Heterogeneous uptake of HCl by sulfuric acid solutions

Journal of Geophysical Research Atmospheres

Volumn 103, Issue D19, 1998, Pages 25371-25381

  Robinson, G N ^a   Worsnop, D R ^a   Jayne, J T ^a   Kolb, C E ^a   Swartz, E ^b   Davidovits, P ^b  

^a AERODYNE RESEARCH INC   (United States)

^b BOSTON COLLEGE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL; ATMOSPHERIC CHEMISTRY; HYDROCHLORIC ACID; LABORATORY METHOD; STRATOSPHERE; SULFURIC ACID;

EID: 0032463094     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/98JD02085     Document Type: Article

References (40)

1. Abbatt, J. P. D., HBr, HCl, and HOBr with supercooled sulfuric acid solutions of stratospheric composition, J. Geophys. Res., 100, 14,009, 1995.
2. Abbatt, J. P. D., and M. J. Molina, Status of stratospheric ozone depletion, Annu. Rev. Energy Environ., 18, 1, 1993.
3. Barr, J., R. J. Gillespie, and E. A. Robinson, The sulphuric acid solvent system, II, Conductivity measurements of some acids, Can. J. Chem., 39, 1266, 1961.
4. 2O, including solubilities of HBr, from <200 to 328 K, J. Phys. Chem., 99, 11,557, 1995.
5. Carslaw, K. S., T. Peter, and S. L. Clegg, Modeling the composition of liquid stratospheric aerosols, Rev. Geophys., 35, 124, 1997.
6. Crank, J., Mathematics of Diffusion, Oxford Univ., New York, 1956.
7. Danckwerts, P. V., Absorption by simultaneous diffusion and chemical reaction into particles of various shapes and into falling drops, Trans. Faraday Soc., 47, 1014, 1951.
8. Danckwerts, P. V., Gas-Liquid Reactions, McGraw-Hill, New York, 1970.
9. Davidovits, P., J. T. Jayne, S. X. Duan, D. R. Worsnop, M. S. Zahniser, and C. E. Kolb, Uptake of gas molecules by liquids: A model, J. Phys. Chem., 95, 6337, 1991.
10. DeMore, W. B., S. P. Sander, D. M. Golden, R. F. Hampson, M. J. Kurylo, C. J. Howard, A. R. Ravishankara, C. E. Kolb, and M. J. Molina, Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling, JPL Publ. 97-4, Jet Propul. Lab., Pasadena, Calif., 1997.
11. Duan, S. X., J. T. Jayne, P. Davidovits, D. R. Worsnop, M. S. Zahniser, and C. E. Kolb, The uptake of gas phase acetone by water surfaces, J. Phys. Chem., 97, 2284, 1993.
12. 2O solutions, Faraday Discuss. Chem. Soc., 100, 269, 1995.
13. Fahey, D. W., et al., Polar ozone, in Scientific Assessment of Ozone Depletion, 1994, Global Ozone Res. Monit. Proj. Rep. 37, chap. 3, pp. 3.1, World Meteorol. Org., Geneva, Switzerland, 1995.
14. Fuchs, N. A., and A. G. Sutugin, Highly Dispersed Aerosols, Ann Arbor Sei., Ann Arbor, Mich., 1970.
15. 2 with submicron sulfuric acid aerosols, Science, 267, 1326, 1995.
16. Hanson, D. R., and E. R. Lovejoy, Heterogeneous reactions in liquid sulfuric acid: HOCl + HCl as model system, J. Phys. Chem., 100, 6397, 1996.
17. Hanson, D. R., and A. R. Ravishankara, The uptake of HCl and HOCl onto sulfuric acid: Solubilities, diffusivities, and reaction, J. Phys. Chem., 97, 12,309, 1993.
18. Hanson, D. R., and A. R. Ravishankara, Heterogeneous chemistry of bromine species in sulfuric acid under stratospheric conditions, Geophys. Res. Lett., 22, 385, 1995.
19. Hanson, D. R., A. R. Ravishankara, and S. Solomon, Heterogeneous reactions in sulfuric acid aerosols: A framework for model calculations, J. Geophys. Res., 99, 3615, 1994.
