Structure, optical and magnetic behaviour of meso- tetraphenylporphyrinatoiron(III) tetracyanoethenide, [FeIII(TPP)] +[TCNE].-

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 4, 2001, Pages 448-455

  Mikami, Shinji ^a   Sugiura, Ken Ichi ^a   Maruta, Tatsuo ^b   Maeda, Yonezo ^b   Ohba, Masaaki ^b,c   Usuki, Naoki ^b   Okawa, Hisashi ^b   Akutagawa, Tomoyuki ^c,d   Nisihara, Sadafumi ^d   Nakamura, Takayoshi ^d   Iwasaki, Kentaro ^e   Miyazaki, Nobuyuki ^e   Hino, Shojun ^e   Asato, Eiji ^f   Miller, Joel S ^g   Sakata, Yoshiteru ^a  

^a OSAKA UNIVERSITY   (Japan)

^b KYUSHU UNIVERSITY   (Japan)

^c JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^d HOKKAIDO UNIVERSITY   (Japan)

^e CHIBA UNIVERSITY   (Japan)

^f UNIVERSITY OF THE RYUKYUS   (Japan)

^g UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIFERROMAGNETISM; CHEMICAL BONDS; ELECTRONIC STRUCTURE; MAGNETIC MOMENTS; MAGNETIZATION; MOSSBAUER SPECTROSCOPY; NITROGEN; OXIDATION; POSITIVE IONS; REDOX REACTIONS;

COORDINATION BONDS;

IRON COMPOUNDS;

EID: 0035925340     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b007931f     Document Type: Article

References (79)

