Formic acid adsorption on anatase TiO2(001)-(1 × 4) thin films studied by NC-AFM and STM

Journal of Physical Chemistry B

Volumn 106, Issue 33, 2002, Pages 8211-8222

  Tanner, Robert E ^a   Sasahara, Akira ^b   Liang, Yong ^c   Altman, Eric I ^a   Onishi, Hiroshi ^b  

^a Yale University   (United States)

^b KANAGAWA ACADEMY OF SCIENCE AND TECHNOLOGY   (Japan)

^c PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^d MOTOROLA INC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ATOMIC FORCE MICROSCOPY; CARBOXYLIC ACIDS; SCANNING TUNNELING MICROSCOPY; SURFACE TOPOGRAPHY; TITANIUM DIOXIDE;

ELECTRONIC EFFECTS;

THIN FILMS;

EID: 0037158934     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp020617y     Document Type: Article

References (62)

1. Gusmano, G.; Montesperelli, G.; Nunziante, P.; Traversa, E.; Montenero, A.; Braghini, M.; Mattogno, G.; Bearzotti, A. Humidity-Sensitive Properties of Titania Films Prepared using the Sol-Gel Process. J. Ceram. Soc. Jpn. 1993, 101, 1095-1100.
2. (x) Monitoring. Sens. Actuators B 1993, 16, 245-248.
3. 2 Films. Thin Solid Films 1983, 109, 169-178.
4. 2 Coatings on Silica Slabs and Fibres. J. Mater. Sci. 1992, 27, 2549-2555.
5. Brown, W.D.; Grannemann, W.W. C-V Characteristics of Metal-Titanium Dioxide-Silicon Capacitors. Solid State Electron. 1978, 21, 837-846.
6. Kingon, A.I.; Maria, J.P.; Streiffer, S.K. Alternative Dielectrics to Silicon Dioxide for Memory and Logic Devices. Nature 2000, 406, 1032-1038.
7. Ebert, R.; Schaldach, M. Proceedings of the World Congress on Medical Phsyics and Biomedical Engineering, Hamburg 1982 3.07.
8. Huang, N.; Chen, Y.R.; Luo, J.M.; Li, J.; Lu, R.; Xiao, J.; Xue, Z.N.; Liu, X.H. In-Vitro Investigation of Blood Compatibility of Titanium with Oxide Layers of Rutile Stucture. J. Biomater. Appl. 1994, 8, 404-412.
9. Wang, X.H.; Zhang, F.; Li, C.R.; Zheng, Z.H.; Wang, X.; Liu, X.H.; Chen, A.Q.; Jiang, Z.B. Improvement of Blood Compatibility of Artificial Heart Valves via Titanium Oxide Film Coated on Low-Temperamre Isotropic Carbon. Surf. Coat. Technol. 2000, 128, 36-42.
10. Fujishima, A.; Honda, K. Electrochemical Photolysis of Water at a Semiconductor Electrode. Nature 1972, 238, 37-38.
11. 2 Films. Nature 1991, 353, 737-740.
12. Butter, M.A.; Ginley, D.S. Review: Principles of Photoelectro-chemical Sloar Energy Conversion. J. Mater. Sci. 1980, 15, 1-19.
13. Kavan, L.; Grätzel, M.; Gilbert, S.E.; Klemenz, C.; Scheel, H. J. Electrochemical and Photoelectrochemical Investigation of Single-Crystal Anatase. J. Am. Chem. Soc. 1996, 118, 6716-6723.
14. 2 Particles. Angew. Chimie 1994, 33, 1091-1092.
15. 2 Particles. Angew. Chimie 1994, 33, 1091-1092.
16. 2 Photocatalytic Oxidation Technology on the SW-31 Spring at the East Tennessee Technology Park (ETTP), Oak Ridge, Tennessee, http://www.ornl.gov/K25/techdemo/epasite.htm.
17. Remillard, J.T.; McBride, J.R.; Nietering, K.E.; Drews, A.R.; Zhang, X. Real Time in situ Spectroscopic Ellipsometry Studies of the Photocatalytic Oxidation of Stearic Acid on Titania Films. J. Phys. Chem. B 2000, 104, 4440-4447.
18. Zhang, H.; Banfield, J.F. Thermodynamic Analysis of Phase Stability of Nanocrystalline Titania. J. Mater. Chem. 1998, 8, 2073-2076.
19. Chambers, S.A. Epitaxial Growth and Properties of Thin Film Oxides. Surf. Sci. Rep. 2000, 39, 105-180.
20. 2(001). Surf. Sci. 2000, 447, 201-211.
21. Gao, Y.; Herman, G.S. Growth of Epitaxial Anatase (001) and (101) Films. Thin Solid Films 2001, 397, 157-161.
