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Volumn 39, Issue 4, 2000, Pages 632-633

Reactivity of the iron porphyrin Fe(TPP)(NO) with excess no. Formation of Fe(TPP)(NO (NO2) occurs via reaction with trace NO2

Author keywords

[No Author keywords available]

Indexed keywords

METALLOPORPHYRIN; NITRIC OXIDE; NITROGEN DIOXIDE; NITRONITROSYL(MESO TETRAPHENYLPORPHYRINATO)IRON(II); NITRONITROSYL(MESO-TETRAPHENYLPORPHYRINATO)IRON(II); NITROSYL(MESO TETRAPHENYLPORPHYRINATO)IRON(II); NITROSYL(MESO-TETRAPHENYLPORPHYRINATO)IRON(II); PORPHYRIN; RUTHENIUM; TRACE ELEMENT;

EID: 0034695860     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9910413     Document Type: Article
Times cited : (58)

References (26)
  • 2
    • 12944325649 scopus 로고    scopus 로고
    • Chapter 33. Academic Press: Kadish, K. M., Smith, K. M., Guilard, R., Eds.; New York, in press. Personal communication from G. B. Richter-Addo
    • (b) Cheng, L.; Richter-Addo, G. B. Chapter 33. In The Prophyrin Handbook; Academic Press: Kadish, K. M., Smith, K. M., Guilard, R., Eds.; New York, in press. Personal communication from G. B. Richter-Addo.
    • The Prophyrin Handbook
    • Cheng, L.1    Richter-Addo, G.B.2
  • 10
    • 12944308674 scopus 로고    scopus 로고
    • note
    • 3. Warning: at -78°C, considerable NO absorbs in the column and precaution should be taken for the controlled NO release when the system warms to room temperature. Solutions were prepared and transferred to cells with gastight syringes inside an inert atmosphere "drybox". Materials in contact with NO solutions (septa, stopcocks, and plungers) were deaerated by storage in the drybox for at least 18 h prior to solution exposure.
  • 11
    • 12944303991 scopus 로고    scopus 로고
    • note
    • 8b who presented evidence that low-T toluene solutions of 1 under NO demonstrate reversible changes in the EPR and optical spectra consistent with the formation of the dinitrosyl. NMR experiments in this laboratory are in agreement with the observation that such a species may be formed at low temperature but not at ambient temperature. It is also notable that there were no indications in Wayland's spectra that 1 reacts further with NO to give 2 at room or lower T.
  • 19
    • 12944299646 scopus 로고    scopus 로고
    • note
    • 3 must have a larger value in the former.
  • 25
    • 12944325152 scopus 로고    scopus 로고
    • note
    • 2O may interact with 1 to inhibit its reactivity with NO. However, solutions of 1 plus NO prepared in an oven-dried silanized UV/vis cell by vacuum line transfer of toluene from highly activated 3 Å molecular sieves (to minimize such traces) demonstrated no differences in reactivity.
  • 26
    • 12944321216 scopus 로고    scopus 로고
    • Personal communication
    • (b) Farmer, P. J. Personal communication.
    • Farmer, P.J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.