Ferrimagnetic Behavior of Multiple Phases and Solvates of (meso-Tetrakis(4-chlorophenyl)porphinato)manganese(III) Tetracyanoethenide, [MnTClPP]-[TCNE]•. Enhancement of Magnetic Coupling by Thermal Annealing

Inorganic Chemistry

Volumn 37, Issue 13, 1998, Pages 3376-3384

  Brandon, Erik J ^a   Rittenberg, Durrell K ^a   Arif, Atta M ^a   Miller, Joel S ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000791994     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971521z     Document Type: Article

References (64)

1. Miller, J. S., Dougherty, D. A., Eds. Proceedings on the Conference on Ferromagnetic and High Spin Molecular Based Materials. Mol. Cryst., Liq. Cryst. 1989, 176. Kahn, O., Gatteschi, D., Miller, J. S., Palacio, F., Eds. Proceedings on the Conference on Molecular Magnetic Materials. NATO ARW Mol. Magn. Mater. 1991, E198. Iwamura, H., Miller, J. S., Eds. Proceedings on the Conference on the Chemistry and Physics of Molecular Based Magnetic Materials. Mol. Cryst., Liq. Cryst. 1993, 232/233. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Itoh, K., Miller, J. S., Takui, T., Guest Eds. Proceedings on the Conference on Molecular-Based Magnets. Mol. Cryst., Liq. Cryst. 1997, 305-306. Turnbull, M. M.; Sugimoto, T.; Thompson, L. K. ACS Symp. Ser. 1996, 644.
2. Miller, J. S., Dougherty, D. A., Eds. Proceedings on the Conference on Ferromagnetic and High Spin Molecular Based Materials. Mol. Cryst., Liq. Cryst. 1989, 176. Kahn, O., Gatteschi, D., Miller, J. S., Palacio, F., Eds. Proceedings on the Conference on Molecular Magnetic Materials. NATO ARW Mol. Magn. Mater. 1991, E198. Iwamura, H., Miller, J. S., Eds. Proceedings on the Conference on the Chemistry and Physics of Molecular Based Magnetic Materials. Mol. Cryst., Liq. Cryst. 1993, 232/233. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Itoh, K., Miller, J. S., Takui, T., Guest Eds. Proceedings on the Conference on Molecular-Based Magnets. Mol. Cryst., Liq. Cryst. 1997, 305-306. Turnbull, M. M.; Sugimoto, T.; Thompson, L. K. ACS Symp. Ser. 1996, 644.
3. Miller, J. S., Dougherty, D. A., Eds. Proceedings on the Conference on Ferromagnetic and High Spin Molecular Based Materials. Mol. Cryst., Liq. Cryst. 1989, 176. Kahn, O., Gatteschi, D., Miller, J. S., Palacio, F., Eds. Proceedings on the Conference on Molecular Magnetic Materials. NATO ARW Mol. Magn. Mater. 1991, E198. Iwamura, H., Miller, J. S., Eds. Proceedings on the Conference on the Chemistry and Physics of Molecular Based Magnetic Materials. Mol. Cryst., Liq. Cryst. 1993, 232/233. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Itoh, K., Miller, J. S., Takui, T., Guest Eds. Proceedings on the Conference on Molecular-Based Magnets. Mol. Cryst., Liq. Cryst. 1997, 305-306. Turnbull, M. M.; Sugimoto, T.; Thompson, L. K. ACS Symp. Ser. 1996, 644.
4. Miller, J. S., Dougherty, D. A., Eds. Proceedings on the Conference on Ferromagnetic and High Spin Molecular Based Materials. Mol. Cryst., Liq. Cryst. 1989, 176. Kahn, O., Gatteschi, D., Miller, J. S., Palacio, F., Eds. Proceedings on the Conference on Molecular Magnetic Materials. NATO ARW Mol. Magn. Mater. 1991, E198. Iwamura, H., Miller, J. S., Eds. Proceedings on the Conference on the Chemistry and Physics of Molecular Based Magnetic Materials. Mol. Cryst., Liq. Cryst. 1993, 232/233. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Itoh, K., Miller, J. S., Takui, T., Guest Eds. Proceedings on the Conference on Molecular-Based Magnets. Mol. Cryst., Liq. Cryst. 1997, 305-306. Turnbull, M. M.; Sugimoto, T.; Thompson, L. K. ACS Symp. Ser. 1996, 644.
