Pentalene complexes of group 7 metal carbonyls: An organometallic mixed-valence system with very large metal-metal electronic coupling

Journal of the American Chemical Society

Volumn 124, Issue 39, 2002, Pages 11610-11611

  Jones, Simon C ^a   Hascall, Tony ^a   Barlow, Stephen ^b   O'Hare, Dermot ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

^b University of Arizona   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL DERIVATIVE; ORGANOMETALLIC COMPOUND;

ARTICLE; CHEMICAL BOND; COMPLEX FORMATION; CYCLIC POTENTIOMETRY; LIGAND BINDING; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 0037010018     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja027705g     Document Type: Article

References (24)

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6. Examples of recent developments in organometallic pentalene chemistry include: (a) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 1997, 119, 7899-7990. (b) Jonas, K.; Gabor, B.; Mynott, R.; Angermund, K.; Heinemann, O.; Kruger, C. Angew. Chem., Int. Ed. Engl. 1997, 36, 1712-1714. (c) Kuchta, M. C.; Cloke, F. G. N.; Hitchcock, P. B. Organometallics 1998, 17, 1934-1936. For a review of the area, see: Cloke, F. G. N. Pure Appl. Chem. 2001, 73, 233-238.
7. Examples of recent developments in organometallic pentalene chemistry include: (a) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 1997, 119, 7899-7990. (b) Jonas, K.; Gabor, B.; Mynott, R.; Angermund, K.; Heinemann, O.; Kruger, C. Angew. Chem., Int. Ed. Engl. 1997, 36, 1712-1714. (c) Kuchta, M. C.; Cloke, F. G. N.; Hitchcock, P. B. Organometallics 1998, 17, 1934-1936. For a review of the area, see: Cloke, F. G. N. Pure Appl. Chem. 2001, 73, 233-238.
8. Examples of recent developments in organometallic pentalene chemistry include: (a) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 1997, 119, 7899-7990. (b) Jonas, K.; Gabor, B.; Mynott, R.; Angermund, K.; Heinemann, O.; Kruger, C. Angew. Chem., Int. Ed. Engl. 1997, 36, 1712-1714. (c) Kuchta, M. C.; Cloke, F. G. N.; Hitchcock, P. B. Organometallics 1998, 17, 1934-1936. For a review of the area, see: Cloke, F. G. N. Pure Appl. Chem. 2001, 73, 233-238.
9. Examples of recent developments in organometallic pentalene chemistry include: (a) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 1997, 119, 7899-7990. (b) Jonas, K.; Gabor, B.; Mynott, R.; Angermund, K.; Heinemann, O.; Kruger, C. Angew. Chem., Int. Ed. Engl. 1997, 36, 1712-1714. (c) Kuchta, M. C.; Cloke, F. G. N.; Hitchcock, P. B. Organometallics 1998, 17, 1934-1936. For a review of the area, see: Cloke, F. G. N. Pure Appl. Chem. 2001, 73, 233-238.
10. Bis(tricarbonylmanganese) complexes of the related s- and as-indacene complexes are known (Bell, W. L.; Curtis, C. J.; Eigenbrot, C. W.; Pierpont, C. G.; Robbins, J. L.; Smart, J. C. Organometallics 1987, 6, 266-273); however, no electrochemical data or mixed-valence phenomena have been reported.
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12. 5-Ic″ also displays four IR-active CO stretching bands, where Ic″ = 1,3,4,7,-tetra-tert-butyl-s-indacene (Roussel, P.; Cary, D. R.; Barlow, S.; Green, J. C.; Varret, F.; O'Hare, D. Organometallics 2000, 19, 1071-1076).
13. 5-Ic″ also displays four IR-active CO stretching bands, where Ic″ = 1,3,4,7,-tetra-tert-butyl-s-indacene (Roussel, P.; Cary, D. R.; Barlow, S.; Green, J. C.; Varret, F.; O'Hare, D. Organometallics 2000, 19, 1071-1076).
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21. For other examples of large-V mixed-valence organometallic and coordination species, see: (a) Spreer, L. O.; Allan, C. B.; MacQueen, D. B.; Otvos, J. W.; Calvin, M. J. Am. Chem. Soc. 1994, 116, 2187-2188. (b) Le Narvor, N.; Toupet, L.; Lapinte, C. J. Am. Chem. Soc. 1995, 117, 7129-7138. (c) Brady, M.; Weng, W.; Zhou, Y.; Seyler, J. W.; Amoroso, Angelo, J.; Arif, A. M.; Boehme, M.; Frenking, G.; Gladysz, J. A. J. Am. Chem. Soc. 1997, 119, 775-788.
22. For other examples of large-V mixed-valence organometallic and coordination species, see: (a) Spreer, L. O.; Allan, C. B.; MacQueen, D. B.; Otvos, J. W.; Calvin, M. J. Am. Chem. Soc. 1994, 116, 2187-2188. (b) Le Narvor, N.; Toupet, L.; Lapinte, C. J. Am. Chem. Soc. 1995, 117, 7129-7138. (c) Brady, M.; Weng, W.; Zhou, Y.; Seyler, J. W.; Amoroso, Angelo, J.; Arif, A. M.; Boehme, M.; Frenking, G.; Gladysz, J. A. J. Am. Chem. Soc. 1997, 119, 775-788.
23. For other examples of large-V mixed-valence organometallic and coordination species, see: (a) Spreer, L. O.; Allan, C. B.; MacQueen, D. B.; Otvos, J. W.; Calvin, M. J. Am. Chem. Soc. 1994, 116, 2187-2188. (b) Le Narvor, N.; Toupet, L.; Lapinte, C. J. Am. Chem. Soc. 1995, 117, 7129-7138. (c) Brady, M.; Weng, W.; Zhou, Y.; Seyler, J. W.; Amoroso, Angelo, J.; Arif, A. M.; Boehme, M.; Frenking, G.; Gladysz, J. A. J. Am. Chem. Soc. 1997, 119, 775-788.
24. Nelsen, S. F.; Tran, H. Q.; Nagy, M. A. J. Am. Chem. Soc. 1998, 120, 298-304 and references therein.