Kinetics and mechanism of the formation of nitroprusside from aquapentacyanoferrate(III) and NO: Complex formation controlled by outer-sphere electron transfer

Inorganic Chemistry

Volumn 41, Issue 21, 2002, Pages 5417-5425

  Roncaroli, Federico ^a,b   Olabe, Jose A ^b   van Eldik, Rudi ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b UNIVERSIDAD DE BUENOS AIRES   (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

AQUAPENTACYANOFERRATE; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; FERRIC ION; IRON DERIVATIVE; NITRIC OXIDE; NITROPRUSSIDE SODIUM; PENTACYANOFERRATE (III); PYRAZINE DERIVATIVE; SCAVENGER; THIOCYANIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

ALGORITHM; ARTICLE; CHEMICAL REACTION; CHEMISTRY; COMPLEX FORMATION; DISSOCIATION; ELECTRON TRANSPORT; KINETICS; OXIDATION REDUCTION REACTION; PH; SYNTHESIS; TEMPERATURE DEPENDENCE;

ALGORITHMS; ELECTRON TRANSPORT; FERRIC COMPOUNDS; INDICATORS AND REAGENTS; KINETICS; NITRIC OXIDE; NITROPRUSSIDE; OXIDATION-REDUCTION;

EID: 0037152367     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic020288o     Document Type: Article

References (55)

