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Benzyl methacrylate, like hexyl methacrylate, is too high-boiling for convenient vacuum transfer.
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73
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n (obs) slightly above 10 810, PDI ∼ 1.10.
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75
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0342526298
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note
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Since this technique provides separate molecular weight information for each fraction of polymer as it elutes, while GPC alone gives the average molecular weight for an entire sample, GPC / LS can more easily detect small amounts of lower molecular weight contaminants at the tail end of the molecular weight distribution.
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77
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0042915771
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Long, T. E.; DePorter, C. D.; Patel, N.; Dwight, D. W.; Wilkes, G. L.; McGrath, J. E. Polym. Prepr., Am. Chem. Soc. Div. Polym. Chem. 1987, 28 (2), 214-216.
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Polym. Prepr., Am. Chem. Soc. Div. Polym. Chem.
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, Issue.2
, pp. 214-216
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Long, T.E.1
DePorter, C.D.2
Patel, N.3
Dwight, D.W.4
Wilkes, G.L.5
McGrath, J.E.6
-
83
-
-
0342526295
-
-
Reference 75
-
Reference 75.
-
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-
-
84
-
-
0342526293
-
-
Geuskens, G.; Hellinckx, E.; David, C. Eur. Polym. J. 1971, 7, 561-568.
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(1971)
Eur. Polym. J.
, vol.7
, pp. 561-568
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Geuskens, G.1
Hellinckx, E.2
David, C.3
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85
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0010768373
-
-
Chemical Reactions on Polymers; Benham, J. L., Kinstle, J., Eds.; American Chemical Society: Washington, DC
-
For polymers with a high percentage of cleavable groups, McGrath has noted that a mixed solvent system (toluene / methanol) is required to maintain solubility. When II was reacted under these conditions, a portion of the deprotected PtBA units were converted into poly(methyl acrylate). Thus, we employed straight toluene as a solvent. A small amount of polymer precipitation was seen, but conversion to PAA was still quantitative. See: (a) Long, T. E.; Allen, R. D.; McGrath, J. E. In Chemical Reactions on Polymers; Benham, J. L., Kinstle, J., Eds.; ACS Symposium Series 364; American Chemical Society: Washington, DC, 1988, pp 258-275.
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(1988)
ACS Symposium Series 364
, pp. 258-275
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Long, T.E.1
Allen, R.D.2
McGrath, J.E.3
-
86
-
-
0343831574
-
-
Reference 80
-
(b) Reference 80.
-
-
-
-
91
-
-
0343395925
-
-
note
-
1H NMR spectrum of IV prepared by acid hydrolysis, which was carried out under nitrogen purge to remove the isobutylene, contained only a very small impurity resonance in this area, and no such peak was seen in the spectrum of V prepared with TMSI. See Reference 85.
-
-
-
-
92
-
-
0342526280
-
-
note
-
n = 29 030, PDI = 1.09. Analysis of IV was unsuccessful due to isorefractivity with the mobile phase.
-
-
-
-
93
-
-
0342526281
-
-
Reference 83
-
Reference 83.
-
-
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95
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0001739617
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Eisenberg, A.; Yokoyama, T.; Sambalido, E. J. Polylm. Sci., Polym. Chem. Ed. 1969, 7, 1717-1728.
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(1969)
J. Polylm. Sci., Polym. Chem. Ed.
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, pp. 1717-1728
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Eisenberg, A.1
Yokoyama, T.2
Sambalido, E.3
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96
-
-
0342526279
-
-
Aldrich Chemical Company
-
Aldrich Chemical Company.
-
-
-
-
97
-
-
5244370033
-
-
Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518-1520.
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(1996)
Organometallics
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, pp. 1518-1520
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Pangborn, A.B.1
Giardello, M.A.2
Grubbs, R.H.3
Rosen, R.K.4
Timmers, F.J.5
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98
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33845183199
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Nolan, S. P.; Stern, D.; Marks, T. J. J. Am. Chem. Soc. 1989, 111, 7844-7853.
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(1989)
J. Am. Chem. Soc.
, vol.111
, pp. 7844-7853
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Nolan, S.P.1
Stern, D.2
Marks, T.J.3
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99
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0000500515
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Evans, W. J.; Bloom, I.; Hunter, W. E.; Atwood, J. L. Organometallics 1985, 4, 112-119.
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(1985)
Organometallics
, vol.4
, pp. 112-119
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Evans, W.J.1
Bloom, I.2
Hunter, W.E.3
Atwood, J.L.4
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100
-
-
0342526277
-
-
Sadtler Research Laboratories: Philadelphia
-
Authentic sample as reported in JEOL High Resolution NMR Spectra; Sadtler Research Laboratories: Philadelphia, 1967.
-
(1967)
JEOL High Resolution NMR Spectra
-
-
-
102
-
-
0343831559
-
-
Pouchert, C. J., Ed.; Aldrich Chemical Company: Milwaukee
-
Authentic sample as reported in The Aldrich Library of FT-IR Spectra, 1st ed.; Pouchert, C. J., Ed.; Aldrich Chemical Company: Milwaukee, 1985; Vol. 2.
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(1985)
The Aldrich Library of FT-IR Spectra, 1st Ed.
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103
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0001431827
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Banks, A. R.; Fibiger, R. F.; Jones, T. J. Org. Chem. 1977, 42, 3965-3966.
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(1977)
J. Org. Chem.
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, pp. 3965-3966
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Banks, A.R.1
Fibiger, R.F.2
Jones, T.3
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105
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0342526275
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Mathias, L. J.; Ingram, J. E.; Kusefoglu, S. H.; Thompson, R. D.; Kress, A. O. Macromol. Synth. 1992, 11, 79-83.
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(1992)
Macromol. Synth.
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, pp. 79-83
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Mathias, L.J.1
Ingram, J.E.2
Kusefoglu, S.H.3
Thompson, R.D.4
Kress, A.O.5
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107
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0026135837
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Mathias, L. J.; Warren, R. M.; Huang, S. Macromolecules 1991, 24, 2036-2042.
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(1991)
Macromolecules
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Mathias, L.J.1
Warren, R.M.2
Huang, S.3
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