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Reviews: (a) Chauvin, Y.; Olivier-Bourbigou, H. Chemtech 1995, 25, 26-30; (b) Welton, T. Chem. Rev. 1999, 99, 2071-2083; (c) Olivier, H. J. Mol. Catal. A: Chem. 1999, 146, 285-289; (d) Holbrey, J. D.; Seddon, K. R. Clean Products and Processes 1999, 1, 223-236; (e) Dupont, J.; Consorti, C. S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337-344; (f) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772-3789; (g) Freemantle, M. Chem. Eng. News 2001, 79, 21-25; (h) Sheldon, R. Chem. Commun. 2001, 2399-2407; (i) Olivier-Bourbigou, H.; Magna, L. J. Mol. Catal. A: Chem. 2002, 182-183, 419-437.
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Reviews: (a) Chauvin, Y.; Olivier-Bourbigou, H. Chemtech 1995, 25, 26-30; (b) Welton, T. Chem. Rev. 1999, 99, 2071-2083; (c) Olivier, H. J. Mol. Catal. A: Chem. 1999, 146, 285-289; (d) Holbrey, J. D.; Seddon, K. R. Clean Products and Processes 1999, 1, 223-236; (e) Dupont, J.; Consorti, C. S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337-344; (f) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772-3789; (g) Freemantle, M. Chem. Eng. News 2001, 79, 21-25; (h) Sheldon, R. Chem. Commun. 2001, 2399-2407; (i) Olivier-Bourbigou, H.; Magna, L. J. Mol. Catal. A: Chem. 2002, 182-183, 419-437.
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Reviews: (a) Chauvin, Y.; Olivier-Bourbigou, H. Chemtech 1995, 25, 26-30; (b) Welton, T. Chem. Rev. 1999, 99, 2071-2083; (c) Olivier, H. J. Mol. Catal. A: Chem. 1999, 146, 285-289; (d) Holbrey, J. D.; Seddon, K. R. Clean Products and Processes 1999, 1, 223-236; (e) Dupont, J.; Consorti, C. S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337-344; (f) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772-3789; (g) Freemantle, M. Chem. Eng. News 2001, 79, 21-25; (h) Sheldon, R. Chem. Commun. 2001, 2399-2407; (i) Olivier-Bourbigou, H.; Magna, L. J. Mol. Catal. A: Chem. 2002, 182-183, 419-437.
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Reviews: (a) Chauvin, Y.; Olivier-Bourbigou, H. Chemtech 1995, 25, 26-30; (b) Welton, T. Chem. Rev. 1999, 99, 2071-2083; (c) Olivier, H. J. Mol. Catal. A: Chem. 1999, 146, 285-289; (d) Holbrey, J. D.; Seddon, K. R. Clean Products and Processes 1999, 1, 223-236; (e) Dupont, J.; Consorti, C. S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337-344; (f) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772-3789; (g) Freemantle, M. Chem. Eng. News 2001, 79, 21-25; (h) Sheldon, R. Chem. Commun. 2001, 2399-2407; (i) Olivier-Bourbigou, H.; Magna, L. J. Mol. Catal. A: Chem. 2002, 182-183, 419-437.
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Holbrey, J.D.1
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Reviews: (a) Chauvin, Y.; Olivier-Bourbigou, H. Chemtech 1995, 25, 26-30; (b) Welton, T. Chem. Rev. 1999, 99, 2071-2083; (c) Olivier, H. J. Mol. Catal. A: Chem. 1999, 146, 285-289; (d) Holbrey, J. D.; Seddon, K. R. Clean Products and Processes 1999, 1, 223-236; (e) Dupont, J.; Consorti, C. S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337-344; (f) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772-3789; (g) Freemantle, M. Chem. Eng. News 2001, 79, 21-25; (h) Sheldon, R. Chem. Commun. 2001, 2399-2407; (i) Olivier-Bourbigou, H.; Magna, L. J. Mol. Catal. A: Chem. 2002, 182-183, 419-437.
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Reviews: (a) Chauvin, Y.; Olivier-Bourbigou, H. Chemtech 1995, 25, 26-30; (b) Welton, T. Chem. Rev. 1999, 99, 2071-2083; (c) Olivier, H. J. Mol. Catal. A: Chem. 1999, 146, 285-289; (d) Holbrey, J. D.; Seddon, K. R. Clean Products and Processes 1999, 1, 223-236; (e) Dupont, J.; Consorti, C. S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337-344; (f) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772-3789; (g) Freemantle, M. Chem. Eng. News 2001, 79, 21-25; (h) Sheldon, R. Chem. Commun. 2001, 2399-2407; (i) Olivier-Bourbigou, H.; Magna, L. J. Mol. Catal. A: Chem. 2002, 182-183, 419-437.
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Reviews: (a) Chauvin, Y.; Olivier-Bourbigou, H. Chemtech 1995, 25, 26-30; (b) Welton, T. Chem. Rev. 1999, 99, 2071-2083; (c) Olivier, H. J. Mol. Catal. A: Chem. 1999, 146, 285-289; (d) Holbrey, J. D.; Seddon, K. R. Clean Products and Processes 1999, 1, 223-236; (e) Dupont, J.; Consorti, C. S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337-344; (f) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772-3789; (g) Freemantle, M. Chem. Eng. News 2001, 79, 21-25; (h) Sheldon, R. Chem. Commun. 2001, 2399-2407; (i) Olivier-Bourbigou, H.; Magna, L. J. Mol. Catal. A: Chem. 2002, 182-183, 419-437.