5. Miller, J. S., Dougherty, D. A., Eds. Proceedings on the Conference on Ferromagnetic and High Spin Molecular Based Materials. Mol. Cryst., Liq. Cryst. 1989, 176. Kahn, O., Gatteschi, D., Miller, J. S., Palacio, F., Eds. Proceedings on the Conference on Molecular Magnetic Materials. NATO ARW Mol. Magn. Mater. 1991, E198. Iwamura, H., Miller, J. S., Eds. Proceedings on the Conference on the Chemistry and Physics of Molecular Based Magnetic Materials. Mol. Cryst., Liq. Cryst. 1993, 232/233. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Itoh, K., Miller, J. S., Takui, T., Guest Eds. Proceedings on the Conference on Molecular-Based Magnets. Mol. Cryst., Liq. Cryst. 1997, 305-306. Turnbull, M. M.; Sugimoto, T.; Thompson, L. K. ACS Symp. Ser. 1996, 644.
6. Miller, J. S., Dougherty, D. A., Eds. Proceedings on the Conference on Ferromagnetic and High Spin Molecular Based Materials. Mol. Cryst., Liq. Cryst. 1989, 176. Kahn, O., Gatteschi, D., Miller, J. S., Palacio, F., Eds. Proceedings on the Conference on Molecular Magnetic Materials. NATO ARW Mol. Magn. Mater. 1991, E198. Iwamura, H., Miller, J. S., Eds. Proceedings on the Conference on the Chemistry and Physics of Molecular Based Magnetic Materials. Mol. Cryst., Liq. Cryst. 1993, 232/233. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Itoh, K., Miller, J. S., Takui, T., Guest Eds. Proceedings on the Conference on Molecular-Based Magnets. Mol. Cryst., Liq. Cryst. 1997, 305-306. Turnbull, M. M.; Sugimoto, T.; Thompson, L. K. ACS Symp. Ser. 1996, 644.
7. Miller, J. S., Dougherty, D. A., Eds. Proceedings on the Conference on Ferromagnetic and High Spin Molecular Based Materials. Mol. Cryst., Liq. Cryst. 1989, 176. Kahn, O., Gatteschi, D., Miller, J. S., Palacio, F., Eds. Proceedings on the Conference on Molecular Magnetic Materials. NATO ARW Mol. Magn. Mater. 1991, E198. Iwamura, H., Miller, J. S., Eds. Proceedings on the Conference on the Chemistry and Physics of Molecular Based Magnetic Materials. Mol. Cryst., Liq. Cryst. 1993, 232/233. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Miller, J. S., Epstein, A. J., Eds. Proceedings on the Conference on Molecule-based Magnets. Mol. Cryst., Liq. Cryst. 1995, 271-274. Itoh, K., Miller, J. S., Takui, T., Guest Eds. Proceedings on the Conference on Molecular-Based Magnets. Mol. Cryst., Liq. Cryst. 1997, 305-306. Turnbull, M. M.; Sugimoto, T.; Thompson, L. K. ACS Symp. Ser. 1996, 644.
8. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
9. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
10. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
11. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
12. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
13. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
14. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
15. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
16. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
17. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
18. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
19. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
20. Reviews: (a) Buchachenko, A. L. Russ. Chem. Rev. 1990, 59, 307; Usp. Khim. 1990, 59, 529. Kahn, O. Struct. Bonding 1987, 65, 89, Kahn, O. Molecular Magnetism; VCH Publishers, Inc.; New York, 1993. (b) Caneschi, A.; Gatteschi, D.; Sessoli, R.; Rey, P. Acc. Chem. Res. 1989, 22, 392. Gatteschi, D. Adv. Mater. 1994, 6, 635. (c) Miller, J. S.; Epstein, A. J.; Reiff, W. M. Acc. Chem. Res. 1988, 21, 114. Miller, J. S.; Epstein, A. J.; Reiff, W. M. Science 1988, 240, 40. Miller, J. S.; Epstein, A. J.; Reiff. W. M. Chem. Rev. 1988, 88, 201. Miller, J. S.; Epstein, A. J. In New Aspects of Organic Chemistry; Yoshida, Z., Shiba, T., Ohsiro, Y., Eds.; VCH Publishers: New York, 1989; Vol. 237. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385; Angew. Chem. 1994, 106, 399. Miller, J. S.; Epstein, A. J. Adv. Chem. Ser. 1995, No. 245, 161.