1. Richter-Addo, G. B.; Legzdins, P. Metal Nitrosyls; Oxford University Press: New York, 1992.
2. Feelish, M., Stamler, J. S., Eds. Methods in Nitric Oxide Research; Wiley: Chichester, England, 1996; and references therein.
3. Lancaster, J., Jr., Ed. Nitric Oxide, Principles and Actions; Academic Press: New York, 1996.
4. Ignarro, L. J. A. Rev. Pharmacol. Toxicol. 1990, 30, 535.
5. Moncada, S. M.; Palmer, R. M.; Higgins, E. A. Biochem. Pharmacol. 1989, 38, 1709.
6. Bredt, D. S.; Hwang, P. M.; Glatt, C. E.; Lowenstein, C.; Reed, R. R.; Snyder, S. H. Nature 1991, 351, 714.
7. Butler, A. R.; Lyn D.; Williams, H. Chem. Soc. Rev. 1993, 22, 233.
8. Stamler, J. S.; Jia, L.; Eu, J. R.; McMahon, T. J.; Demchenko, I. T.; Bonaventura, J.; Gernert, K.; Piantodosi, C. A. Science 1997, 276, 2034.
9. Kamaluddin; Nath, M.; Deopujari, S. Origins Life Evol. Biosphere 1988, 18, 267.
10. Ford, P. C.; Lorkovic, I. M. Chem. Rev. 2002, 102, 993.
11. (a) Armor, J. N.; Scheidegger, H. A.; Taube, H. J. Ant. Chem. Soc. 1968, 90, 5928.
12. (b) Armor, J. N.; Pell, S. D. J. Am. Chem. Soc. 1973, 95, 7625.
13. Hoshino, M.; Laverman, L.; Ford, P. C.Coord. Chem. Rev. 1999, 187, 75-102.
14. (a) Laverman. L.; Ford, P. C. J. Am. Chem. Soc. 2001, 123, 11614.
15. (b) Laverman, L.; Wanat, A.; Oszajca, J.; Stochel, G.; Ford, P.; van Eldik. R. J. Am. Chem. Soc. 2001, 123, 285.
16. (a) Schneppensieper, T.; Wanat, A.; Stochel, G.; Goldstein, S.; Meyerstein, D.; van Eldik, R. Eur. J. Inorg. Chem. 2001, 2317.
17. (b) Wolak, M.; Zahl, A.; Schneppensieper, T.; Stochel, G.; van Eldik, R. J. Am. Chem. Soc. 2001, 123, 9780.
18. Schneppensieper, T.; Zahl, A.; van Eldik, R. Angew. Chem., Int. Ed. 2001, 40, 1678.
19. Bohle, D. S.; Hung, C. H. J. Am. Chem. Soc. 1995, 117, 9584.
20. Wanat, A.; Schneppensieper, T.; Stochel, G.; van Eldik, R.; Bill, E.; Wieghardt, K. Inorg. Chem. 2002, 41, 4.
21. Morando, P. J.; Borghi, E. B.; Schteingart, L. M.; Blesa, M. A. J. Chem. Soc., Dalton Trans. 1981, 435.
22. Butler, A. R. Chem. Soc. Rev. 1987, 16, 361.
23. Stamler, J. S. in Biochemical, Pharmacological and Clinical Aspects of Nitric Oxide: Weissman B. A., Allan, N., Shapira, S., Eds.; Plenum: New York, 1995: p 67.
24. Stamler, J. S.; Singel, D. J.; Loscalzo, J. Science 1992, 258, 1898.
25. Wolfe S. K.; Swinehart, J. H. Inorg. Chem. 1975, 14, 1049.
26. (a) Sharpe, A. G. The Chemistry of Cyano Complexes of the Transition Metals; Academic Press: London, 1976.
27. (b) Macartney, D. H. Rev. Inorg. Chem. 1988, 9, 101.
28. (c) Baraldo, L. M.; Forlano, P.; Parise, A. R.; Slep, L. D.; Olabe, J. A. Coord. Chem. Rev. 2001. 219-221, 881.
29. (a) James, A. D.; Murray, R. S. J. Chem. Soc., Dalton Trans. 1977, 326.
30. (b) James, A. D.; Murray, R. S.; Higginson, W. C. E. J. Chem. Soc., Dalton Trans. 1974, 1273.
31. Stochel, G.; van Eldik, R. Inorg. Chim. Acta 1991, 190, 55.
32. Hejmo, E.; Porcel-Ortega, E.; Senkowski, T.; Stasicka, Z. Bull. Pol. Acad. Sci. 1988, 36, 351.
33. Toma, E. H.; Malin, J. M. Inorg. Chem. 1973, 12, 1039, 2080.
34. Stochel, G.; van Eldik, R.; Hejmo, E.; Stasicka, Z. Inorg. Chem. 1988, 27, 2767.
35. Szacilowski, K.; Stochel, G.; Stasicka. Z.; Kisch, H. New J. Chem. 1997, 21, 893.
36. van Eldik, R.; Gaede, W.; Wieland, S.; Kraft, J.; Spitzer, M.; Palmer, D. A. Rev. Sci. Instrum. 1993, 64, 1355.
37. (a) Binstead, R. A.; Zuberbulher, A. D. SPECFIT; Spectrum Software Associates: Chapel Hill, NC, 1993-1999.
38. (b) Zuberbuhler, A. D. Anal Chem. 1990, 62, 2220.
39. Espenson, J. H.; Wolenuk, S. G. Inorg. Chem. 1972, 11, 2034.
40. Manoharan, P. T.; Gray, H. B. Inorg. Chem. 1966, 5, 823.
41. Paliani, G.; Poletti, A.; Santucci, A. J. Mol. Struct. 1971, 8, 63.
42. Enemark, J. H.; Feltham, R. D. Coord. Chem. Rev. 1974, 13, 339.
43. Toma, H. E.; Batista, A. A.; Gray, H. B. J. Am. Chem. Soc. 1982, 104, 7509.
44. Ridd, J. H. Adv. Phys. Org. Chem. 1979, 16, 1.
45. Bradic, Z.; Pribanic, M.; Asperger, S. J. Chem. Soc., Dalton Trans. 1975, 353.
46. Cheney, R. P.; Simic, M. G.; Hoffman, M. Z.; Taub, I. A.; Asmus, K. D. Inorg. Chem. 1977, 16, 2187.
47. Masek, J.; Wendt, H. Inorg. Chim. Acta 1969, 3, 455.
48. Maciejoska, I.; Stasicka, Z.; Stochel, G.; van Eldik. R. J. Chem. Soc., Dalton Trans. 1999, 3643.
49. Wanat A.; van Eldik, R.; Stochel, G. J. Chem. Soc., Dalton Trans. 1998, 2497.
50. Ilkowska, E.; Lewinski, K.; van Eldik, R.; Stochel, G. J. Biol. Inorg. Chem. 1999, 4, 302.
51. Ball, M. C.; Norbury, A. H. Physical Data for Inorganic Chemists; Longman: Essex, U.K., 1974.
52. 2H absorptions appearing in the UV region, for experiments made at pH 3.0. This complication still allowed reliable kinetic measurements.
53. Toma, E. H.; Malin, J. M. J. Am. Chem. Soc. 1975, 97, 288.
54. Souto, M. F.; Cukiernik, F. D.; Forlano, P.; Olabe, J. A. J. Coord. Chem. 2001, 54, 343.
55. + conversion at the iron(II) center drives the real potential toward more positive values.