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Volumn 41, Issue 19, 2002, Pages 3592-3595

The elusive terminal imido of manganese(v)

Author keywords

Azides; Corroles; Manganese; Multiple bonds; Photolysis

Indexed keywords

AMINATION; ELECTRONS; PHOTOLYSIS; SYNTHESIS (CHEMICAL);

EID: 0037020398     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20021004)41:19<3591::aid-anie3591>3.0.co;2-z     Document Type: Article
Times cited : (63)

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    • note
    • -3. CCDC-191398 (2) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road. Cambridge CB21EZ, UK; fax: (+44) 1223-336-033; or deposit @ccdc.cam.ac.uk).
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    • a) For the first report on the use of a transition-metal catalyst, copper, for azirdination with an organic azide, see: H. Kwart, A. A. Kahn, J. Am. Chem. Soc. 1967, 89, 1951. Four products were formed, and the yield of aziridine was only 15%;
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    • II-porphyrin catalysts for aziridination with organic azides, see: S. Cenini, S. Tollari, A. Penoni, C. Cereda, J. Mol. Catal. A 1999, 137, 135. The aziridine yields are low. ≈30% at best.
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