1. Recent reviews: (a) J. S. Miller and A. J. Epstein, Chem. Commun., 1998, 1319;
2. (b) J. S. Miller and A. J. Epstein, Adv. Chem. Ser., 1995, 245, 161;
3. (c) J. S. Miller and A. J. Epstein, Chem. Eng. News, 1995, 73 30;
4. (d) J. S. Miller and A. J. Epstein, Angew. Chem., Int. Ed. Engl., 1994, 33, 385;
5. (e) D. Gatteschi, Adv. Mater., 1994, 6, 635;
6. (f) M. Kinoshita, Jpn. J. Appl. Phys. Part 1, 1994, 33, 5718;
7. (g) O. Kahn, in Molecular Magnetism, VCH Publishers, Weinheim., 1993;
8. (h) R. Chiarelli, A. Rassat, Y. Dromzee, Y. Jeannin, M. A. Novak and J. L. Tholence, Phys. Scr. T, 1993, 49, 706;
9. (i) A. Caneschi and D. Gatteschi, Prog. Inorg. Chem., 1991, 37, 331;
10. (j) V. I. Ovcharenko, R. Z. Sagdev, Russ. Chem. Rev., 1999, 68, 345;
11. (k) J. S. Miller, Inorg. Chem., 2000, 39, 4392.
12. J. S. Miller, J. C. Calabrese, A. J. Epstein, R. W. Bigelow, J. H. Zhang and W. M. Reiff, J. Chem. Soc., Chem. Commun., 1986, 1026.
13. R. D. Jones, D. A. Summerville and F. Basolo, J. Am. Chem. Soc., 1978, 100, 4416.
14. J. S. Miller, J. C. Calabrese, R. S. McLean and A. J. Epstein, Adv. Mater., 1992, 4, 498.
15. D. K. Rittenberg and J. S. Miller, Inorg. Chem., 1999, 38, 4838.
16. D. K. Rittenberg, K.-i. Sugiura, Y. Sakata, S. Mikami, A. J. Epstein and J. S. Miller, Adv. Mater., 2000, 12, 126.
17. J. S. Miller, C. Vazquez, J. C. Calabrese, R. S. Mclean and A. J. Epstein, Adv. Mater., 1994, 6, 217.
18. J. S. Miller, C. Vazquez, N. L. Jones, R. S. McLean and A. J. Epstein, J. Mater. Chem., 1995, 5, 707.
19. A. Böhm, C. Vazquez, R. S. McLean, J. C. Calabrese, S. E. Kalm, J. L. Manson, A. J. Epstein and J. S. Miller, Inorg. Chem., 1996, 35, 3083.
20. K.-i. Sugiura, S. Mikami, T. Tanaka, M. Sawada, J. L. Manson, J. S. Miller and Y. Sakata, Chem. Lett., 1997, 1071.
21. E. J. Brandon, C. Kollmar and J. S. Miller, J. Am. Chem. Soc., 1998, 120, 1822.
22. E. J. Brandon, A. M. Arif, B. M. Burkhart and J. S. Miller, Inorg. Chem., 1998, 37, 2792.
23. E. J. Brandon, D. K. Rittenberg, A. M. Arif and J. S. Miller, Inorg. Chem., 1998, 37, 3376.
24. E. J. Brandon, A. M. Arif, J. S. Miller, K.-i. Sugiura and B. M. Burkhart, Cryst. Eng., 1998, 1, 97.
25. D. K. Rittenberg, K.-i. Sugiura, Y. Sakata, I. A. Guzei, A. L. Rheingold and J. S. Miller, Chem. Eur. J., 1999, 5, 1874.
26. K.-i. Sugiura, K. Ushiroda, M. T. Johnson, J. S. M. Miller and Y. Sakata, J. Mater. Chem., 2000, 10, 2507.
27. C. M. Wynn, M. A. Gîrtu, K.-i. Sugiura, E. J. Brandon, J. L. Manson, J. S. Miller and A. J. Epstein, Synth. Met., 1997, 85, 1695.
28. M. A. Gîrtu, C. M. Wynn, K.-i. Sugiura, E. J. Brandon, J. L. Manson, J. S. Miller and A. J. Epstein, Synth. Met., 1997, 85, 1703.
29. M. A. Gîrtu, C. M. Wynn, K.-i. Sugiura, J. S. Miller and A. J. Epstein, J. Appl. Phys., 1997, 81, 4410.
30. E. J. Brandon, K.-i. Sugiura, A. M. Arif, L. Liable-Sands, A. L. Rheingold and J. S. Miller, Mol. Cryst. Liq. Cryst., 1997, 305, 269.
31. K.-i. Sugiura, A. M. Arif, D. K. Rittenberg, J. Schweizer, L. Öhrstrom, A. J. Epstein and J. S. Miller, Chem. Eur. J., 1997, 3, 138.
32. C. M. Wynn, M. A. Gîrtu, J. S. Miller and A. J. Epstein, Phys. Rev. B, 1997, 56, 315.
33. C. M. Wynn, M. A. Gîrtu, J. S. Miller and A. J. Epstein, Phys. Rev. B, 1997, 56, 14050.
34. C. M. Wynn, M. A. Gîrtu, W. B. Brinckerhoff, K.-i. Sugiura, J. S. Miller and A. J. Epstein, Chem. Mater., 1997, 9, 2156.
35. A. J. Epstein, C. M. Wynn, M. A. Gîrtu, W. B. Brinckerhoff, K.-i. Sugiura and J. S. Miller, Mol. Cryst. Liq. Cryst., 1997, 305, 321.
36. E. J. Brandon, R. D. Rogers, B. M. Burkhart and J. S. Miller, Chem. Eur. J., 1998, 4, 1938.
37. K.-i. Sugiura, S. Mikami, M. T. Johnson, J. S. Miller, K. Iwasaki, K. Umishita, S. Hino and Y. Sakata, Chem. Lett., 1999, 925.
38. K.-i. Sugiura, S. Mikami, M. T. Johnson, J. S. Miller, K. Iwasaki, K. Umishita, S. Hino and Y. Sakata, J. Mater. Chem., 2000, 10, 959.
39. D. K. Rittenberg, K.-i. Sugiura, A. M. Ariff, Y. Sakata, C. D. Incarvito, A. L. Rheingold and J. S. Miller, Chem. Eur. J., 2000, 6, 1811.
40. M. T. Johnson, A. M. Arif and J. S. Miller, Eur. J. Inorg. Chem., 2000, 1781.
