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-
85033188032
-
-
note
-
-1 with 3 equiv of LiCl at 21 °C.
-
-
-
-
73
-
-
0001436366
-
-
Epimerizations of 18-electron organometallics usually proceed through a dissociative mechanism with initial loss of a monodentate ligand, such as phosphine, giving a stereochemical nonrigid intermediate, and recoordination of the donor ligand, see: (a) Dewey, M. A.; Stark, G. A.; Gladysz, J. A. Organometallics 1996, 15, 4798. (b) Dewey, M. A.; Bakke, J. M.; Gladysz, J. A. Organometallics 1990, 9, 1351. (c) Brunner, H.; Fisch, K.; Jones, P. G.; Salbeck, J. Angew. Chem., Int. Ed. Engl. 1989, 28, 1521. (d) Martin, G. C.; Boncella, J. M. Organometallics 1989, 8, 2968. (e) Brunner, H. Top. Curr. Chem. 1975, 56, 67 and references cited therein.
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(1996)
Organometallics
, vol.15
, pp. 4798
-
-
Dewey, M.A.1
Stark, G.A.2
Gladysz, J.A.3
-
74
-
-
0000579679
-
-
Epimerizations of 18-electron organometallics usually proceed through a dissociative mechanism with initial loss of a monodentate ligand, such as phosphine, giving a stereochemical nonrigid intermediate, and recoordination of the donor ligand, see: (a) Dewey, M. A.; Stark, G. A.; Gladysz, J. A. Organometallics 1996, 15, 4798. (b) Dewey, M. A.; Bakke, J. M.; Gladysz, J. A. Organometallics 1990, 9, 1351. (c) Brunner, H.; Fisch, K.; Jones, P. G.; Salbeck, J. Angew. Chem., Int. Ed. Engl. 1989, 28, 1521. (d) Martin, G. C.; Boncella, J. M. Organometallics 1989, 8, 2968. (e) Brunner, H. Top. Curr. Chem. 1975, 56, 67 and references cited therein.
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(1990)
Organometallics
, vol.9
, pp. 1351
-
-
Dewey, M.A.1
Bakke, J.M.2
Gladysz, J.A.3
-
75
-
-
84990131844
-
-
Epimerizations of 18-electron organometallics usually proceed through a dissociative mechanism with initial loss of a monodentate ligand, such as phosphine, giving a stereochemical nonrigid intermediate, and recoordination of the donor ligand, see: (a) Dewey, M. A.; Stark, G. A.; Gladysz, J. A. Organometallics 1996, 15, 4798. (b) Dewey, M. A.; Bakke, J. M.; Gladysz, J. A. Organometallics 1990, 9, 1351. (c) Brunner, H.; Fisch, K.; Jones, P. G.; Salbeck, J. Angew. Chem., Int. Ed. Engl. 1989, 28, 1521. (d) Martin, G. C.; Boncella, J. M. Organometallics 1989, 8, 2968. (e) Brunner, H. Top. Curr. Chem. 1975, 56, 67 and references cited therein.
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Angew. Chem., Int. Ed. Engl.
, vol.28
, pp. 1521
-
-
Brunner, H.1
Fisch, K.2
Jones, P.G.3
Salbeck, J.4
-
76
-
-
0001078257
-
-
Epimerizations of 18-electron organometallics usually proceed through a dissociative mechanism with initial loss of a monodentate ligand, such as phosphine, giving a stereochemical nonrigid intermediate, and recoordination of the donor ligand, see: (a) Dewey, M. A.; Stark, G. A.; Gladysz, J. A. Organometallics 1996, 15, 4798. (b) Dewey, M. A.; Bakke, J. M.; Gladysz, J. A. Organometallics 1990, 9, 1351. (c) Brunner, H.; Fisch, K.; Jones, P. G.; Salbeck, J. Angew. Chem., Int. Ed. Engl. 1989, 28, 1521. (d) Martin, G. C.; Boncella, J. M. Organometallics 1989, 8, 2968. (e) Brunner, H. Top. Curr. Chem. 1975, 56, 67 and references cited therein.
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(1989)
Organometallics
, vol.8
, pp. 2968
-
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Martin, G.C.1
Boncella, J.M.2
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77
-
-
0016413568
-
-
and references cited therein
-
Epimerizations of 18-electron organometallics usually proceed through a dissociative mechanism with initial loss of a monodentate ligand, such as phosphine, giving a stereochemical nonrigid intermediate, and recoordination of the donor ligand, see: (a) Dewey, M. A.; Stark, G. A.; Gladysz, J. A. Organometallics 1996, 15, 4798. (b) Dewey, M. A.; Bakke, J. M.; Gladysz, J. A. Organometallics 1990, 9, 1351. (c) Brunner, H.; Fisch, K.; Jones, P. G.; Salbeck, J. Angew. Chem., Int. Ed. Engl. 1989, 28, 1521. (d) Martin, G. C.; Boncella, J. M. Organometallics 1989, 8, 2968. (e) Brunner, H. Top. Curr. Chem. 1975, 56, 67 and references cited therein.