21. Miller, J. S.; Calabrese, J. C.; Dixon, D. A.; Epstein, A. J.; Bigelow, R. W.; Zhang, J. H.; Reiff, W. M. J. Am. Chem. Soc. 1987, 109, 769. Miller, J. S.; Calabrese, J. C.; Epstein, A. J.; Bigelow, R. W.; Zhang, J. H.; Reiff, W. M. J. Chem. Soc., Chem. Commun. 1986, 1026. Chittipeddi, S.; Cromack, K. R.; Miller, J. S.; Epstein, A. J. Phys. Rev. Lett. 1987, 22, 2695.
22. Miller, J. S.; Calabrese, J. C.; Dixon, D. A.; Epstein, A. J.; Bigelow, R. W.; Zhang, J. H.; Reiff, W. M. J. Am. Chem. Soc. 1987, 109, 769. Miller, J. S.; Calabrese, J. C.; Epstein, A. J.; Bigelow, R. W.; Zhang, J. H.; Reiff, W. M. J. Chem. Soc., Chem. Commun. 1986, 1026. Chittipeddi, S.; Cromack, K. R.; Miller, J. S.; Epstein, A. J. Phys. Rev. Lett. 1987, 22, 2695.
23. Miller, J. S.; Calabrese, J. C.; Dixon, D. A.; Epstein, A. J.; Bigelow, R. W.; Zhang, J. H.; Reiff, W. M. J. Am. Chem. Soc. 1987, 109, 769. Miller, J. S.; Calabrese, J. C.; Epstein, A. J.; Bigelow, R. W.; Zhang, J. H.; Reiff, W. M. J. Chem. Soc., Chem. Commun. 1986, 1026. Chittipeddi, S.; Cromack, K. R.; Miller, J. S.; Epstein, A. J. Phys. Rev. Lett. 1987, 22, 2695.
24. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J. In Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure; Oxford University Press: New York, 1993; p 461. Chim. Ind. 1992, 74, 845. Epstein, A. J.; Miller, J. S. In Proceedings of Nobel Sympsoium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure; Oxford University Press: New York. 1992; p 475. Chim. Ind. 1993, 75, 185.
25. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J. In Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure; Oxford University Press: New York, 1993; p 461. Chim. Ind. 1992, 74, 845. Epstein, A. J.; Miller, J. S. In Proceedings of Nobel Sympsoium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure; Oxford University Press: New York. 1992; p 475. Chim. Ind. 1993, 75, 185.
26. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J. In Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure; Oxford University Press: New York, 1993; p 461. Chim. Ind. 1992, 74, 845. Epstein, A. J.; Miller, J. S. In Proceedings of Nobel Sympsoium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure; Oxford University Press: New York. 1992; p 475. Chim. Ind. 1993, 75, 185.
27. Miller, J. S.; Yee, G. T.; Manriquez, J. M.; Epstein, A. J. In Proceedings of Nobel Symposium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure; Oxford University Press: New York, 1993; p 461. Chim. Ind. 1992, 74, 845. Epstein, A. J.; Miller, J. S. In Proceedings of Nobel Sympsoium #NS-81 Conjugated Polymers and Related Materials: The Interconnection of Chemical and Electronic Structure; Oxford University Press: New York. 1992; p 475. Chim. Ind. 1993, 75, 185.
28. Miller, J. S.; Calabrese, J. C.; McLean, R. S.; Epstein, A. J. Adv. Mater. 1992, 4, 498.
29. Goldberg, I.; Krupitsky, H.; Stein, Z.; Hsiou, Y.; Strouse, C. E. Supramolecular Chem. 1995, 4, 203. Krupitsky, H.; Stein, Z.; Goldberg, I. J. Inclusion Phenom. Mol. Recognit. 1995, 20, 211. Goldberg, I. Mol. Cryst. Liq. Cryst. 1996, 278, 767. Byrn, M. P.; Curtis, C. J.; Hsiou, Y.; Kahn, S. I.; Sawin, P. A.; Tendick, S. K.; Terzis, A.; Strouse, C. E. J. Am. Chem. Soc. 1993. 115, 9480.
30. Goldberg, I.; Krupitsky, H.; Stein, Z.; Hsiou, Y.; Strouse, C. E. Supramolecular Chem. 1995, 4, 203. Krupitsky, H.; Stein, Z.; Goldberg, I. J. Inclusion Phenom. Mol. Recognit. 1995, 20, 211. Goldberg, I. Mol. Cryst. Liq. Cryst. 1996, 278, 767. Byrn, M. P.; Curtis, C. J.; Hsiou, Y.; Kahn, S. I.; Sawin, P. A.; Tendick, S. K.; Terzis, A.; Strouse, C. E. J. Am. Chem. Soc. 1993. 115, 9480.
