Kinetics of trace gas uptake by liquid surfaces

Progress in Reaction Kinetics and Mechanism

Volumn 27, Issue 1, 2002, Pages 1-46

  Kolb, C E ^a   Davidovits, P ^a,b   Jayne, J T ^a   Shi, Q ^a   Worsnop, D R ^a,b  

^a AERODYNE RESEARCH INC   (United States)

^b BOSTON COLLEGE   (United States)

Author keywords

Bubble train flow reactor; Droplet train flow reactor; Gas liquid interactions; Henry's law constants; Heterogeneous chemistry; Liquid surface reactions; Mass accommodation coefficients; Thermal accommodation coefficients; Uptake coefficients

Indexed keywords

AEROSOLS; ATMOSPHERIC CHEMISTRY; CHEMICAL LABORATORIES; CHEMICAL REACTORS; CLOUDS; GASES; LIQUIDS; REACTION KINETICS; SURFACE CHEMISTRY;

GAS-LIQUID INTERACTIONS; THERMOCHEMISTRY;

TRACE ANALYSIS;

EID: 0036439423     PISSN: 14686783     EISSN: None     Source Type: Journal    
DOI: 10.3184/007967402103165324     Document Type: Review

References (99)

1. Sherwood, T.K., Pigford, R.L. and White, C.R. Mass Transfer, McGraw Hill, New York, 1975.
2. Kolb, C.E., Worsnop, D.R., Zahniser, M.S., Davidovits, P., Hanson, D.R., Ravishankara, A.R., Leu, M.-T; Williams, L.R., Molina, M.J. and Tolbert, M.R., Laboratory Studies of Atmospheric Heterogeneous Chemistry. In: Barker, J.R. (ed.), Problems and Progress in Atmospheric Chemistry, Advances Series in Physical Chemistry, C.-Y. Ng, ed., 771-875, World Scientific, singapore, 1995.
3. Warneck, P., ed., Heterogeneous and Liquid Phase Processes. Laboratory Studies Related to Aerosols and Clouds, Transport and Chemical Transformation of Pollutants in the Troposphere, Vol. 2, Springer, Berlin, 1996.
4. Molina, M.J., Molina, L.T. and Kolb, C.E. Gas-Phase and Heterogeneous Chemical Kinetics of the Troposphere and Stratosphere. Ann. Rev. Phys. Chem., 1996, 47, 327-367.
5. Danckwerts, P.V. Gas-liquid Reactions, McGraw-Hill, New York, 1970.
6. Sherwood, T.K. and Pigford, R.L. Absorption and Extraction, 2nd Ed., McGraw-Hill, New York, 1952.
7. Fuchs, N.A. and Sutugin, A.G. Highly Dispersed Aerosols, Ann Arbor Science Publishers, Ann Arbor, MI, 1970.
8. 2 and Other Gases by Atmospheric Aerosols. J. Aerosol Sci., 1997, 28, 87-106.
9. 2O on Submicron Sulfuric Acid Aerosol and the Implications for the Lower Stratosphere. J. Geophys. Res. 1996, 101, 9063-9069.
10. 2 in Aqueous Solutions, Atmos. Environ., 1981, 15, 1129-1144.
11. Hanson, D.R. Surface-specific Reaction on Liquids. J. Phys. Chem., B, 1997, 101, 4998-5001.
12. Shi, Q., Davidovits, P., Jayne, J.T., Worsnop, D.R. and Kolb, C.E., Uptake of Gas-phase Ammonia. I. Uptake by Aqueous Surfaces as a Function of pH, J. Phys. Chem. A, 1999, 103, 8812-8823. Errata: J. Phys. Chem., A, 2000, 104, 5160.
13. 5 by Sulfuric Acid Solutions. J. Geophys. Res., 1997, 102, 3583-3601.
14. Robinson, G.N., Worsnop, D.R., Jayne, J.T., Kolb, C.E., Swartz, E. and Davidovits, P. Heterogenous Uptake of HCl by Sulfuric Acid Solutions. J. Geophys. Res., 1998, 103, 25, 371-25, 381.
15. 2 on Aqueous Surfaces, J. Phys. Chem., 1989, 93, 1159-1172.
16. Worsnop, D.R., Shi, Q., Jayne, J.T., Kolb, C.E., Swartz, E. and Davidovits, P. Gas Phase Diffusion in Droplet Train Measurements of Uptake Coefficients. J. Aerosol Sci., 2001, 32, 877-891.
17. 3. J. Atmos. Chem., 1993, 16, 1-21.
