Water exchange controls the complex-formation mechanism of water-soluble iron(III) porphyrins: Conclusive evidence for dissociative water exchange from a high-pressure 17O NMR study

Angewandte Chemie - International Edition

Volumn 40, Issue 9, 2001, Pages 1678-1680

  Schneppensieper, Thorsten ^a   Zahl, Achim ^a   Van Eldik, Rudi ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

High pressure chemistry; Iron; NMR spectroscopy; Porphyrinoids; Water exchange

Indexed keywords

CHEMICAL ACTIVATION; ENTROPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PORPHYRINS;

WATER-EXCHANGE REACTIONS;

IRON COMPOUNDS;

IRON; LIGAND; OXYGEN 17; PORPHYRIN; WATER;

ARTICLE; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; DISSOCIATION; ENTROPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRESSURE; SOLUBILIZATION; TEMPERATURE DEPENDENCE; WATER TRANSPORT;

EID: 0035805268     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20010504)40:9<1678::AID-ANIE16780>3.0.CO;2-A     Document Type: Article

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