31. Goldberg, I.; Krupitsky, H.; Stein, Z.; Hsiou, Y.; Strouse, C. E. Supramolecular Chem. 1995, 4, 203. Krupitsky, H.; Stein, Z.; Goldberg, I. J. Inclusion Phenom. Mol. Recognit. 1995, 20, 211. Goldberg, I. Mol. Cryst. Liq. Cryst. 1996, 278, 767. Byrn, M. P.; Curtis, C. J.; Hsiou, Y.; Kahn, S. I.; Sawin, P. A.; Tendick, S. K.; Terzis, A.; Strouse, C. E. J. Am. Chem. Soc. 1993. 115, 9480.
32. Goldberg, I.; Krupitsky, H.; Stein, Z.; Hsiou, Y.; Strouse, C. E. Supramolecular Chem. 1995, 4, 203. Krupitsky, H.; Stein, Z.; Goldberg, I. J. Inclusion Phenom. Mol. Recognit. 1995, 20, 211. Goldberg, I. Mol. Cryst. Liq. Cryst. 1996, 278, 767. Byrn, M. P.; Curtis, C. J.; Hsiou, Y.; Kahn, S. I.; Sawin, P. A.; Tendick, S. K.; Terzis, A.; Strouse, C. E. J. Am. Chem. Soc. 1993. 115, 9480.
33. Jones, R. D.; Summerville, D. A.; Basolo, F. J. Am. Chem. Soc. 1978, 100, 4416.
34. (a) Milgrom, L. R. Tetrahedron 1983, 39, 3895.
35. (b) Ozawa, T.; Hanaji, A. Inorg. Chim, Acta 1987, 130, 231.
36. (a) Sheldrick, G. M. Manuscript in preparation,
37. (b) Using the program CHAIN [Sack, J. S. J. Mol. Graph. 1988, 6, 224] on a graphics workstation evidence for disorder of the cation, anion, and solvent was sought without success: Burkhart, B. M. Private communication.
38. Dixon, D. A.; Miller, J. S. J. Am. Chem. Soc. 1987, 109, 3656.
39. Böhm, A.; Vazquez, C.; McLean, R. S.; Calabrese, J. C.; Kalm, S. E.; Manson, J. L.; Epstein, A. J.; Miller, J. S. Inorg. Chem. 1996, 35, 3083.
40. 12 Although many of the samples displayed Arrenhius type behavior, some exhibited incomplete or no conversion. This was ascribed to differences in crystallinity, solvation, or sample preparation. Also, the specific role of solvent (n-octane or, in this case, mineral oil) is unclear. We are continuing further work aimed at understanding this transformation and the kinetic data.
41. Rao, C. N. R.; Rao, K. J. Phase Transitions in Solids; McGraw-Hill: San Franscisco, CA, 1978. Bym, S. R. Solid-State Chemistry of Drugs; Academic: New York. 1982; pp 59-75.
42. Rao, C. N. R.; Rao, K. J. Phase Transitions in Solids; McGraw-Hill: San Franscisco, CA, 1978. Bym, S. R. Solid-State Chemistry of Drugs; Academic: New York. 1982; pp 59-75.
43. Brandon, E. J.; Kollmar, C.; Miller, J. S. J. Am. Chem. Soc. 1998, 120, 1822.
44. Landrum, J. T.; Hatano, K.; Scheidt, W. R.; Reed, C. A. J. Am. Chem. Soc. 1980, 102, 6729. Hill. C. L.; Williamson, M. M. Inorg. Chem. 1985, 24, 2834, 3024. Fleischer, E. B. Acc. Chem. Res. 1970, 3, 105. Scheldt, W. R.; Reed, C. A. Chem. Rev. 1981, 81, 543. Turner, P.; Gunter, M. J.; Hambley, T. W.; White, A. H.; Skelton, B. W. Inorg. Chem. 1992, 31, 2297. Sugiura, K.-i.; Arif, A.; Schweizer, J.; Öhrstrom, L.; Epstein, A. J.; Miller, J. S. Chem. Eur. J. 1997, 3, 138.