18. Heal, M.R., Pilling, M.J., Titcombe, P.E. and Whitaker, B.J. Mass Accommodation of Aniline, Phenol and Toluene on Aqueous Droplets. Geophys. Res. Lett., 1995, 22, 3043-3046.
19. Schweitzer, F., Mirabel, Ph. and George, Ch. Uptake of Hydrogen Halides by Water Droplets. J. Phys. Chem., A., 2000, 104, 72-76.
20. Magi, L., Schweitzer, F., Pallares, C., Cherif, C., Mirabel Ph. and George, Ch. Investigation of Uptake Rate of Ozone and Methyl Hydroperoxide by Water Surfaces. J. Phys. Chem., A, 1997, 101, 4943-4949.
21. Schweitzer F., Magi, L., Mirabel, Ph. and George, Ch., Uptake Rate Measurement of Methanesulfonic Acid and Glyoxal by Aqueous Droplets. J. Phys. Chem., A, 1998, 102, 593-600.
22. 2 on Water Droplets. J. Geophys. Res., 1987, 92, 10,887-10,895.
23. 2(g) by Aqueous Droplets. J. Geophys. Res., 1990, 95, 20,559-20,563.
24. Watson, L.R., Van Doren, J.M., Davidovits, P., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E. Uptake of HCl Molecules by Aqueous Sulfuric Acid Droplets as a Function of Acid Concentration. J. Geophys. Res., 1990, 95, 5631-5638.
25. 2(g) by Aqueous Surfaces as a Function of pH: The Effect of Chemical Reaction at the Interface. J. Phys. Chem., 1990, 94, 6041-6048.
26. 5 on Aqueous Surfaces. J. Phys. Chem., 1990, 94, 3265-3269.
27. 3 by Aqueous Sulfuric Acid Droplets. J. Phys. Chem., 1991, 95, 1684-1689.
28. Jayne, J.T., Duan, S.X., Davidovits, P., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E. Uptake of Gas-Phase Alcohol Molecules and Organic Acids by Water Surfaces. J. Phys. Chem., 1991, 95, 6329-6336.
29. Jayne, J.T., Duan, S.X., Davidovits, P., Worsnop, D.R., Zahniser; M.S. and Kolb, C.E. Uptake of Gas Phase Aldehydes by Water Surfaces. J. Phys Chem., 1992, 96, 5452-5460.
30. De Bruyn, W.J., Duan, S.X., Shi, X.Q., Davidovits, P., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E. Tropospheric Heterogeneous Chemistry of Haloacetyl and Carbonyl Halides. Geophys. Res. Lett., 1992, 19, 1939-1942.
31. Duan, S.X., Jayne, J.T., Davidovits, P., Worsnop, R., Zahniser, M.S. and Kolb, C.E. The Uptake of Gas Phase Acetone by Water Surfaces. J. Phys. Chem., 1993, 97, 2284-2286.
32. Hu, J., Shorter, J.A., Davidovits, P., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E. Uptake of Gas Phase Haloacetic Acids by Water Surfaces. J. Phys. Chem., 1993, 97, 11,037-11,042.
33. De Bruyn, W.J., Shorter J.A., Davidovits, P., Worsnop, D.R., Zahniser, M.S., Kolb, C.E. Uptake of Gas Phase Sulfur Species Methanesulfonic Acid, Dimethylsulfoxide, and Dimethyl Sulfone by Aqueous Surfaces. J. Geophys. Res., 1994, 99, 16,927-16,932.
34. - Ion Concentration: The Effect of Chemical Reactions at the Interface. J. Phys. Chem., 1995, 99, 8768-8776.
35. Jayne, J.T., Worsnop, D.R., Kolb, C.E., Swartz E. and Davidovits, P. Uptake of Gas-Phase Formaldehyde by Aqueous Acid Surfaces. J. Phys. Chem., 1996, 100, 8015-8022.
36. Shi, Q., Li, Y.Q., Davidovits, P., Jayne, J.T., Worsnop, D.R., Mozurkewich, M. and Kolb, C.E. Isotope Exchange for Gas-phase Ethanol and Acetic Acid at Aqueous Interfaces, J. Phys. Chem., B, 1999, 103, 2417-2430.
37. Swartz, E., Shi, Q., Davidovits, P., Jayne, J.T., Worsnop, D.R. and Kolb, C.E. Uptake of Gas-Phase Ammonia 2: Uptake by Sulfuric Acid Surfaces. J. Phys. Chem., A, 1999, 103, 8824-8833.
38. 2 by Aqueous Solutions. J. Phys Chem., A, 2000, 104, 7502-7510.
