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An ytterbium(II) complex bearing linked cyclopentadienyl-siloxo ligand was recently reported.
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0011505466
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tBu] did not give the expected salt-free, cyclopentadienyl-amido lanthanide(II) complexes. In the case of Sm, an unidentified yellow product, possibly a Sm(III) compound, was obtained, while in the case of Yb, incorporation of LiI seemed to take place.
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33
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0034319290
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2 (Ln = Sm, Yb).
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35
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0011509112
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note
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Complex 2 might adopt a dimeric structure similar to that of 1′, although a single-crystal suitable for X-ray analysis was not yet obtained. The lower THF content of the Sm(II) complex 2 as compared to that of the Yb(II) complex 1 might be due to the larger ion radius of Sm(II), which would thus more easily lead to formation of a further assembled structure through "intermolecular" metal-ligand interactions.
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