41. III(TPP)][TCNE], was reported: S. Sellers, B. Conklin and G. Yee, Abstracts of Papers, Fourth International Conference on Molecular-Based Magnets, Salt Lake City, 1994, Abstract p. 98;
42. II: K.-i. Sugiura, Y. Sakata and J. S. Miller, unpublished work;
43. other metals: J. S. Miller, unpublished work.
44. J. S. Miller, J. C. Calabrese, H. Rommelmann, S. R. Chittipeddi, J. H. Zhang, W. M. Reiff and A. J. Epstein, J. Am. Chem. Soc., 1987, 109, 769.
45. G. A. Candela, L. J. Swartzendruber, J. S. Miller and M. J. Rice, J. Am. Chem. Soc., 1979, 101, 2755.
46. G. T. Yee, J. M. Manriquez, D. A. Dixon, R. S. McLean, D. M. Groski, R. B. Flippen, K. S. Narayan, A. J. Epstein and J. S. Miller, Adv. Mater., 1991, 3, 309.
47. W. E. Broderick, J. A. Thompson, E. P. Day and B. M. Hoffman, Science, 1990, 249, 410.
48. A. Wolberg and J. Manassen, J. Am. Chem. Soc., 1970, 92, 2982;
49. J.-H. Fuhrhop, K. M. Kadish and D. G. Davis, J. Am. Chem. Soc., 1973, 95, 5140;
50. K. M. Kadish, M. M. Morrison, L. A. Constant, L. Dickens and D. G. Davis, J. Am. Chem. Soc., 1976, 98, 8387.
51. The boundary of the ionic-neutral ground state of the ETS is ΔE = +0.17 V using electrochemical redox potentials, i.e. ionic ground state ΔE < +0.17 V, neutral ground state ΔE > +0.17 V: T. J. B. Torrance, J. E. Vazquez, J. J. Mayerle and V. Y. Lee, Phys. Rev. Lett., 1981, 46, 253.
52. H. Kobayashi and Y. Yanagawa, Bull. Chem. Soc. Jpn., 1972, 45, 450.
53. .-.
54. M. P. Byrn, C. J. Curtis, Y. Hsiou, S. I. Khan, P. A. Sawin, S. K. Tendick, A. Terzis and C. E. Strouse, J. Am. Chem. Soc., 1993, 115, 9480.
55. W. R. Scheidt and Y. J. Lee, Struct. Bonding (Berlin), 1987, 64, 1.
56. F. A. Walker, H. Nasri, I. Turowska-Tyrk, K. Mohanrao, C. T. Watson, N. V. Shokhirev, P. G. Debrunner and W. R. Scheidt, J. Am. Chem. Soc., 1996, 118, 12109.
57. J. Silver, P. J. Marsh, M. C. R. Symons, D. A. Svistunenko, C. S. Frampton and G. R. Fern, Inorg. Chem., 2000, 39, 2874.
58. O. Q. Munro, J. A. Serth-Guzzo, I. Turowska-tyrk, K. Mohanrao, T. K. Shokhireva, F. A. Waker, P. G. Debrunner and W. R. Scheidt, J. Am. Chem. Soc., 1999, 121, 11144.
59. O. Q. Munro, H. M. Marques, P. G. Debrunner, K. Mohanrao and W. R. Scheidt, J. Am. Chem. Soc., 1995, 117, 935.
60. D. A. Dixon and J. S. Miller, J. Am. Chem. Soc., 1987, 109, 3656.
61. G. T. Yee, J. C. Calabrese, C. Vazquez and J. S. Miller, Inorg. Chem., 1993, 32, 377.
62. V. Gutmann, in The Donor-Acceptor Approach to Molecular Interactions, Plenum, New York, 1978, ch. 1.
63. Out-of-register refers to parallel chains with D's (donor molecules) near A's (acceptor molecules) and A's near D's, and in-register refers the chain with D's near D's and A's near D's.
64. K. Nakamoto, in Infrared and Raman Spectra of Inorganic and Coordination Compounds 5th Edition (Part B); John Wiley & Sons, New York, 1997, p. 113.
65. A. Johnson and H. Taube, J. Indian Chem. Soc., 1989, 66, 503.
66. M. K. Safo, G. P. Gupta, C. T. Watson, U. Simonis, F. A. Walker and W. R. Scheidt, J. Am. Chem. Soc., 1992, 114, 7066.
67. -1 was not determined; ref. 46.
68. J. R. Sams and T. B. Tsin, in The Porphyrins Vol. IV, ed. D. Dolphin, Academic Press, New York, 1979, p. 425.
69. Y. Maeda, J. Phys. Colloq., 1979, C2-40, 514.
70. 3/2 of the ETS, 708.3 eV, is closer to values reported for iron(III), 708.5-709.7 eV, than for iron(II) porphyrins, 706.6-706.9 eV: A. J. Signorelli and R. G. Hayes, J. Chem. Phys., 1976, 64, 4517.
71. 3/2 of porphyrinatoiron complexes are not sensitive to their oxidation states: K. Ichimura, Y. Nakahara, K. Kimura and H. Inokuchi, J. Mater. Chem., 1992, 2, 1185.
72. .-·2PhCl are 2.0 and 3.1 at 77 K.
73. (a) O. Kahn, in Molecular Magnetism, VCH Publishers Inc., Weinheim, 1993, ch. 11;
74. 1/2;
75. (b) J. C. Bonner and M. E. Fisher, Phys. Rev., 1964, 135, A640.
76. D. A. Summerville, I. A. Cohen, K. Hatano and W. R. Scheidt, Inorg. Chem., 1978, 17, 2906.
77. D. K. Geiger, Y. J. Lee and W. R. Scheidt, J. Am. Chem. Soc., 1984, 106, 6339.
78. S. Hino, K. Umishita, K. Iwasaki, K. Tanaka, T. Sato, T. Yamabe, K. Yoshizawa and K. Okahara, J. Phys. Chem. A, 1997, 101, 4346.
79. M. Manago, S. Hayami, Y. Yano, K. Inoue, R. Nakata, A. Ishida and Y. Maeda, Bull. Chem. Soc. Jpn., 1999, 72, 2229.