39. 2O (g) on Liquid Water as a Function of Temperature. J. Phys. Chem., A, 2001, 105, 10,627-10,634.
40. Li, Y.Q., Zhang, H.Z., Davidovits, P., Jayne, J.T., Kolb, C.E., and Worsnop D.R. Uptake of HCl(g) and HBr(g) on Ethylene Glycol Surfaces as a Function of Relative Humidity and Temperature. J. Phys. Chem., A, 2002, 106, 1220-1227.
41. Davidovits, P., Jayne, J.T., Duan, S.X., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E., Uptake of Gas Molecules by Liquids: A Model, J. Phys. Chem., 1991, 95, 6337-6340.
42. Nathanson, G.M., Davidovits, P., Worsnop, D.R. and Kolb, C.E. Dynamics and Kinetics at the Gas-Liquid Interface. J. Phys. Chem., 1996, 100, 13007-13020.
43. Bongartz, A., Schweighoefer, S., Roose, C. and Schurath, U. The Mass Accommodation Coefficient of Ammonia on Water. J. Atmos. Chem., 1995, 20, 35-58.
44. Mozurkewich, M. Aerosol Growth and the Condensation Coefficient for Water: A Review. Aerosol Sci. Technol., 1986, 5, 223-226.
45. Ben-Naim, A. and Marcus, Y. Solvation Thermodynamics of Nonionic Solutions. J. Chem. Phys., 1984, 81, 2016-27.
46. Ben-Naim, A. Solvation Thermodynamics, Plenum Press, New York, 1988.
47. Snider, J.R. and Dawson, G.A. Tropospheric Light Alcohols, Carbonyls, and Acetonitrile: Concentrations in the Southwestern United States and Henry'S Law Data. J. Geophys. Res., 1985, 90, 3797-3805.
48. Lind, J. and Kok, G.L. Henry'S Law Determination for Aqueous Solutions of Hydrogen Peroxide, Methylhydroperoxide, and Peroxyacetic Acid. J. Geophys. Res., 1986, 91, 7889-7995.
49. Pollack, G.L. Why Gases Dissolve in Liquids. Science, 1991, 251, 1323-1330.
50. Davidovits, P., Hu, J., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E. Entry of Gas Molecules into Liquids. Faraday Discuss., 1995, 100, 65-82.
51. Braslau, A., Deutsch, M., Pershan, P.S., Weiss, A.H., Als-Nielsen, J. and Bohr, J. Surface Roughness of Water Measured by X-ray Reflectivity. Phys. Rev. Lett., 1985, 54, 114-117.
52. Braslau, A., Pershan, P.S., Swislow, G., Ocko, B.M. and Als-Nielsen, J. Capillary Waves on the Surface of Simple Liquids Measured by X-ray Reflectivity. Phys. Rev. A., 1988, 38, 2457-2470.
53. Matsumoto, M. and Kataoka, Y. Study on Liquid-Vapor Interface of Water. 1. Simulational Results of Thermodynamic Properties and Orientational Structure. J. Chem. Phys., 1988, 88, 3233-3245.
54. Wilson, M.A., Pohorille, A. and Pratt, L.R. Molecular Dynamics of the Water Liquid-Vapor Interface. J. Phys. Chem., 1987, 91, 4873-4878.
55. Townsend, R.M. and Rice, S.A. Molecular Dynamics Studies of the Liquid-Vapor Interface of Water. J. Chem. Phys., 1991, 94, 2207-2218.
56. Besseling, N.A.M. and Lyklema, J. Equilibrium Properties of Water and Its Liquid-Vapor Interface. J. Phys. Chem., 1994, 98, 11,610-11,622.
57. Taylor, R.S., Dang, L.X. and Garrett, B.C. Molecular Dynamics Simulations of the Liquid/Vapor Interface of SPC/E Water. J. Phys. Chem., 1996, 100, 11,720-11,725.
58. Du, Q., Superfine, R., Freysz, E. and Shen, Y.R. Vibrational Spectroscopy of Water at the Vapor/Water Interface. Phys. Rev. Lett., 1993, 70, 2313-2316.
59. Wilson, K.R., Rude, B.S., Catalano, T., Schaller, R.D., Tobin, J.G., Co, D.T. and Saykally, R.J.,X-ray Spectroscopy of Liquid Water Microjets. J. Phys. Chem., B, 2001, 105, 3346-3349.
60. 2 at the Aqueous-Air Interface. J. Phys. Chem., 1995, 99, 9313-9315.
