Regio- and stereocontrolled hydrosilylation polyaddition catalyzed by RhI(PPh3)3. Syntheses of polymers containing (E)- or (Z)-alkenylsilane moieties

Macromolecules

Volumn 33, Issue 4, 2000, Pages 1115-1116

  Mori, Atsunori ^a   Takahisa, Eisuke ^a   Kajiro, Hiroshi ^a   Nishihara, Yasushi ^a   Hiyama, Tamejiro ^b  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CATALYSIS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; PRECIPITATION (CHEMICAL); SILANES; STEREOCHEMISTRY;

ALKENYSILANE MOIETIES; HYDROSILATION; STEREOCHEMICAL CONTROL;

SILICONES;

EID: 0033879607     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9913360     Document Type: Article

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36. Other model reactions with 1,4-diethynylbenzene (1a) and dimethylphenylsilane were also carried out to yield the corresponding E-and Z-alkenylsilanes with high stereose-lectivities along with trace amounts of the α-adducts. See Supporting Information.