45. Landrum, J. T.; Hatano, K.; Scheidt, W. R.; Reed, C. A. J. Am. Chem. Soc. 1980, 102, 6729. Hill. C. L.; Williamson, M. M. Inorg. Chem. 1985, 24, 2834, 3024. Fleischer, E. B. Acc. Chem. Res. 1970, 3, 105. Scheldt, W. R.; Reed, C. A. Chem. Rev. 1981, 81, 543. Turner, P.; Gunter, M. J.; Hambley, T. W.; White, A. H.; Skelton, B. W. Inorg. Chem. 1992, 31, 2297. Sugiura, K.-i.; Arif, A.; Schweizer, J.; Öhrstrom, L.; Epstein, A. J.; Miller, J. S. Chem. Eur. J. 1997, 3, 138.
46. Landrum, J. T.; Hatano, K.; Scheidt, W. R.; Reed, C. A. J. Am. Chem. Soc. 1980, 102, 6729. Hill. C. L.; Williamson, M. M. Inorg. Chem. 1985, 24, 2834, 3024. Fleischer, E. B. Acc. Chem. Res. 1970, 3, 105. Scheldt, W. R.; Reed, C. A. Chem. Rev. 1981, 81, 543. Turner, P.; Gunter, M. J.; Hambley, T. W.; White, A. H.; Skelton, B. W. Inorg. Chem. 1992, 31, 2297. Sugiura, K.-i.; Arif, A.; Schweizer, J.; Öhrstrom, L.; Epstein, A. J.; Miller, J. S. Chem. Eur. J. 1997, 3, 138.
47. Landrum, J. T.; Hatano, K.; Scheidt, W. R.; Reed, C. A. J. Am. Chem. Soc. 1980, 102, 6729. Hill. C. L.; Williamson, M. M. Inorg. Chem. 1985, 24, 2834, 3024. Fleischer, E. B. Acc. Chem. Res. 1970, 3, 105. Scheldt, W. R.; Reed, C. A. Chem. Rev. 1981, 81, 543. Turner, P.; Gunter, M. J.; Hambley, T. W.; White, A. H.; Skelton, B. W. Inorg. Chem. 1992, 31, 2297. Sugiura, K.-i.; Arif, A.; Schweizer, J.; Öhrstrom, L.; Epstein, A. J.; Miller, J. S. Chem. Eur. J. 1997, 3, 138.
48. Landrum, J. T.; Hatano, K.; Scheidt, W. R.; Reed, C. A. J. Am. Chem. Soc. 1980, 102, 6729. Hill. C. L.; Williamson, M. M. Inorg. Chem. 1985, 24, 2834, 3024. Fleischer, E. B. Acc. Chem. Res. 1970, 3, 105. Scheldt, W. R.; Reed, C. A. Chem. Rev. 1981, 81, 543. Turner, P.; Gunter, M. J.; Hambley, T. W.; White, A. H.; Skelton, B. W. Inorg. Chem. 1992, 31, 2297. Sugiura, K.-i.; Arif, A.; Schweizer, J.; Öhrstrom, L.; Epstein, A. J.; Miller, J. S. Chem. Eur. J. 1997, 3, 138.
49. Landrum, J. T.; Hatano, K.; Scheidt, W. R.; Reed, C. A. J. Am. Chem. Soc. 1980, 102, 6729. Hill. C. L.; Williamson, M. M. Inorg. Chem. 1985, 24, 2834, 3024. Fleischer, E. B. Acc. Chem. Res. 1970, 3, 105. Scheldt, W. R.; Reed, C. A. Chem. Rev. 1981, 81, 543. Turner, P.; Gunter, M. J.; Hambley, T. W.; White, A. H.; Skelton, B. W. Inorg. Chem. 1992, 31, 2297. Sugiura, K.-i.; Arif, A.; Schweizer, J.; Öhrstrom, L.; Epstein, A. J.; Miller, J. S. Chem. Eur. J. 1997, 3, 138.
50. Next-nearest-neighbor intrachain interactions may also contribute to the ferromagnetic coupling.
51. Coronado, E.; Drillen, M.; Georges, R. In Research Frontiers in Magnetochemistry; O'Connor, C. J., Ed.; World Scientific: Singapore, 1993; p 26. Beltran, D.; Drillon, M.; Coronado, E.; Georges, R. Stud Inorg. Chem. 1983, 3, 589. Drillon, M.; Coronado, E.; Beltran, D.; Georges, R. Chem. Phys. 1983, 79, 449. Verdaguer, M.; Julve, M. Michalowicz, A.; Kahn, O. Inorg. Chem. 1983, 22, 2624. Drillon, M.; Gianduzzo, J. C.; Georges, R. Phys. Lett. A 1983, 96A, 413.