61. 3. J. Phys. Chem., A, 1999, 103, 62-70.
62. 4 Alcohols, Acids, and Acetone. J. Phys. Chem., A, 1999, 103, 871-876.
63. Mmereki, B.T., Hicks, J.M. and Donaldson, D.J. Adsorption of Atmospheric Gases at the Air-Water Interface. 3. Methylamines. J. Phys. Chem. A, 2000, 104, 10,789-10,793.
64. Dabkowski, J., Zargorska, L., Dabkowska, M., Koczorowski, Z. and Trasatti, S. Adsorption of DMSO at the Free Surface of Water: Surface Excess and Surface Potential Shifts in the Low Concentration Range. J. Chem. Soc, Faraday Trans., 1996, 92, 3873-3878.
65. Karpovich, D.S. and Ray, D. Adsorption of Dimethyl Sulfoxide to the Liquid/Vapor Interface of Water and the Thermochemistry of Transport Across the Interface. J. Phys. Chem., B, 1998, 102, 649-652.
66. Allen, H.C., Gragson, D.E. and Richmond, G.L. Molecular Structure and Adsorption of Dimethyl Sulfoxide at the Surface of Aqueous Solutions, J. Phys. Chem., B, 1999, 103, 660-666.
67. Allen, H.C., Raymond, E.A. and Richmond, G.L. Surface Structural Studies of Methanesulfonic Acid at Air/Aqueous Solution Interfaces Using Vibrational Sum Frequency Spectroscopy. J. Phys. Chem., B, 2001, 105, 660-666.
68. Wilson, M.A. and Pohorille, A. Adsorption and Solvation of Ethanol at the Water Liquid-Vapor Interface: A Molecular Dynamics Study. J. Phys. Chem., B, 1997, 101, 3130-3135.
69. Taylor, R.S. and Garrett, B.C. Accommodation of Alcohols by the Liquid/Vapor Interface of Water: Molecular Dynamics Study. J. Phys. Chem. B, 1999, 103, 844-851.
70. Schwartz, S.E. Mass-transport Considerations Pertinent to Aqueous Phase Reactions of Gases in Liquid-Water Clouds, In: Jaeschke, W. (ed.), Chemistry of Multiphase Atmospheric Systems, pp. 415-471, NATO ASI Ser., vol. G6. Springer-Verlag, New York, 1986.
71. Kolb, C.E., Jayne, J.T., Worsnop D.R., and Davidovits, P. Solubility Data Requirements and New Experimental Methods in Atmospheric Aerosol Research. Pure Appl. Chem., 1997, 69, 959-968.
72. Vesala, T., Hannemann, A.U., Luo, B.P., Kulmala, M. and Peter, Th. Rigorous Treatment of Time-dependent Trace Gas Uptake by Droplets Including Bulk Diffusion and Surface Accommodation. J. Aerosol Sci., 2001, 843-860.
73. 2O Including Solubilities of HBr, from <200 to 328 K. J. Phys. Chem., 1995, 99, 11,557-11,574.
74. 2O and HCl and HOCl with HCl in Sulfuric Acid Solution. J. Geophys. Res., 2001, 106, 24,259-24,274.
75. 2. J. Phys. Chem., A, 1998, 102, 3942-3952.
76. Garland, J.A., Elzerman, A.W. and Penkett, S.A. The Mechanism for Dry Deposition of Ozone to Seawater Surfaces. J. Geophys. Res., 1980, 85, 7488-7492.
77. 2 Over Aqueous Solutions Containing Iodide. Geophys. Res. Lett., 1995, 22, 1505-1508.
78. Katrib, Y., Deiber, G., Schweitzer, F., Mirabel, Ph. and George, Ch. Chemical Transformation of Bromine Chloride at the Air/Water Interface. J. Aerosol Sci., 2001, 32, 893-911.
79. George, Ch., Lagrange, J., Lagrange, P., Mirable, Ph., Pallares, C. and Ponche, J.L. Heterogeneous Chemistry of Trichloroacetyl Chloride in the Atmosphere. J. Geophys. Res., 1994, 99, 1255-1262.
80. George, Ch., Saison, J.Y., Ponche, J.L., and Mirable, Ph. Kinetics of Mass Transfer of Carbonyl Fluoride, Trifluoroacetyl Fluoride, and Trifluoroacetyl Chloride at the Air/Water Interface. J. Phys. Chem., 1994, 98, 10,857-10,862.
