Electron transfer reduction of a highly electron-deficient fullerene, C60F18

Chemical Communications

Volumn , Issue 17, 2002, Pages 1952-1953

  Ohkubo, Kei ^a   Taylor, Roger ^c   Boltalina, Olga V ^b   Ogo, Seiji ^a   Fukuzumi, Shunichi ^a  

^a OSAKA UNIVERSITY   (Japan)

^b MOSCOW STATE UNIVERSITY   (Russian Federation)

^c NONE

Author keywords

[No Author keywords available]

Indexed keywords

10,10' DIMETHYL 9,9',10,10' TETRAHYDRO 9,9' BIACRIDINE; ACRIDINE DERIVATIVE; ANION; CHLORANIL; COBALT 60; FLUORINE; FLUORINE 18; FULLERENE; RADICAL; UNCLASSIFIED DRUG;

ARTICLE; DEFLUORINATION; ELECTRIC POTENTIAL; ELECTRON; ELECTRON TRANSPORT; REDUCTION;

EID: 0036970696     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b205642a     Document Type: Article

References (18)

1. I. S. Neretin, K. A. Lyssenko, M. Y. Antipin, Y. L. Slovokhotov, O. V. Boltalina, P. A. Troshin, A. Y. Lukonin, L. N. Sidorov and R. Taylor, Angew. Chem., Int. Ed., 2000, 39, 3273.
2. S. Jenkins, M. I. Heggie and R. Taylor, J. Chem. Soc., Perkin Trans. 2, 2000, 2415.
3. A. G. Avent, O. V. Boltalina, J. M. Street, R. Taylor and X.-W. Wei, J. Chem. Soc., Perkin Trans. 2, 2001, 994.
4. Y. Yoshida, A. Otsuka, O. O. Drozdova and G. Saito, J. Am. Chem. Soc., 2000, 122, 7244.
5. 60. See: F. Zhou, G. J. Van Berkel and B. T. Donovan, J. Am. Chem. Soc., 1994, 116, 5485; N. Liu, Y. Morio, F. Okino, H. Touhara, O. V. Boltalina and V. K. Pavlovich, Synth. Met., 1997, 86, 2289.
6. 60. See: F. Zhou, G. J. Van Berkel and B. T. Donovan, J. Am. Chem. Soc., 1994, 116, 5485; N. Liu, Y. Morio, F. Okino, H. Touhara, O. V. Boltalina and V. K. Pavlovich, Synth. Met., 1997, 86, 2289.
7. S. Fukuzumi and T. Yorisue, Bull. Chem. Soc. Jpn., 1992, 65, 715.
8. S. Fukuzumi, I. Nakanishi, T. Suenobu and K. M. Kadish, J. Am. Chem. Soc., 1999, 121, 3468.
9. S. Fukuzumi, T. Suenobu, M. Patz, T. Hirasaka, S. Itoh, M. Fujitsuka and O. Ito, J. Am. Chem. Soc., 1998, 120, 8060.
10. 2 was employed to assist liquid nebulization. The orifice potential was maintained at -30 V. Acetonitrile was used as a solvent because of the higher ESI sensitivity relative to PhCN.
11. 2.
12. Theoretical calculations were performed on a COMPAQ DS20E computer using the PM3 Hamiltonian. Final geometries and energetics were obtained by optimizing the total molecular energy with respect to all structural variables. The DFT calculations gave similar results.
13. S. Fukuzumi, T. Suenobu, X. Gao and K. M. Kadish, J. Phys. Chem. A, 2000, 104, 2908.
14. 17· which would decay obeying a bimolecular second-order kinetics
15. The Eyring plot gave a good linear correlation, from which the activation enthalpy and entropy were determined.
16. 0 value by the conventional electrochemical method
17. S. Fukuzumi and Y. Tokuda, J. Phys. Chem., 1992, 96, 8409.
18. S. Fukuzumi, K. Ohkubo and J. Otera, J. Org. Chem., 2001, 66, 1450.