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, vol.56
, pp. 67
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Brunner, H.1
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78
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0001248656
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Giardello, M. A.; Conticello, V. P.; Brard, L.; Sabat, M.; Rheingold, A. L.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1994, 116, 10212.
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Giardello, M.A.1
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Rheingold, A.L.5
Stern, C.L.6
Marks, T.J.7
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79
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0001235228
-
-
(a) Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4045.
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Diamond, G.M.1
Jordan, R.F.2
Petersen, J.L.3
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80
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0038800186
-
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(b) Christopher, J. N.; Diamond, G. M.; Jordan, R. F.; Petersen, J. L. Organometallics 1996, 15, 4038.
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Christopher, J.N.1
Diamond, G.M.2
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Petersen, J.L.4
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81
-
-
33751273121
-
-
2 was synthesized in a rac/meso ratio of 1/2, see ref 29a. Synthesis of the corresponding dichloro complex via metathesis gave a rac/meso ratio of 1/1, see ref 25, whereas the synthesis of the scandium and neodymium analogues gave solely the meso-isomer, see: (a) Bunel, E.; Burger, B. J.; Bercaw, J. E. J. Am. Chem. Soc. 1988, 110, 976. (b) Esser, L. Ph.D. Dissertation, Technische Universität Berlin, Germany, 1991.
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Bunel, E.1
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82
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33751273121
-
-
Ph.D. Dissertation, Technische Universität Berlin, Germany
-
2 was synthesized in a rac/meso ratio of 1/2, see ref 29a. Synthesis of the corresponding dichloro complex via metathesis gave a rac/meso ratio of 1/1, see ref 25, whereas the synthesis of the scandium and neodymium analogues gave solely the meso-isomer, see: (a) Bunel, E.; Burger, B. J.; Bercaw, J. E. J. Am. Chem. Soc. 1988, 110, 976. (b) Esser, L. Ph.D. Dissertation, Technische Universität Berlin, Germany, 1991.
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(1991)
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Esser, L.1
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83
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33646974594
-
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For photoisomerization of ansa-metallocenes see: (a) Wild, F. R. W. P.; Zsolnai, L.; Huttner, G.; Brintzinger, H. H. J. Organomet. Chem. 1982, 232, 233. (b) Collins, S.; Hong, Y.; Taylor, N. J. Organometallics 1990, 9, 2695. (c) Collins, S.; Hong, Y.; Ramachandran, R.; Taylor, N. J. Organometallics 1991, 10, 2349. (d) Rheingold, A. L.; Robinson, N. P.; Whelan, J.; Bosnich, B. Organometallics 1992, 11, 1869. (e) Kaminsky, W.; Schauwienold, A.-M.; Freidanck, F. J. Mol. Catal. A: Chemical 1996, 112, 37.
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Wild, F.R.W.P.1
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Huttner, G.3
Brintzinger, H.H.4
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84
-
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0000488070
-
-
For photoisomerization of ansa-metallocenes see: (a) Wild, F. R. W. P.; Zsolnai, L.; Huttner, G.; Brintzinger, H. H. J. Organomet. Chem. 1982, 232, 233. (b) Collins, S.; Hong, Y.; Taylor, N. J. Organometallics 1990, 9, 2695. (c) Collins, S.; Hong, Y.; Ramachandran, R.; Taylor, N. J. Organometallics 1991, 10, 2349. (d) Rheingold, A. L.; Robinson, N. P.; Whelan, J.; Bosnich, B. Organometallics 1992, 11, 1869. (e) Kaminsky, W.; Schauwienold, A.-M.; Freidanck, F. J. Mol. Catal. A: Chemical 1996, 112, 37.
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Collins, S.1
Hong, Y.2
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85
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0011564162
-
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For photoisomerization of ansa-metallocenes see: (a) Wild, F. R. W. P.; Zsolnai, L.; Huttner, G.; Brintzinger, H. H. J. Organomet. Chem. 1982, 232, 233. (b) Collins, S.; Hong, Y.; Taylor, N. J. Organometallics 1990, 9, 2695. (c) Collins, S.; Hong, Y.; Ramachandran, R.; Taylor, N. J. Organometallics 1991, 10, 2349. (d) Rheingold, A. L.; Robinson, N. P.; Whelan, J.; Bosnich, B. Organometallics 1992, 11, 1869. (e) Kaminsky, W.; Schauwienold, A.-M.; Freidanck, F. J. Mol. Catal. A: Chemical 1996, 112, 37.
