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2142667151
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note
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18 using the geometric mean method.
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29
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2142683177
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note
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26.27 show that the fcc 3-fold hollow site is energetically favorable over the hcp site by 1 kcal/ mol. However, this difference should not have much effect on the calculated CFM force-distance curves.
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30
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0000912529
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31
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0000678746
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0038476915
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34
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2142667150
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For constant-force scanning, eq 3 is given in ref 14
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For constant-force scanning, eq 3 is given in ref 14.
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35
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2142839851
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note
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M in Figures 2 and 4.
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36
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0000469962
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1/3 = 2.2, which is in the JKR range (μ > 1.0). In CFM experiments, since the apparatus has a finite stiffness, the unstable pull-off point will shift slightly relative to the JKR unstable point (soft machine with load control) (see: Greenwood, J. A. Proc. R. Soc. London A 1997, 453, 1277). Therefore, eq 8 still holds.
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Johnson, K.L.1
Kendall, K.2
Roberts, A.D.3
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37
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33746776200
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1/3 = 2.2, which is in the JKR range (μ > 1.0). In CFM experiments, since the apparatus has a finite stiffness, the unstable pull-off point will shift slightly relative to the JKR unstable point (soft machine with load control) (see: Greenwood, J. A. Proc. R. Soc. London A 1997, 453, 1277). Therefore, eq 8 still holds.
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Proc. R. Soc. London A
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Greenwood, J.A.1
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39
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2142785584
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note
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3 pair.
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40
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0012618901
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41
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2142724850
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note
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3-terminated SAM chains on the CFM tip by substrate SAM chains divided by the number of chains involved in interactions. In CFM experiments, total interactions are measured and divided by the estimated number of chains at the interface.
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42
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2142781776
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note
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Similarly, the calculated mean single-molecule force for the OH/OH pair is the total force, i.e., the sum of van der Waals and hydrogen-bonding forces, exerted on SAMs on the CFM tip by substrate SAM chains.
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45
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0005681276
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He, G.; Muser, M. H.; Robbins, M. O. Science 1999, 284, 1650.
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He, G.1
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Robbins, M.O.3
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