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Volumn 105, Issue 12, 1996, Pages 5099-5111

Phase behaviors of supercooled water: Reconciling a critical point of amorphous ices with spinodal instability

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EID: 18144365354     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.472354     Document Type: Article
Times cited : (144)

References (60)
  • 1
    • 0000163856 scopus 로고
    • edited by F. Franks Plenum, New York, Chap. 1
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    • (1981) Water: A Comprehensive Treatise , vol.7
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  • 18
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    • Phys. Rev. E 48, 3799 (1993).
    • (1993) Phys. Rev. E , vol.48 , pp. 3799
  • 32
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    • H. Tanaka, Nature 380, 328 (1996).
    • (1996) Nature , vol.380 , pp. 328
    • Tanaka, H.1
  • 34
    • 0003983916 scopus 로고
    • edited by M-.C. Bellissent-Funel, and J. C. Dore Kluwer, Dordrecht
    • in Hydrogen Bond Networks, edited by M-.C. Bellissent-Funel, and J. C. Dore (Kluwer, Dordrecht, 1994), pp. 3-22.
    • (1994) Hydrogen Bond Networks , pp. 3-22
  • 36
    • 34547809547 scopus 로고
    • J. Chem. Phys. 81, 511 (1984).
    • (1984) J. Chem. Phys. , vol.81 , pp. 511
  • 42
    • 85033043112 scopus 로고    scopus 로고
    • note
    • β, the critical temperature is higher by 0.3 to 0.4 K than the intersect (213 K) with atmospheric pressure line. Then, the critical pressure is not lower than -5 MPa if (dp/dT) along the coexistence line does not change from that estimated at 0.1 MPa. Even if we adopt an exponent of β=0.5 from a mean field theory, the critical pressure is not lower than -20 MPa.
  • 46
    • 33646037865 scopus 로고    scopus 로고
    • note
    • MD simulations for monatomic fluid interacting via Lennard-Jones potential have been performed at temperature 1.25 in LJ reduced unit which is just below its (gas-liquid) critical point, and at pressure 0.10. The critical temperature and pressure are 1.313 and 0.13, see J. K Johnson, J.A. Zollweg, and K.E. Gubbins, Mol. Phys. 78, 591 (1993). The density fluctuates in a range from 0.01 to 0.5 and its mean values is approximately the same as the critical density 0.3.
  • 55
    • 2742527290 scopus 로고
    • edited by H. J. White, J. V. Sengers, D. B. Neumann, and J. C. Bellows Begell House, New York
    • C. M. Sorensen, in Physical Chemistry of Aqueous Systems, edited by H. J. White, J. V. Sengers, D. B. Neumann, and J. C. Bellows (Begell House, New York, 1995), pp. 308-316.
    • (1995) Physical Chemistry of Aqueous Systems , pp. 308-316
    • Sorensen, C.M.1
  • 59
    • 85033061531 scopus 로고    scopus 로고
    • note
    • This point is not clear from only those shown in the text. In a fairly large number of molecules, only 30 cycles of the coarse graining do not take effect appreciably. When we adopt a system with smaller number of water molecules such as 64, the number of Q-structures in configuration space is rather limited and the number of structures after coarse graining is much reduced: The number of independent structures, 523 obtained from simple quenching was much reduced to 113 after 50 cycles of coarse graining when the number of water molecules was 64. See Ref. 52.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.