81. Shorter, J.A., De Bruyn, W.J., Hu, J., Swartz, E., Davidovits, P., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E. Bubble Column Apparatus for Gas-Liquid Chemistry Studies. Environ. Sci. Technol., 1995, 29, 1171-1178.
82. Swartz, E., Boniface, J., Tchertkov, I., Rattigan, O.V., Robinson, D.V., Davidovits, P., Worsnop, D.R., Jayne, J.T. and Kolb, C.E. Horizontal Bubble Train Apparatus for Heterogeneous Chemistry Studies; Uptake of Gas Phase Formaldehyde. Environ. Sci. Technol., 1997, 31, 2634-2641.
83. De Bruyn, W.E., Shorter, J.A., Davidovits, P., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E., Uptake of Haloacetyl and Carbonyl Halides by Water Surfaces. Environ. Sci. Technol., 1995, 29, 1179-1185.
84. Manogue, W. and Pigford, G.L. The Kinetics of the Absorption of Phosgene into Water and Aqueous Solutions. AIChE J., 1960, 6, 494-500.
85. Mertens, R., von Sonntag, C., Lind, J. and Merenyi, G. A Kinetic Study of the Hydrolysis of Phosgene in Aqueous solutions by Pulse Radiolysis. Angew. Chem., Int. Ed. Engl., 1994, 33, 1259-1261.
86. Wild, O., Rattigan, O.V., Jones, R.L., Pyle, J.A. and Cox, A. Two-Dimensional Modeling of Some CFC Replacement Compounds. J. Atmos. Chem., 1996, 25, 167-199.
87. De Bruyn, W.J., Swartz, E., Shorter, J.A., Davidovits, P., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E. Henry'S Law Solubilities and Setchenow Coefficients for Biogenic Reduced Sulfur Compounds Obtained from Gas-Liquid Uptake Measurements. J. Geophys. Res., 1995, 100, 7245-7251.
88. 2 with Aqueous Surfaces. J. Phys. Chem., A, 2000, 104, 2655-2662.
89. Mertes, S. and Wahner, A. Uptake of Nitrogen Dioxide and Nitrous Acid on Aqueous Surfaces. J. Phys. Chem., 1995, 99, 14,000-14,006.
90. 3, and HONO. J. Geophys. Res., 2000, 105, 29,065-28,078.
91. Gershenzon, M., Davidovits, P., Jayne, J.T., Kolb, C.E. and Worsnop, D.R. Simultaneous Uptake of DMS and Ozone on Water. J. Phys. Chem., A, 2001, 105, 7031-7036.
92. Loerting, T., Liedl, K.R. and Rode, B.M. Predictions of Rate Constants and Estimates of Tunnel Splittings of Concerted Proton Transfer in Small Cyclic Water Clusters. J. Chem. Phys., 1998, 109, 2672-2679.
93. Saxena, P. and Hildemann, L.M. Water-Soluble Organics in Atmospheric Particles: A Critical Review of the Literature and Application of Thermodynamics to Identify Candidate Compounds. J. Atmos. Chem., 1996, 24, 57-109.
94. Jacobson, M.C., Hansson, H.-C., Noone, K.J. and Charlson, R.J. Organic Atmospheric Aerosols: Review and State of the Science. Rev. Geophys., 2000, 38, 267-294.
95. Novakov, T., and Penner, J.E. Large Contribution of Organic Aerosols to Cloud Condensation Nuclei. Nature, 1993, 365, 823-826.
96. Facchini, M.C., Mircea, M., Fuzzi, S., Charlson, R.J. Cloud Albedo Enhancement by Surface-active Organic Solutes in Growing Droplets. Nature, 1999, 401, 257-259.
97. Andreae, M.O. and Crutzen, P.J. Atmospheric Aerosols: Biogeochemical Sources and Role in Atmospheric Chemistry. Science, 1997, 276, 1052-1058.
98. Turpin B.J., Saxena, P. and Andrews, E. Measuring and Simulating Particulate Organics in the Atmosphere: Problems and Prospects. Atmos. Environ., 2000, 34, 2983-3013.
99. Moise, T. and Rudich, Y. Reactive Uptake of Ozone by Proxies for Organic Aerosols: Surface Versus Bulk Processes. J. Geophys. Res., 2000, 105, 14,667-14,676.