. Essmann, and H. E. Stanley, Phys. Rev. E 55, 727 (1997); S. Harrington et al., Phys. Rev. Lett. 78, 2409 (1997); H. E. Stanley et al., Physica A 205, 122 (1994); 236, 19 (1997).
20. F. Sciortino, P. H. Poole, U. Essmann, and H. E. Stanley, Phys. Rev. E 55, 727 (1997); S. Harrington et al., Phys. Rev. Lett. 78, 2409 (1997); H. E. Stanley et al., Physica A 205, 122 (1994); 236, 19 (1997).
21. F. Sciortino, P. H. Poole, U. Essmann, and H. E. Stanley, Phys. Rev. E 55, 727 (1997); S. Harrington et al., Phys. Rev. Lett. 78, 2409 (1997); H. E. Stanley et al., Physica A 205, 122 (1994); 236, 19 (1997).
22. F. Sciortino, P. H. Poole, U. Essmann, and H. E. Stanley, Phys. Rev. E 55, 727 (1997); S. Harrington et al., Phys. Rev. Lett. 78, 2409 (1997); H. E. Stanley et al., Physica A 205, 122 (1994); 236, 19 (1997).
23. H. Tanaka, Nature (London) 380, 328 (1996).
24. C. J. Roberts, A. Z. Panagiotopoulus, and P. G. Debenedetti, Phys. Rev. Lett. 77, 4386 (1996); E. G. Ponyatovskii, V. V. Sinitsyn, and T. A. Pozdnyakova, JETP Lett. 60, 360 (1994); A. C. Mitus and A. Z. Patashinskii, Acta Phys. Pol. A 74, 779 (1988).
25. C. J. Roberts, A. Z. Panagiotopoulus, and P. G. Debenedetti, Phys. Rev. Lett. 77, 4386 (1996); E. G. Ponyatovskii, V. V. Sinitsyn, and T. A. Pozdnyakova, JETP Lett. 60, 360 (1994); A. C. Mitus and A. Z. Patashinskii, Acta Phys. Pol. A 74, 779 (1988).
26. C. J. Roberts, A. Z. Panagiotopoulus, and P. G. Debenedetti, Phys. Rev. Lett. 77, 4386 (1996); E. G. Ponyatovskii, V. V. Sinitsyn, and T. A. Pozdnyakova, JETP Lett. 60, 360 (1994); A. C. Mitus and A. Z. Patashinskii, Acta Phys. Pol. A 74, 779 (1988).
27. P. C. Hemmer and G. Stell, Phys. Rev. Lett. 24, 1284 (1970); G. Stell and P. C. Hemmer, J. Chem. Phys. 56, 4274 (1972).
28. P. C. Hemmer and G. Stell, Phys. Rev. Lett. 24, 1284 (1970); G. Stell and P. C. Hemmer, J. Chem. Phys. 56, 4274 (1972).
29. P. C. Hemmer and J. L. Lebowitz, in Phase Transitions and Critical Phenomena, edited by C. Domb and M. S. Green (Academic, London, 1976), Vol. 5b.
30. M. R. Sadr-Lahijany, A. Scala, S. V. Buldyrev, and H. E. Stanley, Phys. Rev. Lett. 81, 4895 (1998).
31. J. M. Kincaid, G. Stell, and E. Goldmark, J. Chem. Phys. 65, 2172 (1976).
32. E. A. Jagla, Phys. Rev. E 58, 1478 (1998).
33. E. A. Jagla, J. Chem. Phys. 110, 451 (1999).
34. R. J. Speedy, Mol. Phys. 83, 591 (1994); R. J. Speedy, J. Chem. Phys. 100, 6684 (1994).
35. R. J. Speedy, Mol. Phys. 83, 591 (1994); R. J. Speedy, J. Chem. Phys. 100, 6684 (1994).
36. l) part. Since a precise determination of this constant is difficult, and we pursue a qualitative description of the phase diagram, we took this constant to be zero, having verified that finite values do not change the qualitative characteristics of the results.
37. Reaching of metastable configuration without crystallization in this system is rather easy because of the nature of the interaction potential, that allows for the existence of competing structures, from which frustration and disorder appears [see H. Tanaka, J. Phys. C 10, L207 (1998)].
38. C. H. Cho, S. Singh, and G. W. Robinson, Phys. Rev. Lett. 76, 1651 (1996).
39. M. Campolat et al., Chem. Phys. Lett. 294, 9 (1998).
40. E. Velasco, L. Mederos, and G. Navascués, Phys. Rev. Lett. 79, 179 (1997); C. H. Cho, S. Singh, and G. W. Robinson, ibid. 79, 180 (1997).
41. E. Velasco, L. Mederos, and G. Navascués, Phys. Rev. Lett. 79, 179 (1997); C. H. Cho, S. Singh, and G. W. Robinson, ibid. 79, 180 (1997).
42. In fact, fitting of properties of water in the stable and metastable regime with expressions derived from a Landau-type theory with only one free parameter is remarkably good (see Ref. 12).