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In addition to the examples mentioned in the text, M. Drillon is currently studying a family of layered magnets proposed to order due to dipole interactions as reported at the Fifth International Conference on Molecule-Based Magnetism, Osaka, Japan, July 1996.
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The same conclusions can be reached by treating the entire entity (porphyrin core and substituent) as the ground state, with kinetic exchange between these larger units.
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Further, the phenyl rings are twisted nearly out of conjugation with the porphyrin plane (angles typically greater than 75°), significantly reducing the phenyl-porphyrin overlap, and hence nearly eliminating spin delocalization from the porphyrin to the covalently bonded phenyl ring. In addition, the π and π* energy levels of the porphyrin and the covalently bonded phenyls are mismatched, further inhibiting delocalization of spin.
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