52. Coronado, E.; Drillen, M.; Georges, R. In Research Frontiers in Magnetochemistry; O'Connor, C. J., Ed.; World Scientific: Singapore, 1993; p 26. Beltran, D.; Drillon, M.; Coronado, E.; Georges, R. Stud Inorg. Chem. 1983, 3, 589. Drillon, M.; Coronado, E.; Beltran, D.; Georges, R. Chem. Phys. 1983, 79, 449. Verdaguer, M.; Julve, M. Michalowicz, A.; Kahn, O. Inorg. Chem. 1983, 22, 2624. Drillon, M.; Gianduzzo, J. C.; Georges, R. Phys. Lett. A 1983, 96A, 413.
53. Coronado, E.; Drillen, M.; Georges, R. In Research Frontiers in Magnetochemistry; O'Connor, C. J., Ed.; World Scientific: Singapore, 1993; p 26. Beltran, D.; Drillon, M.; Coronado, E.; Georges, R. Stud Inorg. Chem. 1983, 3, 589. Drillon, M.; Coronado, E.; Beltran, D.; Georges, R. Chem. Phys. 1983, 79, 449. Verdaguer, M.; Julve, M. Michalowicz, A.; Kahn, O. Inorg. Chem. 1983, 22, 2624. Drillon, M.; Gianduzzo, J. C.; Georges, R. Phys. Lett. A 1983, 96A, 413.
54. Coronado, E.; Drillen, M.; Georges, R. In Research Frontiers in Magnetochemistry; O'Connor, C. J., Ed.; World Scientific: Singapore, 1993; p 26. Beltran, D.; Drillon, M.; Coronado, E.; Georges, R. Stud Inorg. Chem. 1983, 3, 589. Drillon, M.; Coronado, E.; Beltran, D.; Georges, R. Chem. Phys. 1983, 79, 449. Verdaguer, M.; Julve, M. Michalowicz, A.; Kahn, O. Inorg. Chem. 1983, 22, 2624. Drillon, M.; Gianduzzo, J. C.; Georges, R. Phys. Lett. A 1983, 96A, 413.
55. Coronado, E.; Drillen, M.; Georges, R. In Research Frontiers in Magnetochemistry; O'Connor, C. J., Ed.; World Scientific: Singapore, 1993; p 26. Beltran, D.; Drillon, M.; Coronado, E.; Georges, R. Stud Inorg. Chem. 1983, 3, 589. Drillon, M.; Coronado, E.; Beltran, D.; Georges, R. Chem. Phys. 1983, 79, 449. Verdaguer, M.; Julve, M. Michalowicz, A.; Kahn, O. Inorg. Chem. 1983, 22, 2624. Drillon, M.; Gianduzzo, J. C.; Georges, R. Phys. Lett. A 1983, 96A, 413.
56. Seiden, J. J. Phys. Lett. 1983, 44, L947.
57. Miller, J. S.; C. Vazquez, C.; Jones, N. L.; McLean, R. S.; Epstein, A. J. J. Mater. Chem. 1995, 5, 707.
58. The low moment for 1 leads to a displacement of the χT(T) as calculated by the Seiden expression. To simply compare the shapes of the curves the observed χT(T) was increased by 14%.
59. Drillon, M.; Coronado, E.; Georges, R.; Gianduazzo, J. C.; Curely, J. Phys. Rev. B 1989, 40, 10992.
60. This relationship has been obtained from a numerical model that considers the exact quantum nature of the S = 2 spin; hence discrepancies with the classical Sieden model reflect the limitations, imposed when the S = 2 spin is taken as a classical spin.
61. Candela, G. A.; Swartzendruber, L. J.; Miller, J. S.; Rice, M. J. J. Am. Chem. Soc. 1979. 101, 2755.
62. Zhou, P.; Morin, B. G.; Epstein, A. J.; McLean, R. S.; Miller, J. S. J. Appl. Phys. 1993, 73, 6569. Brinekerhoff, W. B.; Morin, B. G.; Brandon, E. J.; Miller, J. S.; Epstein, A. J. J. App. Phys. 1996, 79, 6147.
63. Zhou, P.; Morin, B. G.; Epstein, A. J.; McLean, R. S.; Miller, J. S. J. Appl. Phys. 1993, 73, 6569. Brinekerhoff, W. B.; Morin, B. G.; Brandon, E. J.; Miller, J. S.; Epstein, A. J. J. App. Phys. 1996, 79, 6147.
64. Mydosh, J. A. Spin Classes: Francois and Taylor: Washington, DC, 1993.