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Volumn 8, Issue 24, 2002, Pages 5709-5722

Iron carbonyl, nitrosyl, and nitro complexes of a tetrapodal pentadentate amine ligand: Synthesis, electronic structure, and nitrite reductase-like reactivity

Author keywords

Chelates; Iron; N ligands; Nitrite reductase

Indexed keywords

COMPLEXATION; ELECTRONIC STRUCTURE; HYDROLYSIS; IRON COMPOUNDS; MOSSBAUER SPECTROSCOPY; OXIDATION; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL);

EID: 0037122243     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20021216)8:24<5709::AID-CHEM5709>3.0.CO;2-I     Document Type: Article
Times cited : (59)

References (86)
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    • III couple is sufficiently negative in this case, favouring the formation of a well-defined iron(III) complex over oxidative destruction of the amine ligand: see P. V. Bernhardt, T. Hambley, G. A. Lawrance, J. Chem. Soc. Chem. Commun. 1989, 553-554.
    • (2002) Inorg. Chem. Commun.
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  • 23
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    • III couple is sufficiently negative in this case, favouring the formation of a well-defined iron(III) complex over oxidative destruction of the amine ligand: see P. V. Bernhardt, T. Hambley, G. A. Lawrance, J. Chem. Soc. Chem. Commun. 1989, 553-554.
    • (1989) J. Chem. Soc. Chem. Commun. , pp. 553-554
    • Bernhardt, P.V.1    Hambley, T.2    Lawrance, G.A.3
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    • 0348204606 scopus 로고    scopus 로고
    • note
    • 2 to a stirred suspension of 3 in the same solvent, and removal of the the precipitated NaBr by filtration after about 30 min.
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    • note
    • 2, see ref. [22].
  • 49
    • 0000971074 scopus 로고    scopus 로고
    • Wiley-VCH, Weinheim
    • Pyridine is a weak π-acceptor: L. H. Gade, Koordinationschemie, Wiley-VCH, Weinheim 1998, p. 108; D. A. House, J. Browning, L. Zipper, W. Marty, Inorg. Chim. Acta 1999, 288, 181-188.
    • (1998) Koordinationschemie , pp. 108
    • Gade, L.H.1
  • 55
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    • III/NO coordination, see: A. K. Patra, R. Afshar, M. M. Olmstead, P. K. Mascharak, Angew. Chem. 2002, 114, 2622-2625; Angew. Chem. Int. Ed. 2002, 41, 2512-2515.
    • (2002) Angew. Chem. Int. Ed. , vol.41 , pp. 2512-2515
  • 60
    • 4243616042 scopus 로고
    • This bonding description is based on molecular orbital correlation diagrams that examine the nature of the highest-occupied molecular. orbital in order to ascertain the structural consequences fo the M(NO) moiety: J. H. Enemark, R. D. Feltham, Coord. Chem. Rev. 1974, 13, 339-406.
    • (1974) Coord. Chem. Rev. , vol.13 , pp. 339-406
    • Enemark, J.H.1    Feltham, R.D.2
  • 81
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    • (Eds.: P. Jensen ,P.R. Bunker), Wiley, Chichester
    • J. M. Brown in Computational Molecular Spectroscopy (Eds.: P. Jensen, P. R. Bunker), Wiley, Chichester, 2000, p. 518.
    • (2000) Computational Molecular Spectroscopy , pp. 518
    • Brown, J.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.