20. Jayne, J. T., S. X. Duan, P. Davidovits, D. R. Worsnop, M. S. Zahniser, and C. E. Kolb, Uptake of gas-phase alcohol molecules and organic acids by water surfaces, J. Phys. Chem., 95, 6329, 1991.
21. Jayne, J. T., S. X. Duan, P. Davidovits, D. R. Worsnop, M. S. Zahniser, and C. E. Kolb, Uptake of gas phase aldehydes by water surfaces, J. Phys. Chem., 96, 5452, 1992.
22. Jayne, J. T., D. R. Worsnop, C. E. Kolb, E. Swartz, and P. Davidovits, Uptake of gas-phase formaldehyde by aqueous acid solutions, J. Phys. Chem., 100, 8015, 1996.
23. Key, R. J., G. Dixon-Lewis, J. Warnatz, M. E. Coltrin, and J. A. Miller, CHEMKIN: A chemical kinetics code package, Rep. SAN086-8256, Sandia Natl. Lab., Albuquerque, N. M., 1986.
24. Klassen, J. K., Z. Hu, and L. R. Williams, Diffusion coefficients for HCl and Hbr in 30 wt % to 72 wt % sulfuric acid at temperature between 220 and 300 K, J. Geophys. Res., 103, 16,197, 1998.
25. Kolb, C. E., et al., Laboratory studies of atmospheric heterogeneous chemistry, in Progress and Problems in Atmospheric Chemistry, Adv. Ser. Phys. Chem., vol. 3, edited by J. R. Barker, pp. 771-875, World Sci., River Edge, N. J., 1995.
26. Liler, M., Reactions Mechanisms in Sulphuric Acid and Other Strong Acid Solutions, Academic, San Diego, Calif., 1971.
27. Motz, H., and H. Wise, Diffusion and heterogeneous reaction, III, Atomic recombination at a catalytic boundary, J. Chem. Phys., 32, 1893, 1960.
28. Nathanson, G. M., P. Davidovits, D. R. Worsnop, and C. E. Kolb, Dynamics at the gas-liquid interface, J. Phys. Chem., 100, 13,007, 1996.
29. Perry, J. H., Chemical Engineers Handbook, pp. 184, 540, McGraw-Hill, New York, 1950.
30. 5 by sulfuric acid solutions, J. Geophys. Res., 102, 3583, 1997.
31. Schwartz, S. E., Mass-transport considerations pertinent to aqueous phase reactions of gases in liquid-water clouds, in Chemistry of Multiphase Atmospheric Systems, NATO ASI Ser., vol. G6, edited by W. Jaeschke, pp. 415-471, Springer-Verlag, New York, 1986.
32. Tabazadeh, A., R. P. Turco, and M. Z. Jacobson, A model for studying the composition and chemical effects of stratospheric aerosols, J. Geophys. Res., 99, 12,897, 1994.
33. Turco, R. P., R. C. Whitten, and O. B. Toon, Stratospheric aerosols: Observation and theory, Rev. Geophys., 20, 233, 1982.
34. 5 by water droplets, J. Phys. Chem., 94, 3265, 1990.
35. Watson, L. R., J. M. Van Doren, P. Davidovits, D. R. Worsnop, M. S. Zahniser, and C. E. Kolb, Uptake of HCl molecules by aqueous sulfuric acid droplets as a function of acid concentration, J. Geophys. Res., 95, 5631, 1990.
36. 2 and other gases by atmospheric aerosols, J. Aerosol Sci., 28, 87, 1997.
37. Williams, L. R., and D. M. Golden, Solubility of HCl in sulfuric acid at stratospheric temperatures, Geophys. Res. Lett., 20, 2227, 1993.
38. Williams, L. R., and F. S. Long, Viscosity of supercooled sulfuric acid solutions, J. Phys. Chem., 99, 3748, 1995.
39. 2 on aqueous surfaces, J. Phys. Chem., 93, 1159, 1989.
40. 2O systems: Incorporation of stratospheric acids into background sulfate aerosols, J. Phys. Chem., 97, 8541, 1993.