22. 2(001): Reconstruction, Atomic Steps, and Domains. Phys. Rev. B 2001, 63, 5402.
23. 3 Substrate by Laser Molecular-Beam Epitaxy. Appl. Phys. Lett. 2001, 78, 2664-2666.
24. 2(001) Surface. Phys. Rev. Lett. 2000, 84, 3354-3357.
25. 2(001). Surf. Sci. 2002, 506, 251-271.
26. 2(101) and (001) Surfaces. Surf. Sci. 2000, 460, 162-169.
27. Fahmi, A.; Minot, C.; Silvi, B.; Causá, M. Theoretical Analysis of the Structures of Titanimn Dioxide Crystals. Phys. Rev. B 1993, 47, 11717-11724.
28. Stashans, A.; Lunell, S.; Bergström, R.; Hagfeldt, A.; Lindquist, S.-E. Theoretical Study of Lithium Intercalation in Rutile and Anatase. Phys. Rev. B 1996, 53, 159-170.
29. 2 Crystals. J. Phys. Chem. Solids 1996, 9, 1293-1301.
30. 2. Surf. Sci. 2001, 490, 116-124.
31. Fahmi, A.; Minot, C. A Theoretical Investigation of Water Adsorption in Titanium Dioxide Surfaces. Surf. Sci. 1994, 304, 343-359.
32. 2 Polymorphs Rutile and Anatase. J. Mater. Chem. 1997, 7, 563-568.
33. 2 Anatase (101) and (001) Surfaces. Phys. Rev. Lett. 1998, 81, 2954-2957.
34. 2 Anatase Surfaces. Phys. Rev. B 2001, 63, 5409.
35. 2(001)-(1 × 4) Surface. Phys. Rev. Lett. 2001, 87, 6105.
36. 2(110) Surface. Chem. Phys. Lett. 1994, 226, 111-114.
37. 60 Molecules Deposited on Si(111) by Noncontact Atomic Force Microscopy. Appl. Surf. Sci. 1999, 140, 281-286.
38. 2(110) Determined by Scanning Tunneling Microscopy-A New Surface-Limited Phase of Titanium Oxide. Bull. Chem. Soc. Jpn. 1995, 68, 2447-2458.
39. 2(110)-(1 × 2). Phys. Rev. B 1998, 58, 1586-1589.
40. 2(110): Surface Rearrangement and Reactivity Studies using Elevated Temperature Scanning Tunneling Microscopy.
41. 2(110) Surface: A Comprehensive Study. Surf. Sci. 1999, 437, 173-190.
42. 2(110) using Low-Density Electron-Beams. Surf. Sci. 1994, 320, 295-306.
43. 2 Surfaces: Diffusion of Oxygen to the Surface or Titanium to the Bulk? Surf. Sci. 1995, 343, L1156-L1160.
44. Onishi, H.; Iwasawa, Y. Dynamic Visualisation of a Metal Oxide Surface/Gas-Phase Reaction: Time-Resolved Observation by Scanning Tunneling Microscopy at 800 K. Phy. Rev. Lett. 1996, 76, 791-794.
45. Onishi, H.; Iwasawa, Y. STM Observation of Surface Reactions on a Metal Oxide. Surf. Sci. 1996, 357/358, 773-776.
46. 3(001) Surface: A Comprehensive Study of Oxidation and Reduction by Scanning Tunneling Microscopy and Low-Energy Electron Diffraction. J. Vac. Sci. Technol. A 2001, 19, 1502-1509.
47. 2(110) Surface. Surf. Sci. 1998, 412-413, 672-681.
48. th ed.; John Wiley and Sons: New York, 1998.
49. 2(110)-(1 × 1) Surface and their Reaction with Oxygen: A Scanning Tunnelling Microscopy Study. Surf. Sci. 1998, 411, 137-153.
50. 2(110). Appl. Surf. Sci. 2002, in press.
51. 2(110) Surface by Noncontact Atomic Force Microscopy. Chem. Phys. Lett. 1997, 280, 296-301.
52. 2(110). Appl. Phys. A 2001, 72, S101-S103.
53. 2(110) Surface by Noncontact Atomic Force Microscopy. Phys. Rev. Lett. 1997, 79, 4202-4205.
54. 2(110). Surf. Sci. 2000, 454-456, 390-395.
55. 2(110)-(1 × 1) and -(1 × 2) Surfaces with Acetic Acid Adsorption-A PES Study. Surf. Sci. 1997, 377-379, 135-139.
56. 2(110). J. Phys. Chem. B 1999, 103, 203-208.
57. 2(110). Surf. Sci. 2001, 471, 163-169.
58. 2 (Anatase). Kinetics and Catalysis 2000, 41, 805-811.
59. 2. Langmuir 1988, 4, 945-953.
60. 2(001) Surfaces. Langmuir 1990, 6, 1485-1488.
61. 2(001) Single-Crystal Surfaces. J. Catal. 1990, 125, 353-375.
62. 2(001) Surfaces. Surf. Sci. 1996, 348, 39-48.