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It has been reported that nonaflates are less susceptible than inflates to nucleophilic attack at the sulfur atom, which we believe to be the source of undesired phenol formation. See: Neuville, L.; Bigot, A.; Dau, M. E. T. H.; Zhu, J. J. Org. Chem. 1999, 64, 7638.
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0043272119
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36
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0042269618
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note
-
Lower yields of these couplings result from problematic separation of the hydrocarbon product from the polymethylsiloxane byproducts.
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37
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0042269617
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note
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3e
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