Stabilization of organosilicenium ions by means of intramolecular coordination of O, S, or P ligands

Angewandte Chemie - International Edition

Volumn 38, Issue 13-14, 1999, Pages 2048-2050

  Berlekamp, Uwe H ^a   Jutzi, Peter ^a   Mix, Andreas ^a   Neumann, Beate ^a   Stammler, Hans Georg ^a   Schoeller, Wolfgang W ^a  

^a BIELEFELD UNIVERSITY   (Germany)

Author keywords

Ab initio calculations; Donor acceptor systems; Molecular dynamics; Silicon

Indexed keywords

ORGANOSILICON DERIVATIVE; PHOSPHORUS; SULFUR;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; MOLECULAR DYNAMICS; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 0033549577     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990712)38:13/14<2048::AID-ANIE2048>3.0.CO;2-C     Document Type: Article

References (25)

1. a) Review: P. Lickiss in The Chemistry of Organic Silicon Compounds, Vol. 2, Part 1 (Eds.: Z. Rappoport, Y. Apeloig), Wiley, 1998, pp. 557-594;
2. b) o donors: J. Y. Corey, R. West, J. Am. Chem. Soc. 1963, 85, 4034-4035; B. J. Aylett, J. M. Campbell, J. Chem. Soc. Chem. Commun. 1967, 159; Hensen, T. Zengerly, P. Pickel, G. Klebe, Angew. Chem. 1983, 95, 739; Angew. Chem. Int. Ed. Engl. 1983, 22, 725;
3. b) o donors: J. Y. Corey, R. West, J. Am. Chem. Soc. 1963, 85, 4034-4035; B. J. Aylett, J. M. Campbell, J. Chem. Soc. Chem. Commun. 1967, 159; Hensen, T. Zengerly, P. Pickel, G. Klebe, Angew. Chem. 1983, 95, 739; Angew. Chem. Int. Ed. Engl. 1983, 22, 725;
4. b) o donors: J. Y. Corey, R. West, J. Am. Chem. Soc. 1963, 85, 4034-4035; B. J. Aylett, J. M. Campbell, J. Chem. Soc. Chem. Commun. 1967, 159; Hensen, T. Zengerly, P. Pickel, G. Klebe, Angew. Chem. 1983, 95, 739; Angew. Chem. Int. Ed. Engl. 1983, 22, 725;
5. b) o donors: J. Y. Corey, R. West, J. Am. Chem. Soc. 1963, 85, 4034-4035; B. J. Aylett, J. M. Campbell, J. Chem. Soc. Chem. Commun. 1967, 159; Hensen, T. Zengerly, P. Pickel, G. Klebe, Angew. Chem. 1983, 95, 739; Angew. Chem. Int. Ed. Engl. 1983, 22, 725;
6. c) A. R. Bassindale, T. Stout, J. Chem. Soc. Chem. Commun. 1984, 1387-1389;
7. d) A. R. Bassindale, T. Stout, Tetrahedron Lett. 1985, 26, 3403-3406;
8. e) J. Chojnowski, W. Stanczyk, Adv. Organomet. Chem. 1990, 30, 243-307;
9. f) M. Kira, T. Hino, H. Sakurai, Chem. Lett. 1993, 153-156;
10. g) S. R. Bahr, P. Boudjouk, J. Am. Chem. Soc. 1993, 115, 4514-4519.
11. π Donors: a) J. B. Lambert, S. Zhang, C. L. Stern, J. C. Huffman, Science 1993, 260, 1917;
12. b) P. Jutzi, E. A. Bunte, Angew. Chem. 1992, 104, 1636-1638; Angew. Chem. Int. Ed. Engl. 1992, 31, 1605;
13. b) P. Jutzi, E. A. Bunte, Angew. Chem. 1992, 104, 1636-1638; Angew. Chem. Int. Ed. Engl. 1992, 31, 1605;
14. c) H.-U. Steinberger, T. Müller, N. Auner, C. Maerker, P. von R. Schleyer, Angew. Chem. 1997, 109, 667-669; Angew. Chem. Int. Ed Engl. 1997, 36, 626-628.
15. c) H.-U. Steinberger, T. Müller, N. Auner, C. Maerker, P. von R. Schleyer, Angew. Chem. 1997, 109, 667-669; Angew. Chem. Int. Ed Engl. 1997, 36, 626-628.
16. C. Chuit, R. J. P. Corriu, A. Mehdi, C. Reyé, Angew. Chem. 1993, 105, 1372; Angew. Chem. Int. Ed. Engl. 1993, 32, 1311.
17. C. Chuit, R. J. P. Corriu, A. Mehdi, C. Reyé, Angew. Chem. 1993, 105, 1372; Angew. Chem. Int. Ed. Engl. 1993, 32, 1311.
18. J. Belzner, D. Schär, B. O. Kneisel, R. Herbst-Irmer, Organometallics 1995, 14, 1840.
19. The chlorosilanes were obtained from the reaction of the corresponding aryllithium compounds with trichlorosilane (see Supporting Information).
20. -3. All non-hydrogen atoms were refined anisotropically, all hydrogen atoms - with the exception of H(1), which was refined anisotropically - on calculated positions. Crystallographic Data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-113253. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
21. N. Auner, R. Probst, F. Hahn, E. Herdtweck, J. Organomet. Chem. 1993, 459, 25-41.
22. a) B. Becker, R. J. P. Corriu, C. Guérin, B. Henner, Q. Wang, J. Organomet. Chem. 1989, 368, C25;
23. b) C. Maerker, J. Kapp, P. von R. Schleyer in Organosilicon Chemistry: From Molecules to Materials, Vol. 2 (Eds.: N. Auner, J. Weis), VCH, Weinheim, 1996, pp. 329-359.
24. 3. Review: C. Maerker, P. von R. Schleyer in The Chemistry of Organic Silicon Compounds, Vol. 2, Part 1 (Eds.: Z. Rappoport, Y. Apeloig), Wiley, 1998, pp. 513-555.
25. 29Si-CP-MAS spectrum of 1d was kindly recorded by Dr. A. Sebald, Bayerisches Geoinstitut der Universität Bayreuth (Germany).