메뉴 건너뛰기




Volumn 37, Issue 12, 1998, Pages 3107-3110

Electronic Structures of Nitridomanganese(V) Complexes

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001603124     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970598k     Document Type: Article
Times cited : (34)

References (50)
  • 22
    • 85174988245 scopus 로고    scopus 로고
    • note
    • Salen = N,N′-ethylenebis(salicylideneaminato) dianion; 1S,2S-(-)-saldpen = N,N′-(1S,2S-(-)-diphenyl)ethylenebis(salicylideneaminato) dianion; 1R,2R-(+)-saldpen = N,N′-(1R,2R-(+)-diphenyl)ethylenebis- (salicylideneaminato) dianion.
  • 28
    • 0002541481 scopus 로고
    • Universität Göttingen: Göttingen, Germany
    • Sheldrick, G. M. SHELXS-86; Universität Göttingen: Göttingen, Germany, 1990.
    • (1990) SHELXS-86
    • Sheldrick, G.M.1
  • 29
    • 21544448227 scopus 로고
    • Universität Göttingen: Göttingen, Germany
    • Sheldrick, G. M. SHELXL-93; Universität Göttingen: Göttingen, Germany, 1993.
    • (1993) SHELXL-93
    • Sheldrick, G.M.1
  • 30
  • 43
    • 85174987529 scopus 로고    scopus 로고
    • note
    • -1).
  • 44
    • 85174987151 scopus 로고    scopus 로고
    • note
    • -1). The asymmetric near-UV absorption, corresponding to intraligand azomethine transitions, is slightly red-shifted (380 nm for 1, 386 nm for 2 and 3). The higher-lying intraligand transitions are observed at similar energies for all three complexes.
  • 45
    • 0001401054 scopus 로고
    • The relationship between absorption and CD band shapes and maxima has been discussed previously: Moffitt, W.; Moscowitz J. Chem. Phys. 1959, 30, 648-660.
    • (1959) Moscowitz J. Chem. Phys. , vol.30 , pp. 648-660
    • Moffitt, W.1
  • 47
    • 85174986587 scopus 로고    scopus 로고
    • note
    • Molecular orbital calculations and previous experimental studies suggest that the lowest energy π-π* transition involves orbitals that originate from the ligand azomethine group (refs 38-40). It is interesting to note that the split signal found in the CD spectrum, as well as the asymmetry in the corresponding absorption band, may be attributed to exciton (Davydov) interactions that give rise to nondegenerate π-π* transitions of the azomethine chromophore.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.