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2N=IPh increased the rate of aziridine formation. These observations suggest that electronic factors play a crucial role in the formation of the probable nitrenoid species. For similar notes and procedures for preparing the nitrene precursors, see: M. J. Södergren, D. A. Alonso, A. V. Bedekar and P. G. Andersson, Tetrahedron Lett., 1997, 39, 6897.
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(b) In our case, addition of 4-phenylpyridine N-oxide resulted in lower yield and enantioselectivity with both catalysts.
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