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Chem. Eng. News
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Reviews: (a) Chauvin, Y.; Olivier-Bourbigou, H. Chemtech 1995, 25, 26-30; (b) Welton, T. Chem. Rev. 1999, 99, 2071-2083; (c) Olivier, H. J. Mol. Catal. A: Chem. 1999, 146, 285-289; (d) Holbrey, J. D.; Seddon, K. R. Clean Products and Processes 1999, 1, 223-236; (e) Dupont, J.; Consorti, C. S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337-344; (f) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772-3789; (g) Freemantle, M. Chem. Eng. News 2001, 79, 21-25; (h) Sheldon, R. Chem. Commun. 2001, 2399-2407; (i) Olivier-Bourbigou, H.; Magna, L. J. Mol. Catal. A: Chem. 2002, 182-183, 419-437.
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Chem. Commun.
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Sheldon, R.1
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Reviews: (a) Chauvin, Y.; Olivier-Bourbigou, H. Chemtech 1995, 25, 26-30; (b) Welton, T. Chem. Rev. 1999, 99, 2071-2083; (c) Olivier, H. J. Mol. Catal. A: Chem. 1999, 146, 285-289; (d) Holbrey, J. D.; Seddon, K. R. Clean Products and Processes 1999, 1, 223-236; (e) Dupont, J.; Consorti, C. S.; Spencer, J. J. Braz. Chem. Soc. 2000, 11, 337-344; (f) Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772-3789; (g) Freemantle, M. Chem. Eng. News 2001, 79, 21-25; (h) Sheldon, R. Chem. Commun. 2001, 2399-2407; (i) Olivier-Bourbigou, H.; Magna, L. J. Mol. Catal. A: Chem. 2002, 182-183, 419-437.
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J. Mol. Catal. A: Chem.
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Olivier-Bourbigou, H.1
Magna, L.2
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Bouquillon S., du Moulinet d'Hardemare A., Averbuch-Pouchot M.-Th., Hénin F., Muzart J. Polyhedron. 18:1999;3511-3516.
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Polyhedron
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Du Moulinet d'Hardemare, A.2
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Bouquillon S., Ganchegui B., Estrine B., Hénin F., Muzart J. J. Organomet. Chem. 634:2001;153-156.
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Bortolo R., Bianchi D., D'Alosio R., Querci C., Ricci M. J. Mol. Catal. A: Chem. 153:2000;25-29.
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J. Mol. Catal. A: Chem.
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Bortolo, R.1
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D'Alosio, R.3
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Ricci, M.5
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. The addition of tetraalkylammonium salts in ruthenium-catalyzed oxidations of alcohols has allowed the recovery of the catalyst but methylene chloride was used as solvent. See: Ley S.V., Ramarao C., Smith M.D. Chem. Commun. 2001;2278-2279.
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(2001)
Chem. Commun.
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Ley, S.V.1
Ramarao, C.2
Smith, M.D.3
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57249113610
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. For a Wacker-type reaction, see: Namboodiri V.V., Varma R.S., Sahle-Demessie E., Pillai U.R. Green Chem. 4:2002;170-173.
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Green Chem.
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Namboodiri, V.V.1
Varma, R.S.2
Sahle-Demessie, E.3
Pillai, U.R.4
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0011225164
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4a,6,7
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4a,6,7.
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37
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0011166092
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6): 1-butyl-3-methylimidazolium hexafluorophosphate
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6): 1-butyl-3-methylimidazolium hexafluorophosphate.
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40
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0011247808
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note
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4NBr (1.5 g). The system was connected to a vacuum/argon line and the flask was heated under vacuum at 120°C (oil bath) for 2 h. After switching to the argon line, indan-1-ol (134 mg, 1 mmol) was introduced and the temperature of the oil bath was maintained at 120°C for 22 h. After removing the oil bath, diethyl ether (5 ml) was added by the top of the condenser. The mixture was stirred for a few minutes and then poured on a sintered-glass frit. The flask was washed with diethyl ether and the solid carefully triturated with the same solvent (2 ml×5). GC analysis (capillary column HP-Innowax, 170°C, dec-9-en-1-ol as internal standard) of the solution showed the complete conversion of the substrate and the formation of indan-1-one (95%).
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42
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0011166388
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Low amounts of 2 were also obtained from a DMF solution of 1 heated at 120°C for 21 h (Conv.: 9%, yield: 7%)
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Low amounts of 2 were also obtained from a DMF solution of 1 heated at 120°C for 21 h (Conv.: 9%, yield: 7%).
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43
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0011170625
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4NBr
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3.
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44
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0037181029
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The formation of esters from aldehyde insertion into rhodium-alkoxide complexes and subsequent β-H elimination has been recently reported. See: Krug C., Hartwig J.F. J. Am. Chem. Soc. 124:2002;1674-1679.
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(2002)
J. Am. Chem. Soc.
, vol.124
, pp. 1674-1679
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Krug, C.1
Hartwig, J.F.2
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