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Collins, S.1
Hong, Y.2
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Taylor, N.J.4
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86
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0010804014
-
-
For photoisomerization of ansa-metallocenes see: (a) Wild, F. R. W. P.; Zsolnai, L.; Huttner, G.; Brintzinger, H. H. J. Organomet. Chem. 1982, 232, 233. (b) Collins, S.; Hong, Y.; Taylor, N. J. Organometallics 1990, 9, 2695. (c) Collins, S.; Hong, Y.; Ramachandran, R.; Taylor, N. J. Organometallics 1991, 10, 2349. (d) Rheingold, A. L.; Robinson, N. P.; Whelan, J.; Bosnich, B. Organometallics 1992, 11, 1869. (e) Kaminsky, W.; Schauwienold, A.-M.; Freidanck, F. J. Mol. Catal. A: Chemical 1996, 112, 37.
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Rheingold, A.L.1
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Whelan, J.3
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87
-
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0030579192
-
-
For photoisomerization of ansa-metallocenes see: (a) Wild, F. R. W. P.; Zsolnai, L.; Huttner, G.; Brintzinger, H. H. J. Organomet. Chem. 1982, 232, 233. (b) Collins, S.; Hong, Y.; Taylor, N. J. Organometallics 1990, 9, 2695. (c) Collins, S.; Hong, Y.; Ramachandran, R.; Taylor, N. J. Organometallics 1991, 10, 2349. (d) Rheingold, A. L.; Robinson, N. P.; Whelan, J.; Bosnich, B. Organometallics 1992, 11, 1869. (e) Kaminsky, W.; Schauwienold, A.-M.; Freidanck, F. J. Mol. Catal. A: Chemical 1996, 112, 37.
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Kaminsky, W.1
Schauwienold, A.-M.2
Freidanck, F.3
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89
-
-
85033170821
-
-
note
-
Cent (136.9(2)°), are slightly smaller than in 1a. Full crystallographic data and an ORTEP diagram of the structure of 2a are given in the Supporting Information.
-
-
-
-
90
-
-
2342512360
-
-
2 Y-C(Cp) = 2.632(7)-2.737(7) Å, see: den Haan, K. H.; de Boer, J. L.; Teuben, J. H.; Spek, A. L.; Kojic-Prodic, B.; Hays, G. R.; Huis, R. Organometallics 1986, 5, 1726.
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Den Haan, K.H.1
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Kojic-Prodic, B.5
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Huis, R.7
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91
-
-
85033177731
-
-
note
-
2 Y-C(Cp) = 2.59(1)-2.81(1) Å, see: ref 28.
-
-
-
-
92
-
-
0000713430
-
-
2 Y-C(Cp) = 2.56(2)-2.69(2) Å, see: Evans, W. J.; Peterson, T. T.; Rausch, M. D.; Hunter, W. E.; Zhang, H.; Atwood, J. L. Organometallics 1985, 4, 554.
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Evans, W.J.1
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Atwood, J.L.6
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93
-
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0001977702
-
-
2 Y-C(Cp) = 2.621(10)-2.683(9) Å, see: Holton, J.; Lappert, M. F.; Ballard, D. G. H.; Pearce, R.; Atwood, J. L.; Hunter, W. E. J. Chem. Soc., Dalton Trans. 1979, 54.
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94
-
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0000982937
-
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3Y(THF) Y-C(Cp) = 2.65(1)-2.766(7) Å, see: Rogers, R. D.; Atwood, J. L.; Emad, A.; Sikora, P. J.; Rausch, M. D. J. Organomet. Chem. 1981, 216, 383.
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37049078218
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Cent-Y = 2.363(3) Å, see: Schaverien, C. J.; Frijns, J. H. G.; Heeres, H. J.; van den Hende, J. R.; Teuben, J. H.; Spek, A. L. J. Chem. Soc., Chem. Commun. 1991, 642.
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2542517424
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0001064808
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84990165959
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2, whose crown ether like structure can be compared with that in 1a, see: Barr, D.; Berrisford, D. J.; Jones, R. V. H.; Slawin, A. M. Z.; Snaith, R.; Stoddart, J. F.; Williams, D. J. Angew. Chem., Int. Ed. Engl. 1989, 28, 1044.
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0000451073
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Cent = 127.7(3)°, see: Beletskaya, I. P.; Voskoboynikov, A. Z.; Shestakova, A. K.; Yanovsky, A. I.; Fukin, G. K.; Zacharov, L. N.; Struchkov, Y. T.; Schumann, H. J. Organomet. Chem. 1994, 468, 121.
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