RhCl(PPh3)3/NaI catalyst system for hydrosilylation of 1-alkynes: Stereodivergent syntheses of E-and Z-alkenylsilanes with heteroatom substituents on silicon

Chemistry Letters

Volumn , Issue 5, 1998, Pages 443-444

  Mori, Atsunori ^a   Takahisa, Eisuke ^a   Kajiro, Hiroshi ^a   Hirabayashi, Kazunori ^a   Nishihara, Yasushi ^a   Hiyama, Tamejiro ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0032374573     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.443     Document Type: Article

References (21)

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14. 2 caused the polymerization even in the presence of a hydrosilane.
15. 2: 250.1209 ; Found: 250.1233.
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19. This result is not due to the temperature effect. The reaction at 55°C under the condition to form the (Z)-product did not exhibit high (E)-selectivity to give (Z)-major product with slightly lower selectivity.
20. 3) δ 0.13 (s, 9H), 0.23 (s, 6H), 6.43 (d, J = 19 Hz, 1H), 6.95 (d, J = 19 Hz, 1H), 7.26-7.49 (m, 5H).
21. 2: 250.1209; Found: 250.1223.